Abstract: Modified lignin products, processes for making them, and their use to produce rigid polyurethane or polyisocyanurate foams are disclosed. The processes comprise heating a lignin source with a nitrogen source and a starved concentration of a C1-C5 aldehyde to give a reaction mixture comprising a Mannich condensation product, neutralizing the reaction mixture, and isolating the modified lignin product. The process is performed at a mass ratio of lignin source to nitrogen source within the range of 1:1 to 1:5 and at a molar ratio of nitrogen source to C1-C5 aldehyde within the range of 3.5:1 to 1:1. Polyol blends and performance additives that contain the modified lignin products are described. Rigid foams that process well and incorporate up to 60 wt. %, based on the amount of polyol component, of the modified lignin contribute to excellent flame retardancy and low-temperature R-value performance.

Abstract: Modified lignin products, processes for making them, and their use to produce rigid polyurethane or polyisocyanurate foams are disclosed. The processes comprise heating a lignin source with a nitrogen source and a starved concentration of a C1-C5 aldehyde to give a reaction mixture comprising a Mannich condensation product, neutralizing the reaction mixture, and isolating the modified lignin product. The process is performed at a mass ratio of lignin source to nitrogen source within the range of 1:1 to 1:5 and at a molar ratio of nitrogen source to C1-C5 aldehyde within the range of 3.5:1 to 1:1. Polyol blends and performance additives that contain the modified lignin products are described. Rigid foams that process well and incorporate up to 60 wt.%, based on the amount of polyol component, of the modified lignin contribute to excellent flame retardancy and low-temperature R-value performance.

Abstract: Soy-based high temperature products, or thermoset resins, are produced by solvent free polymerization of soy polyols and polyisocyanates at room temperature. The ratio of isocyanate equivalents to polyol equivalent used in the synthesis is greater than or equal to 3. The invented soy-based products are polyisocyanurate solid materials with excellent stability at high temperature. Heat resistance of the material is influenced by ratio of soy polyol and polyisocyanate.

Abstract: Soy-based high temperature products, or thermoset resins, are produced by solvent free polymerization of soy polyols and polyisocyanates at room temperature. The ratio of isocyanate equivalents to polyol equivalent used in the synthesis is greater than or equal to 3. The invented soy-based products are polyisocyanurate solid materials with excellent stability at high temperature. Heat resistance of the material is influenced by ratio of soy polyol and polyisocyanate.

Abstract: A reinforced hose includes an inner layer, a reinforcing intermediate layer, and an outer layer. The inner layer has and inwardly projecting sealing rib extending circumferentially on an inner surface thereof. The inner surface may also have an end stop to be engaged by a fitting received in the hose. The outer layer has a pair of annular clamp guides projecting outwardly which are axially spaced from an end of the hose. The sealing rib is positioned between the clamp guides to indicate an optimum location for a hose clamp.

Abstract: A reinforced hose includes an inner layer, a reinforcing intermediate layer, and an outer layer. The inner layer has and inwardly projecting sealing rib extending circumferentially on an inner surface thereof. The inner surface may also have an end stop to be engaged by a fitting received in the hose. The outer layer has a pair of annular clamp guides projecting outwardly which are axially spaced from an end of the hose. The sealing rib is positioned between the clamp guides to indicate an optimum location for a hose clamp.

Abstract: Soy-based high temperature products, or thermoset resins, are produced by solvent free polymerization of soy polyols and polyisocyanates at room temperature. The ratio of isocyanate equivalents to polyol equivalent used in the synthesis is greater than or equal to 3. The invented soy-based products are polyisocyanurate solid materials with excellent stability at high temperature. Heat resistance of the material is influenced by ratio of soy polyol and polyisocyanate.

Abstract: New methods of synthesizing new types of plant derived high molecular weight polyols are provided.

Abstract: Methods of one-pot synthesis of high molecular weight natural oil polyols having a functionality of between about 4 and about 8 are provided. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: A method of forming a stable mixture of a natural plant oil polyol and a petroleum-based polyol, including mixing a natural plant oil polyol with a monoglyceride, followed by adding a petroleum based polyol. Stabilized mixtures of plant oil and petroleum-based polyols can be used for synthesis of polyurethanes.

Abstract: Methods of one-pot synthesis of high molecular weight natural oil polyols having a functionality of at least two are provided. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: Methods of producing plant polyols from plant oils include reacting a plant oil with a designed reactant having one or more nucleophilic functional groups and one or more active hydrogen functional groups in the presence of an addition reaction catalyst in a single reaction step. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: Methods of producing a hybrid petro-plant oil polyol having a high bio-content by coupling a petro-chemical polyol with a plant oil based polyol is provided, including coupling an intermediate petro-polyol prepolymer with a plant oil polyol so as to synthesize a hybrid petro-plant oil polyol having a high bio-content and a hydroxyl number of between about 50 and 60.

Abstract: Methods of coupling plant oil based polyols so as to synthesis high molecular weight plant oil polyols having a hydroxyl number between from about 40 to about 60. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: Methods of one-pot synthesis of high molecular weight natural oil polyols having a functionality of at least two are provided. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: Methods of one-pot synthesis of high molecular weight natural oil polyols having a functionality of between about 4 and about 8 are provided. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: Methods of coupling plant oil based polyols so as to synthesis high molecular weight plant oil polyols having a hydroxyl number between from about 40 to about 60. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: Methods of producing plant polyols from plant oils include reacting a plant oil with a designed reactant having one or more nucleophilic functional groups and one or more active hydrogen functional groups in the presence of an addition reaction catalyst in a single reaction step. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: Methods of producing plant polyols from plant oils include reacting a plant oil with a designed reactant having one or more nucleophilic functional groups and one or more active hydrogen functional groups in the presence of an addition reaction catalyst in a single reaction step. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.

Abstract: Methods of producing plant polyols from plant oils include reacting a plant oil with a designed reactant having one or more nucleophilic functional groups and one or more active hydrogen functional groups in the presence of an addition reaction catalyst in a single reaction step. The resultant polyols may be directly reacted with polyisocyanates to produce polyurethanes.