Patents by Inventor Thomas Robertson Ralph

Thomas Robertson Ralph has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230352713
    Abstract: A reinforced ion-conducting membrane comprises a planar reinforcing component which comprises a porous polymer material; an ion-conducting component embedded in at least a region of the planar reinforcing component, which ion-conducting component comprises an ion-conducting polymer material; and linking groups which are chemically bonded to both the planar reinforcing component and the ion-conducting component. The reinforced ion-conducting membrane is useful as the membrane in a membrane-electrode assembly for example as used in fuel cells.
    Type: Application
    Filed: June 23, 2023
    Publication date: November 2, 2023
    Inventors: David Edward BARNWELL, Peter GRAY, Thomas Robertson RALPH, Mayur Kishorbhai MISTRY
  • Patent number: 11239485
    Abstract: A process for the recovery of a perfluorosulphonic acid ionomer from a component comprising a perfluorosulphonic acid ionomer is disclosed, the process comprising immersing the component comprising the perfluorosulphonic acid ionomer in a solvent comprising an aliphatic diol and heating. Also disclosed is the use of the recovered perfluorosulphonic acid ionomer, for example in to prepared a proton conducting membrane or a catalyst ink.
    Type: Grant
    Filed: March 5, 2020
    Date of Patent: February 1, 2022
    Assignee: Johnson Matthey Fuel Cells Limited
    Inventors: Robert Jeffrey Coleman, Thomas Robertson Ralph, Sam Haig, Natalia V. Plechkova
  • Patent number: 10964967
    Abstract: A process for the recovery of a perfluorosulphonic acid ionomer from a component comprising a perfluorosulphonic acid ionomer is disclosed, the process comprising immersing the component comprising the perfluorosulphonic acid ionomer in a solvent comprising an aliphatic diol and heating. Also disclosed is the use of the recovered perfluorosulphonic acid ionomer, for example in to prepared a proton conducting membrane or a catalyst ink.
    Type: Grant
    Filed: March 24, 2016
    Date of Patent: March 30, 2021
    Assignee: Johnson Matthey Fuel Cells Limited
    Inventors: Robert Jeffrey Coleman, Thomas Robertson Ralph, Sam Haig, Natalia V. Plechkova
  • Publication number: 20200303753
    Abstract: A reinforced ion-conducting membrane comprises a planar reinforcing component which comprises a porous polymer material; an ion-conducting component embedded in at least a region of the planar reinforcing component, which ion-conducting component comprises an ion-conducting polymer material; and linking groups which are chemically bonded to both the planar reinforcing component and the ion-conducting component. The reinforced ion-conducting membrane is useful as the membrane in a membrane-electrode assembly for example as used in fuel cells.
    Type: Application
    Filed: May 25, 2017
    Publication date: September 24, 2020
    Inventors: David Edward BARNWELL, Peter GRAY, Thomas Robertson RALPH, Mayur Kishorbhai MISTRY
  • Publication number: 20200203751
    Abstract: A process for the recovery of a perfluorosulphonic acid ionomer from a component comprising a perfluorosulphonic acid ionomer is disclosed, the process comprising immersing the component comprising the perfluorosulphonic acid ionomer in a solvent comprising an aliphatic diol and heating. Also disclosed is the use of the recovered perfluorosulphonic acid ionomer, for example in to prepared a proton conducting membrane or a catalyst ink.
    Type: Application
    Filed: March 5, 2020
    Publication date: June 25, 2020
    Inventors: Robert Jeffrey Coleman, Thomas Robertson Ralph, Sam Haig, Natalia V. Plechkova
  • Publication number: 20180166695
    Abstract: A platinum alloy catalyst PtXY, wherein X is nickel, cobalt, chromium, copper, titanium or manganese and Y is tantalum or niobium, characterised in that in the alloy the atomic percentage of platinum is 46-75 at %, of X is 1-49 at % and of Y is 1-35 at %; provided that the alloy is not 66 at % Pt20 at % Cr14 at % Ta or 50 at % Pt, 25 at % Co, 25 at % Ta is disclosed. The catalyst has particular use as an oxygen reduction catalyst in fuel cells, and in particular in phosphoric acid fuel cells.
    Type: Application
    Filed: February 6, 2018
    Publication date: June 14, 2018
    Inventors: SARAH BALL, THOMAS ROBERTSON RALPH, BRIAN RONALD THEOBALD, DAVID THOMPSETT
  • Patent number: 9960430
    Abstract: A platinum alloy catalyst PtXY, wherein X is nickel, cobalt, chromium, copper, titanium or manganese and Y is tantalum or niobium, characterised in that in the alloy the atomic percentage of platinum is 46-75 at %, of X is 1-49 at % and of Y is 1-35 at %; provided that the alloy is not 66 at % Pt20 at % Cr14 at % Ta or 50 at % Pt, 25 at % Co, 25 at % Ta is disclosed. The catalyst has particular use as an oxygen reduction catalyst in fuel cells, and in particular in phosphoric acid fuel cells.
