Patents by Inventor Thomas R. Forbus

Thomas R. Forbus has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8252735
    Abstract: A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.
    Type: Grant
    Filed: October 28, 2009
    Date of Patent: August 28, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mark Paul Hagemeister, Thomas R. Forbus, Jr.
  • Publication number: 20100048434
    Abstract: A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.
    Type: Application
    Filed: October 28, 2009
    Publication date: February 25, 2010
    Inventors: Mark Paul Hagemeister, Thomas R. Forbus, JR.
  • Patent number: 7645395
    Abstract: The present invention utilizes simple dimethylsilicone fluids of the proper viscosity/molecular weight added to modify the low temperature properties of polycyclic hydrocarbons. One preferred embodiment of a polycyclic hydrocarbon is a perhydro dimer of alpha-methyl styrene. Addition of the dimethylsilicone fluid to the perhydo dimer of alpha-methyl styrene improves the low temperature performance without degrading the requisite low shear stress shear strength properties. Low viscosity dimethylsilicone lubricating fluids combined with polycyclic hydrocarbons are suitable for use in infinitely variable transmissions providing good low temperature flow properties and high shear strength at high temperature and low contact stress conditions.
    Type: Grant
    Filed: August 4, 2006
    Date of Patent: January 12, 2010
    Assignee: Ashland Licensing and Intellectual Property, LLC
    Inventor: Thomas R. Forbus
  • Patent number: 7629303
    Abstract: A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.
    Type: Grant
    Filed: August 17, 2005
    Date of Patent: December 8, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mark Paul Hagemeister, Thomas R. Forbus, Jr.
  • Patent number: 7553429
    Abstract: The present invention utilizes simple dimethylsilicone fluids of the proper viscosity/molecular weight distribution to modify the low temperature properties of cycloaliphatic hydrocarbon fluids. Addition of the dimethylsilicone fluid to cycloaliphatic fluids improves their low temperature performance without degrading the requisite elastohydrodynamic shear strength properties. Low viscosity dimethylsilicone lubricating fluids combined with cycloaliphatic hydrocarbon fluids are suitable for use in infinitely variable transmissions and other traction-drive transmission providing good low temperature flow properties and high elastohydrodynamic shear strength.
    Type: Grant
    Filed: August 4, 2006
    Date of Patent: June 30, 2009
    Assignee: Ashland Licensing And Intellectual Property, LLC
    Inventor: Thomas R. Forbus
  • Patent number: 7067049
    Abstract: The present invention relates to formulated lubricant oils derived from a highly paraffinic basestock. The lubricating oils of the present invention achieve the extremely stringent viscosity requirements of SAE “0W” crossgraded engine oils and demonstrate an excellent combination of low-temperature performance and biodegradability not achievable by other formulations derived from other classes of basestocks.
    Type: Grant
    Filed: February 4, 2000
    Date of Patent: June 27, 2006
    Assignee: Exxonmobil Oil Corporation
    Inventors: David J. Baillargeon, Thomas R. Forbus, Jr., Kenneth R. Graziani, Gretchen R. Hall, Nancy M. Page, Richard F. Socha
  • Patent number: 6972275
    Abstract: Novel oil-in-oil emulsions and methods of lubrication using the same are provided. The lubricants are stable emulsions of carrier fluid and high viscosity fluid that display superior properties related to lubricating film thickness and reduced shear strength.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: December 6, 2005
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Thomas R. Forbus, Jr.
  • Publication number: 20040002429
    Abstract: Novel oil-in-oil emulsions and methods of lubrication using the same are provided. The lubricants are stable emulsions of carrier fluid and high viscosity fluid that display superior properties related to lubricating film thickness and reduced shear strength.
    Type: Application
    Filed: June 28, 2002
    Publication date: January 1, 2004
    Inventor: Thomas R. Forbus
  • Patent number: 6287454
    Abstract: Lubricant oils of low pour point and improved oxidation stability are produced by catalytically dewaxing a lube feedstock over a zeolite dewaxing catalyst such as ZSM-5 in the hydrogen or decationized form. The use of these catalysts enables products of excellent oxidative stability to be obtained and reduces the catalyst aging rate in the first and subsequent dewaxing cycles to values below 5° F./day. The duration of the dewaxing cycles may be extended, particularly in the second and subsequent cycles after hydrogen reactivation.
