Patents by Inventor Thomas R. Forbus
Thomas R. Forbus has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8252735Abstract: A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.Type: GrantFiled: October 28, 2009Date of Patent: August 28, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Mark Paul Hagemeister, Thomas R. Forbus, Jr.
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Publication number: 20100048434Abstract: A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.Type: ApplicationFiled: October 28, 2009Publication date: February 25, 2010Inventors: Mark Paul Hagemeister, Thomas R. Forbus, JR.
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Patent number: 7645395Abstract: The present invention utilizes simple dimethylsilicone fluids of the proper viscosity/molecular weight added to modify the low temperature properties of polycyclic hydrocarbons. One preferred embodiment of a polycyclic hydrocarbon is a perhydro dimer of alpha-methyl styrene. Addition of the dimethylsilicone fluid to the perhydo dimer of alpha-methyl styrene improves the low temperature performance without degrading the requisite low shear stress shear strength properties. Low viscosity dimethylsilicone lubricating fluids combined with polycyclic hydrocarbons are suitable for use in infinitely variable transmissions providing good low temperature flow properties and high shear strength at high temperature and low contact stress conditions.Type: GrantFiled: August 4, 2006Date of Patent: January 12, 2010Assignee: Ashland Licensing and Intellectual Property, LLCInventor: Thomas R. Forbus
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Patent number: 7629303Abstract: A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.Type: GrantFiled: August 17, 2005Date of Patent: December 8, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Mark Paul Hagemeister, Thomas R. Forbus, Jr.
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Patent number: 7553429Abstract: The present invention utilizes simple dimethylsilicone fluids of the proper viscosity/molecular weight distribution to modify the low temperature properties of cycloaliphatic hydrocarbon fluids. Addition of the dimethylsilicone fluid to cycloaliphatic fluids improves their low temperature performance without degrading the requisite elastohydrodynamic shear strength properties. Low viscosity dimethylsilicone lubricating fluids combined with cycloaliphatic hydrocarbon fluids are suitable for use in infinitely variable transmissions and other traction-drive transmission providing good low temperature flow properties and high elastohydrodynamic shear strength.Type: GrantFiled: August 4, 2006Date of Patent: June 30, 2009Assignee: Ashland Licensing And Intellectual Property, LLCInventor: Thomas R. Forbus
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Patent number: 7067049Abstract: The present invention relates to formulated lubricant oils derived from a highly paraffinic basestock. The lubricating oils of the present invention achieve the extremely stringent viscosity requirements of SAE “0W” crossgraded engine oils and demonstrate an excellent combination of low-temperature performance and biodegradability not achievable by other formulations derived from other classes of basestocks.Type: GrantFiled: February 4, 2000Date of Patent: June 27, 2006Assignee: Exxonmobil Oil CorporationInventors: David J. Baillargeon, Thomas R. Forbus, Jr., Kenneth R. Graziani, Gretchen R. Hall, Nancy M. Page, Richard F. Socha
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Patent number: 6972275Abstract: Novel oil-in-oil emulsions and methods of lubrication using the same are provided. The lubricants are stable emulsions of carrier fluid and high viscosity fluid that display superior properties related to lubricating film thickness and reduced shear strength.Type: GrantFiled: June 28, 2002Date of Patent: December 6, 2005Assignee: ExxonMobil Research and Engineering CompanyInventor: Thomas R. Forbus, Jr.
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Publication number: 20040002429Abstract: Novel oil-in-oil emulsions and methods of lubrication using the same are provided. The lubricants are stable emulsions of carrier fluid and high viscosity fluid that display superior properties related to lubricating film thickness and reduced shear strength.Type: ApplicationFiled: June 28, 2002Publication date: January 1, 2004Inventor: Thomas R. Forbus
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Patent number: 6287454Abstract: Lubricant oils of low pour point and improved oxidation stability are produced by catalytically dewaxing a lube feedstock over a zeolite dewaxing catalyst such as ZSM-5 in the hydrogen or decationized form. The use of these catalysts enables products of excellent oxidative stability to be obtained and reduces the catalyst aging rate in the first and subsequent dewaxing cycles to values below 5° F./day. The duration of the dewaxing cycles may be extended, particularly in the second and subsequent cycles after hydrogen reactivation.Type: GrantFiled: August 16, 1994Date of Patent: September 11, 2001Assignee: Mobil Oil CorporationInventors: Thomas R. Forbus, Jr., Chwan P. Kyan
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Patent number: 6150574Abstract: When different trialkyl methanes containing 25 through 36 carbon atoms are mixed the mixture exhibits surprisingly superior lubricant properties including low viscosity, high VI, low volatility, very low pour point and a dynamic viscosity at low temperatures that is less than those of PAO lubricants. Statistically predictable mixture compositions of mixed trialkyl methanes are prepared by reaction of mixtures of n-alkyl organometallic compounds with mixed aliphatic esters or equivalent compounds.Type: GrantFiled: May 6, 1999Date of Patent: November 21, 2000Assignee: Mobil Oil CorporationInventor: Thomas R. Forbus, Jr.