    Type: Grant
    Filed: February 3, 2010
    Date of Patent: May 1, 2018
    Assignee: JOHNSON MATTHEY FUEL CELLS LIMITED
    Inventors: Sarah Ball, Thomas Robertson Ralph, Brian Ronald Theobald, David Thompsett
  • Publication number: 20180108932
    Abstract: A process for the recovery of a perfluorosulphonic acid ionomer from a component comprising a perfluorosulphonic acid ionomer is disclosed, the process comprising immersing the component comprising the perfluorosulphonic acid ionomer in a solvent comprising an aliphatic diol and heating. Also disclosed is the use of the recovered perfluorosulphonic acid ionomer, for example in to prepared a proton conducting membrane or a catalyst ink.
    Type: Application
    Filed: March 24, 2016
    Publication date: April 19, 2018
    Inventors: Robert Jeffrey COLEMAN, Thomas Robertson RALPH, Sam HAIG, Natalia V. PLECHKOVA
  • Patent number: 9923210
    Abstract: A platinum alloy catalyst PtXY, wherein X is nickel, cobalt, chromium, copper, titanium or manganese and Y is tantalum or niobium, characterised in that in the alloy the atomic percentage of platinum is 46-75 at %, of X is 1-49 at % and of Y is 1-35 at %; provided that the alloy is not 66 at % Pt20 at % Cr14 at % Ta or 50 at % Pt, 25 at % Co, 25 at % Ta is disclosed. The catalyst has particular use as an oxygen reduction catalyst in fuel cells, and in particular in phosphoric acid fuel cells.
    Type: Grant
    Filed: March 25, 2014
    Date of Patent: March 20, 2018
    Assignee: Johnson Matthey Fuel Cells Limited
    Inventors: Sarah Ball, Thomas Robertson Ralph, Brian Ronald Theobald, David Thompsett
  • Patent number: 9692071
    Abstract: A membrane, suitable for use in a fuel cell comprises: (a) a central region comprising an ion-conducting polymeric material; (b) a border region which creates a frame around the central region and which consists of one or more non-ion-conducting materials wherein at least one of the one or more non-ion-conducting materials forms a layer; wherein the non-ion-conducting material of the border region overlaps the ion-conducting polymeric material of the central region by 0 to 10 mm in an overlap region.
    Type: Grant
    Filed: July 21, 2011
    Date of Patent: June 27, 2017
    Assignee: JOHNSON MATTHEY FUEL CELLS LIMITED
    Inventors: David Edward Barnwell, Peter Antony Trew, Thomas Robertson Ralph, Robert Jeffrey Coleman
  • Publication number: 20140205928
    Abstract: A platinum alloy catalyst PtXY, wherein X is nickel, cobalt, chromium, copper, titanium or manganese and Y is tantalum or niobium, characterised in that in the alloy the atomic percentage of platinum is 46-75 at %, of X is 1-49 at % and of Y is 1-35 at %; provided that the alloy is not 66 at % Pt 20 at % Cr14 at % Ta or 50 at % Pt, 25 at % Co, 25 at % Ta is disclosed. The catalyst has particular use as an oxygen reduction catalyst in fuel cells, and in particular in phosphoric acid fuel cells.
    Type: Application
    Filed: March 25, 2014
    Publication date: July 24, 2014
    Applicant: JOHNSON MATTHEY FUEL CELLS LIMITED
    Inventors: Sarah BALL, Thomas Robertson RALPH, Brian Ronald THEOBALD, David THOMPSETT
  • Publication number: 20130224623
    Abstract: A membrane, suitable for use in a fuel cell, comprises: (a) a central region comprising an ion-conducting polymeric material; (b) a border region which creates a frame around the central region and which consists of one or more non-ion-conducting materials wherein at least one of the one or more non-ion-conducting materials forms a layer; wherein the non-ion-conducting material of the border region overlaps the ion-conducting polymeric material of the central region by 0 to 10 mm in an overlap region.
    Type: Application
    Filed: July 21, 2011
    Publication date: August 29, 2013
    Applicant: JOHNSON MATTHEY FUEL CELLS LIMITED
    Inventors: David Edward Barnwell, Peter Antony Trew, Thomas Robertson Ralph, Robert Jeffrey Coleman
  • Patent number: 8399145
    Abstract: A membrane electrode assembly having a peripheral edge region and a central region. The membrane electrode assembly comprises an ion-conducting membrane, first and second electrocatalyst layers disposed either side of the ion-conducting membrane, and first and second gas diffusion layers disposed either side of the first and second electrocatalyst layers respectively. The membrane electrode assembly further comprises an edge protection member, the edge protection member comprising a film layer, a bonding layer, and one or more additives selected from the group consisting of free radical decomposition catalyst, self regenerating antioxidant, hydrogen donors (H-donor) primary antioxidant, free radical scavenger secondary antioxidant, oxygen absorbers (oxygen scavenger) and elemental palladium.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: March 19, 2013
    Assignee: Johnson Matthey Fuel Cells Limited
    Inventors: David Edward Barnwell, Thomas Robertson Ralph, Peter Anthony Trew
  • Publication number: 20120046161
    Abstract: A platinum alloy catalyst PtXY, wherein X is nickel, cobalt, chromium, copper, titanium or manganese and Y is tantalum or niobium, characterised in that in the alloy the atomic percentage of platinum is 46-75 at %, of X is 1-49 at % and of Y is 1-35 at %; provided that the alloy is not 66 at % Pt20 at % Cr14 at % Ta or 50 at % Pt, 25 at % Co, 25 at % Ta is disclosed. The catalyst has particular use as an oxygen reduction catalyst in fuel cells, and in particular in phosphoric acid fuel cells.
