Abstract: Luminescent materials that include a luminescent phosphor compound, articles including a security feature, and methods for producing the luminescent phosphor compounds are provided herein. In an embodiment, a luminescent material includes a medium and luminescent particles. The luminescent particles include a luminescent benzothiazole having a ureido linkage. The luminescent benzothiazole has a peak intensity within a wavelength of from about 555 to about 630 nm in response to excitation with electromagnetic radiation at a wavelength of about 366 nm.

Abstract: A process for producing high purity lithium bis(fluorosulfonyl) imide includes contacting bis(fluorosulfonyl) imide with a lithium salt, followed by purification and drying of lithium bis(fluorosulfonyl) imide.

Abstract: Luminescent materials that include a luminescent phosphor compound, articles including a security feature, and methods for producing the luminescent phosphor compounds are provided herein. In an embodiment, a luminescent material includes a medium and luminescent particles. The luminescent particles include a luminescent benzothiazole having a ureido linkage. The luminescent benzothiazole has a peak intensity within a wavelength of from about 555 to about 630 nm in response to excitation with electromagnetic radiation at a wavelength of about 366 nm.

Abstract: There is provided rare earth metal complexes of formula (I): wherein M is a cation, RE is a rare earth metal; X is a counter anion; and R1, R2, R3, and R4 are each independently selected from hydrogen, alkyl of 1-8 carbon atoms, aryl, halo, and alkoxy. Also provided is a composition of europium bis(2,2?-bipyridine-N,N?)-trinitrate with a diketonate dopant. The disclosure also provides processes for preparing the rare earth metal complexes. A mark comprising the rare earth metal complexes, and a method of applying the mark, are disclosed. The rare earth metal complexes may be used in printing systems, and for security applications.

Abstract: Luminescent fibers, articles including the luminescent fibers, and methods of forming the luminescent fibers are provided herein. In an embodiment, a luminescent fiber includes a regenerated cellulose and a luminescent polycyclic compound. The luminescent polycyclic compound includes a heterocyclic ring. The heterocyclic ring includes two nitrogen atoms therein.

Abstract: Fluorescent compositions having emission under long UV excitation can be utilized as security taggants in printing inks. The fluorescent compositions can be esters of 2-naphthalenesulfonamide, and can be produced as solids in crystal or powder form.

Abstract: A composition comprising an organic fluorophore having a structure of: or a derivative thereof; as well as articles of manufacture marked with the fluorophore, methods for marking articles with the fluorophore, and methods for producing a fluorescent fiber.

Abstract: Fluorescent compositions having emission under long UV excitation can be utilized as security taggants in printing inks. The fluorescent compositions can be esters of 2-naphthalenesulfonamide, and can be produced as solids in crystal or powder form.

Abstract: The present disclosure provides Benzoxazinone compounds represented by the formula: wherein each R1, R2, R3, and R4 is independently selected from hydrogen, alkyl of 1-12 carbon atoms, substituted alkyl, aryl of 6-12 carbon atoms, substituted aryl, halo, and alkoxy; and R5 is selected from alkyl of 1-12 carbon atoms, substituted alkyl, aryl of 6-12 carbon atoms, substituted aryl, halo, and alkoxy; wherein each of the substituted alkyl and the substituted aryl groups have a substituent selected from alkyl, aryl, halo, and alkoxy. The present disclosure provides a mark having a benzoxazinone compound, and a method for applying the mark onto an article. Also provided is a process for preparing benzoxazinone compounds.

Abstract: An electrolyte with an indicator, such as a dye, for detecting leakage from an electrochemical energy storage device is provided. Also provided is a method of making such an electrolyte with indicator; a device that incorporates such an electrolyte with indicator; a method of manufacturing an electronic or electrical system that incorporates such a device; and a method of detecting the leakage of electrolyte from a battery or capacitor.