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Patent number: 6090989Abstract: A liquid hydrocarbon composition, containing paraffinic hydrocarbon components in which the extent of branching, as measured by the percentage of methyl hydrogens (BI), and the proximity of branching, as measured by the percentage of recurring methylene carbons which are four or more carbons removed from an end group or branch (CH.sub.2 >4), are such that:(a) BI-0.5(CH.sub.2 >4)>15; and(b) BI+0.85(CH.sub.2 >4)<45as measured over said liquid hydrocarbon composition as a whole.Type: GrantFiled: October 13, 1998Date of Patent: July 18, 2000Assignee: Mobil Oil CorporationInventors: Jeffrey C. Trewella, Thomas R. Forbus, Jr., Zhaozhong Jiang, Randall D. Partridge, Suzanne Elaine Schramm
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Patent number: 5614079Abstract: A molecular sieve catalyst is composited with an inert binder derived from an organic silicon source and organic polymer. The catalyst is used in dewaxing of petroleum chargestocks.Type: GrantFiled: September 29, 1994Date of Patent: March 25, 1997Assignee: Mobil Oil CorporationInventors: Maria D. Farnos, Thomas R. Forbus, Jr., John P. McWilliams, David S. Shihabi
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Patent number: 5603822Abstract: Raffinate is catalytically hydrodewaxed to lube basestock in a mixture containing between 0.01 and 1 weight percent of pour point depressants comprising the copolymer residue of a mixture of 1-alkene comonomers selected from the group consisting of C.sub.3 -C.sub.28 1-alkenes. The mixture is contacted with hydrogen and shape selective metallosilicate catalyst particles under mild hydrodewaxing conditions to produce an increased yield of lube basestock having a pour point below -25.degree. F. and viscosity index greater than 100.Type: GrantFiled: November 3, 1995Date of Patent: February 18, 1997Assignee: Mobil Oil CorporationInventors: Thomas R. Forbus, Jr., David S. Shihabi
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Patent number: 5456820Abstract: A process for making a lubricant oil of low pour point which comprises a) catalytically dewaxing a lube boiling range feedstock in the presence of hydrogen over a dewaxing catalyst comprising an intermediate pore size zeolite in the hydrogen or decationized form during a dewaxing cycle in which the temperature is progressively increased to maintain a substantially constant product pour point to produce a lubricant oil product of improved oxidation stability. The feedstock is sequenced during a dewaxing cycle from a heavy feed to a lighter feed in order to avoid contacting the lighter feed with the catalyst in its most active conditions.Type: GrantFiled: December 23, 1991Date of Patent: October 10, 1995Assignee: Mobil Oil CorporationInventors: Thomas R. Forbus, Jr., David S. Shihabi, Chwan P. Kyan, Robert W. Bortz, Rene B. LaPierre
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Patent number: 5370787Abstract: Thermal treatment of heavy petroleum resid in the presence of moderate amounts of light aromatics or paraffins produces more liquid product at the expense of gas and coke than when treated alone under identical conditions.Type: GrantFiled: April 30, 1993Date of Patent: December 6, 1994Assignee: Mobil Oil CorporationInventor: Thomas R. Forbus, Jr.