    Type: Application
    Filed: February 3, 2010
    Publication date: February 23, 2012
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: Sarah Ball, Thomas Robertson Ralph, Brian Ronald Theobald, David Thompsett
  • Publication number: 20110091790
    Abstract: An ion-conducting membrane structure comprising (i) an ion-conducting membrane wherein said membrane has a first face and a second face, (ii) a first hydrogen peroxide decomposition catalyst and (iii) a first radical scavenger, wherein the first hydrogen peroxide decomposition catalyst is in a first layer on the first face of the ion-conducting membrane in an amount from 0.01 to 15 ?g/cm2 or the first hydrogen peroxide decomposition catalyst in embedded within the ion-conducting membrane in an amount from 0.001 to 5% by weight is disclosed.
    Type: Application
    Filed: March 4, 2009
    Publication date: April 21, 2011
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: David Edward Barnwell, Adam John Hodgkinson, Thomas Robertson Ralph
  • Publication number: 20100209811
    Abstract: A membrane electrode assembly having a peripheral edge region and a central region. The membrane electrode assembly comprises an ion-conducting membrane, first and second electrocatalyst layers disposed either side of the ion-conducting membrane, and first and second gas diffusion layers disposed either side of the first and second electrocatalyst layers respectively. The membrane electrode assembly further comprises an edge protection member, the edge protection member comprising a film layer, a bonding layer, and one or more additives selected from the group consisting of free radical decomposition catalyst, self regenerating antioxidant, hydrogen donors (H-donor) primary antioxidant, free radical scavenger secondary antioxidant, oxygen absorbers (oxygen scavenger) and elemental palladium.
    Type: Application
    Filed: September 18, 2008
    Publication date: August 19, 2010
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: David Edward Barnwell, Thomas Robertson Ralph, Peter Anthony Trew
  • Patent number: 7405021
    Abstract: A novel anode structure for making a proton exchange membrane fuel cell (PEMFC) tolerant to incidences of cell reversal includes an electrocatalyst layer having at least one electrocatalyst and at least one proton conducting polymer. The anode structure also includes one or more water retaining material(s), such as carbon nanofibers, embedded within the electrocatalyst layer.
    Type: Grant
    Filed: June 20, 2001
    Date of Patent: July 29, 2008
    Assignee: Johnson Matthey Public Limited Company
    Inventors: John Malcolm Gascoyne, Graham Alan Hards, Thomas Robertson Ralph
  • Patent number: 7396610
    Abstract: The present invention relates to a membrane electrode assembly wherein each gas diffusion substrate comprises a porous electrically conductive gasket member is located on the first and second planar faces of a peripheral portion of the sheet material. The electrocatalyst layers are not present adjacent to the gasket members and the edge of the membrane is sandwiched between the gasket members. The invention further relates to integrated cell assemblies and fuel cell stacks comprising membrane electrode assemblies according to the invention.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: July 8, 2008
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Christopher James Barnett, John Malcolm Gascoyne, Graham Alan Hards, Thomas Robertson Ralph
  • Patent number: 7128993
    Abstract: The present invention relates to a composite membrane comprising at least one ion-conducting polymer and a network of randomly orientated individual fibers, wherein there is a continuous region of the membrane at one or both of the membrane faces wherein the density of fibers is lower than the density of fibers in the membrane as a whole. The invention further relates to processes for manufacturing membranes according to the invention, and membrane electrode assemblies comprising membranes according to the invention.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: October 31, 2006
    Assignee: Johnson Matthey Public Limited Company
    Inventors: David Edward Barnwell, Silvain Buche, Lorenz Gubler, Thomas Robertson Ralph
  • Patent number: 7049025
    Abstract: A novel flexible non-woven carbon fibre gas diffusion substrate comprising a plurality of first carbon fibres orientated in the x-, y- and optionally z-directions, said first fibres being bonded with a thermoplastic polymeric substance, and a carbon based filler material, characterised, in that the flexible non-woven carbon fibre gas diffusion substrate has a total density of greater than 0.35 g/cm3, and a gas diffusion electrode obtained therefrom is disclosed. Also disclosed is a process for the manufacture of the substrate and electrode.
    Type: Grant
    Filed: November 2, 2001
    Date of Patent: May 23, 2006
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Susan Joy Cooper, John Malcolm Gascoyne, Thomas Robertson Ralph, Karen Leanne Hogarth