Abstract: An electrolyte with an indicator, such as a dye, for detecting leakage from an electrochemical energy storage device is provided. Also provided is a method of making such an electrolyte with indicator; a device that incorporates such an electrolyte with indicator; a method of manufacturing an electronic or electrical system that incorporates such a device; and a method of detecting the leakage of electrolyte from a battery or capacitor.

Abstract: A composition comprising an organic fluorophore having a structure of: or a derivative thereof; as well as articles of manufacture marked with the fluorophore, methods for marking articles with the fluorophore, and methods for producing a fluorescent fiber.

Abstract: The present disclosure provides Benzoxazinone compounds represented by the formula: wherein each R1, R2, R3, and R4 is independently selected from hydrogen, alkyl of 1-12 carbon atoms, substituted alkyl, aryl of 6-12 carbon atoms, substituted aryl, halo, and alkoxy; and R5 is selected from alkyl of 1-12 carbon atoms, substituted alkyl, aryl of 6-12 carbon atoms, substituted aryl, halo, and alkoxy; wherein each of the substituted alkyl and the substituted aryl groups have a substituent selected from alkyl, aryl, halo, and alkoxy. The present disclosure provides a mark having a benzoxazinone compound, and a method for applying the mark onto an article. Also provided is a process for preparing benzoxazinone compounds.

Abstract: There is provided rare earth metal complexes of formula (I): wherein M is a cation, RE is a rare earth metal; X is a counter anion; and R1, R2, R3, and R4 are each independently selected from hydrogen, alkyl of 1-8 carbon atoms, aryl, halo, and alkoxy. Also provided is a composition of europium bis(2,2?-bipyridine-N,N?)-trinitrate with a diketonate dopant. The disclosure also provides processes for preparing the rare earth metal complexes. A mark comprising the rare earth metal complexes, and a method of applying the mark, are disclosed. The rare earth metal complexes may be used in printing systems, and for security applications.

Abstract: An article of manufacture marked with compositions comprising rare earth metal compounds which, due to their luminescence when irradiated with UV light, are suitable in particular for the marking of security-relevant items, such as documents or data carriers.

Abstract: This invention provides security articles comprising fibers, threads and fiber sections (“dots”) possessing multiple verification characteristics. The fibers possess unique and difficulty duplicated combinations of complex cross-sections, components, and multiple luminescent responses. The many verifiable characteristics of the security fibers, threads and dots provide high levels of protection against fraudulent duplication of articles in which they are incorporated. The manifold security features provide means of tailoring specific identity characteristics for specific use and users.

Abstract: Rare earth metal compounds are described which, due to their luminescence when irradiated with UV light, are suitable in particular for the marking of security-relevant items, such as documents or data carriers.

Abstract: Fluorescent pigment compounds comprising aryl-ureido benzoxazinone compounds of the general formula (I): wherein R1 is an substituted or unsubstituted aryl group, R2 and R3 are each independently selected from an H atom, an alkyl group, an alkoxy group, an alkylcarboxy group and a halogen atom, X is a carbon or sulfur atom and n is an integer of 1 or more. Many of the compounds of this class produce a yellow, generally deep yellow, emission at wavelengths of about 560 to about 585 nm when excited by an appropriate UV source. These compounds produce fluorescence making them useful as fluorescent pigments, those compounds providing emission wavelengths within the range of from about 560 to about 585 or higher when excited by a UV source are particularly useful. Those compounds having this emission spectra for the compounds makes these compounds particularly useful as pigments in security applications, particularly as pigments for use in security inks and fibers.

Abstract: An article of manufacture marked with compositions comprising rare earth metal compounds which, due to their luminescence when irradiated with UV light, are suitable in particular for the marking of security-relevant items, such as documents or data carriers.

Abstract: This invention provides security articles comprising fibers, threads and fiber sections (“dots”) possessing multiple verification characteristics. The fibers possess unique and difficulty duplicated combinations of complex cross-sections, components, and multiple luminescent responses. The many verifiable characteristics of the security fibers, threads and dots provide high levels of protection against fraudulent duplication of articles in which they are incorporated. The manifold security features provide means of tailoring specific identity characteristics for specific use and users.