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Patent number: 5246568Abstract: A process for making a lubricant oil of low pour point and improved oxidation stability by catalytically hydro-dewaxing a lube chargestock containing paraffin wax in a vertical column reactor having a cascade series of fixed downflow catalyst beds over dewaxing catalyst comprising acid medium pore size zeolite. The treatment is carried out by selectively hydrodewaxing paraffinic wax contained in the liquid petroleum in a first serial catalyst bed under adiabatic cracking temperature conditions while controlling adiabatic exothermal heat of reaction within a 30.degree. C. maximum excursion from the initial reaction temperature, thereby producing lighter olefinic components, recovering partially hydrodewaxed liquid petroleum from a bottom portion of the first serial catalyst bed, and redistributing said partially hydrodewaxed liquid petroleum for contact with said catalyst in at least one downstream fixed catalyst bed.Type: GrantFiled: September 5, 1991Date of Patent: September 21, 1993Assignee: Mobil Oil CorporationInventors: Thomas R. Forbus, Chwan P. Kyan
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Patent number: 5180863Abstract: A process is disclosed for the preparation of low viscosity lubricant range hydrocarbons having high viscosity index which comprises: contacting olefinic dimer, or mixtures thereof, with a Group 6 metal oxide disproportionation catalyst on a solid support under disproportionation reaction conditions. The dimer comprises the product of the oligomerization of C.sub.6 -C.sub.20 alpha-olefins in contact with reduced chromium oxide catalyst on silica support. The disproportionation catalyst preparation includes treatment by oxidation at a temperature of 200.degree. C. to 900.degree. C. in the presence of an oxidizing gas and then treatment with a reducing agent at a temperature and a time sufficient to reduce said catalyst. The disproportionation reaction effluent is separated and lubricant range hydrocarbons recovered. The preferred disproportionation catalyst for the process is reduced tungsten oxide on silica support.Type: GrantFiled: June 17, 1991Date of Patent: January 19, 1993Assignee: Mobil Oil CorporationInventor: Thomas R. Forbus
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Patent number: 5171915Abstract: It is disclosed that aromatic compounds can be alkylated with mono-olefinic HVI-PAO dimer in contact with an acidic catalyst to produce novel alkylated aromatic compositions. It has been found that the novel HVI-PAO dimer alkylated aromatic compositions exhibit an extraordinary combination of properties relating to low viscosity with high viscosity index and low pour point which renders them very useful as lubricant basestock. Further, it has been found that the novel alkylaromatic compositions of the present invention show improved oxidative stability. Depending upon the substituent groups on the aromatic nucleus, useful lubricant additives can be prepared for improved antiwear, antioxidant and other properties. HVI-PAO dimer is prepared as a product or by-product from 1-alkene oligomerization using reduced chromium oxide on solid support.Type: GrantFiled: February 21, 1989Date of Patent: December 15, 1992Assignee: Mobil Oil CorporationInventors: Thomas R. Forbus, Bruce P. Pelrine
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Patent number: 5144082Abstract: It is disclosed that aromatic compounds can be alkylated with mono-olefinic HVI-PAO dimer in contact with an acidic catalyst to produce novel alkylated aromatic compositions. It has been found that the novel HVI-PAO dimer alkylated aromatic compositions exhibit an extraordinary combination of properties relating to low viscosity with high viscosity index and low pour point which renders them very useful as lubricant basestock. Further, it has been found that the novel alkylaromatic compositions of the present invention show improved oxidative stability. Depending upon the substituent groups on the aromatic nucleus, useful lubricant additives can be prepared for improved antiwear, antioxidant and other properties. HVI-PAO dimer is prepared as a product or by-product from 1-alkene oligomerization using reduced chromium oxide on solid support. Particularly disclosed are the alkylphenols prepared by the process of alkylation a phenol at the aromatic nucleus with the novel oligomer.Type: GrantFiled: April 17, 1991Date of Patent: September 1, 1992Assignee: Mobil Oil CorporationInventors: Thomas R. Forbus, Bruce P. Pelrine
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Patent number: 5026948Abstract: A process is disclosed for the preparation of low viscosity lubricant range hydrocarbons having high viscosity index which comprises: contacting olefinic dimer, or mixtures thereof, with a Group 6 metal oxide disproportionation catalyst on a solid support under disproportionation reaction conditions. The dimer comprises the product of the oligomerization of C.sub.6 -C.sub.20 alpha-olefins in contact with reduced chromium oxide catalyst on silica support. The disproportionation catalyst preparation includes treatment by oxidation at a temperature of 200.degree. C. to 900.degree. C. in the presence of an oxidizing gas and then treatment with a reducing agent at a temperature and a time sufficient to reduce said catalyst. The disproportionation reaction effluent is separated and lubricant range hydrocarbons recovered. The preferred disproportionation catalyst for the process is reduced tungsten oxide on silica support.Type: GrantFiled: February 21, 1989Date of Patent: June 25, 1991Assignee: Mobil Oil CorporationInventor: Thomas R. Forbus