    Type: Grant
    Filed: August 16, 1994
    Date of Patent: September 11, 2001
    Assignee: Mobil Oil Corporation
    Inventors: Thomas R. Forbus, Jr., Chwan P. Kyan
  • Patent number: 6150574
    Abstract: When different trialkyl methanes containing 25 through 36 carbon atoms are mixed the mixture exhibits surprisingly superior lubricant properties including low viscosity, high VI, low volatility, very low pour point and a dynamic viscosity at low temperatures that is less than those of PAO lubricants. Statistically predictable mixture compositions of mixed trialkyl methanes are prepared by reaction of mixtures of n-alkyl organometallic compounds with mixed aliphatic esters or equivalent compounds.
    Type: Grant
    Filed: May 6, 1999
    Date of Patent: November 21, 2000
    Assignee: Mobil Oil Corporation
    Inventor: Thomas R. Forbus, Jr.
  • Patent number: 6090989
    Abstract: A liquid hydrocarbon composition, containing paraffinic hydrocarbon components in which the extent of branching, as measured by the percentage of methyl hydrogens (BI), and the proximity of branching, as measured by the percentage of recurring methylene carbons which are four or more carbons removed from an end group or branch (CH.sub.2 >4), are such that:(a) BI-0.5(CH.sub.2 >4)>15; and(b) BI+0.85(CH.sub.2 >4)<45as measured over said liquid hydrocarbon composition as a whole.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: July 18, 2000
    Assignee: Mobil Oil Corporation
    Inventors: Jeffrey C. Trewella, Thomas R. Forbus, Jr., Zhaozhong Jiang, Randall D. Partridge, Suzanne Elaine Schramm
  • Patent number: 5614079
    Abstract: A molecular sieve catalyst is composited with an inert binder derived from an organic silicon source and organic polymer. The catalyst is used in dewaxing of petroleum chargestocks.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: March 25, 1997
    Assignee: Mobil Oil Corporation
    Inventors: Maria D. Farnos, Thomas R. Forbus, Jr., John P. McWilliams, David S. Shihabi
  • Patent number: 5603822
    Abstract: Raffinate is catalytically hydrodewaxed to lube basestock in a mixture containing between 0.01 and 1 weight percent of pour point depressants comprising the copolymer residue of a mixture of 1-alkene comonomers selected from the group consisting of C.sub.3 -C.sub.28 1-alkenes. The mixture is contacted with hydrogen and shape selective metallosilicate catalyst particles under mild hydrodewaxing conditions to produce an increased yield of lube basestock having a pour point below -25.degree. F. and viscosity index greater than 100.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: February 18, 1997
    Assignee: Mobil Oil Corporation
    Inventors: Thomas R. Forbus, Jr., David S. Shihabi
  • Patent number: 5456820
    Abstract: A process for making a lubricant oil of low pour point which comprises a) catalytically dewaxing a lube boiling range feedstock in the presence of hydrogen over a dewaxing catalyst comprising an intermediate pore size zeolite in the hydrogen or decationized form during a dewaxing cycle in which the temperature is progressively increased to maintain a substantially constant product pour point to produce a lubricant oil product of improved oxidation stability. The feedstock is sequenced during a dewaxing cycle from a heavy feed to a lighter feed in order to avoid contacting the lighter feed with the catalyst in its most active conditions.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: October 10, 1995
    Assignee: Mobil Oil Corporation
    Inventors: Thomas R. Forbus, Jr., David S. Shihabi, Chwan P. Kyan, Robert W. Bortz, Rene B. LaPierre
  • Patent number: 5370787
    Abstract: Thermal treatment of heavy petroleum resid in the presence of moderate amounts of light aromatics or paraffins produces more liquid product at the expense of gas and coke than when treated alone under identical conditions.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: December 6, 1994
    Assignee: Mobil Oil Corporation
    Inventor: Thomas R. Forbus, Jr.
  • Patent number: 5246568
    Abstract: A process for making a lubricant oil of low pour point and improved oxidation stability by catalytically hydro-dewaxing a lube chargestock containing paraffin wax in a vertical column reactor having a cascade series of fixed downflow catalyst beds over dewaxing catalyst comprising acid medium pore size zeolite. The treatment is carried out by selectively hydrodewaxing paraffinic wax contained in the liquid petroleum in a first serial catalyst bed under adiabatic cracking temperature conditions while controlling adiabatic exothermal heat of reaction within a 30.degree. C. maximum excursion from the initial reaction temperature, thereby producing lighter olefinic components, recovering partially hydrodewaxed liquid petroleum from a bottom portion of the first serial catalyst bed, and redistributing said partially hydrodewaxed liquid petroleum for contact with said catalyst in at least one downstream fixed catalyst bed.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: September 21, 1993
    Assignee: Mobil Oil Corporation
    Inventors: Thomas R. Forbus, Chwan P. Kyan
  • Patent number: 5180863
    Abstract: A process is disclosed for the preparation of low viscosity lubricant range hydrocarbons having high viscosity index which comprises: contacting olefinic dimer, or mixtures thereof, with a Group 6 metal oxide disproportionation catalyst on a solid support under disproportionation reaction conditions. The dimer comprises the product of the oligomerization of C.sub.6 -C.sub.20 alpha-olefins in contact with reduced chromium oxide catalyst on silica support. The disproportionation catalyst preparation includes treatment by oxidation at a temperature of 200.degree. C. to 900.degree. C. in the presence of an oxidizing gas and then treatment with a reducing agent at a temperature and a time sufficient to reduce said catalyst. The disproportionation reaction effluent is separated and lubricant range hydrocarbons recovered. The preferred disproportionation catalyst for the process is reduced tungsten oxide on silica support.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: January 19, 1993
    Assignee: Mobil Oil Corporation
    Inventor: Thomas R. Forbus
  • Patent number: 5171915
    Abstract: It is disclosed that aromatic compounds can be alkylated with mono-olefinic HVI-PAO dimer in contact with an acidic catalyst to produce novel alkylated aromatic compositions. It has been found that the novel HVI-PAO dimer alkylated aromatic compositions exhibit an extraordinary combination of properties relating to low viscosity with high viscosity index and low pour point which renders them very useful as lubricant basestock. Further, it has been found that the novel alkylaromatic compositions of the present invention show improved oxidative stability. Depending upon the substituent groups on the aromatic nucleus, useful lubricant additives can be prepared for improved antiwear, antioxidant and other properties. HVI-PAO dimer is prepared as a product or by-product from 1-alkene oligomerization using reduced chromium oxide on solid support.
    Type: Grant
    Filed: February 21, 1989
    Date of Patent: December 15, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Thomas R. Forbus, Bruce P. Pelrine
  • Patent number: 5144082
    Abstract: It is disclosed that aromatic compounds can be alkylated with mono-olefinic HVI-PAO dimer in contact with an acidic catalyst to produce novel alkylated aromatic compositions. It has been found that the novel HVI-PAO dimer alkylated aromatic compositions exhibit an extraordinary combination of properties relating to low viscosity with high viscosity index and low pour point which renders them very useful as lubricant basestock. Further, it has been found that the novel alkylaromatic compositions of the present invention show improved oxidative stability. Depending upon the substituent groups on the aromatic nucleus, useful lubricant additives can be prepared for improved antiwear, antioxidant and other properties. HVI-PAO dimer is prepared as a product or by-product from 1-alkene oligomerization using reduced chromium oxide on solid support. Particularly disclosed are the alkylphenols prepared by the process of alkylation a phenol at the aromatic nucleus with the novel oligomer.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: September 1, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Thomas R. Forbus, Bruce P. Pelrine
  • Patent number: 5026948
    Abstract: A process is disclosed for the preparation of low viscosity lubricant range hydrocarbons having high viscosity index which comprises: contacting olefinic dimer, or mixtures thereof, with a Group 6 metal oxide disproportionation catalyst on a solid support under disproportionation reaction conditions. The dimer comprises the product of the oligomerization of C.sub.6 -C.sub.20 alpha-olefins in contact with reduced chromium oxide catalyst on silica support. The disproportionation catalyst preparation includes treatment by oxidation at a temperature of 200.degree. C. to 900.degree. C. in the presence of an oxidizing gas and then treatment with a reducing agent at a temperature and a time sufficient to reduce said catalyst. The disproportionation reaction effluent is separated and lubricant range hydrocarbons recovered. The preferred disproportionation catalyst for the process is reduced tungsten oxide on silica support.
    Type: Grant
    Filed: February 21, 1989
    Date of Patent: June 25, 1991
    Assignee: Mobil Oil Corporation
    Inventor: Thomas R. Forbus