Abstract: An extrusion die (16) including a plurality of pins (38) having side surfaces defining an intersecting array of slots (30) extending axially into the die (16) from a discharge face (34) of the die (16). A plurality of feedholes (28) extend axially from an inlet face (32) of the die (16) opposite to the discharge face (34). The feedholes (28) connect with the slots (30) at intersections (35) within the die (16) to create a flow path from the inlet face (32) to the discharge face (34). A first coating (42) is on at least a portion of the feedholes (28) in a first zone (46) extending over a first axial length of the flow path. A second coating (44) that is different than the first coating (42) is on at least a portion of the side surfaces (37) of the pins (38) in a second zone (48) extending over a second axial length of the flow path. Methods of fabricating an extrusion die (16) and manufacturing a ceramic article (100), such as a honeycomb body, are also disclosed.

Abstract: A honeycomb extrusion die (120) includes a die body (342) including an inlet face (315) and an outlet face (341). A plurality of pins (330) extend from the die body (342), wherein the pins (330) are arranged to define primary (312P) and secondary slots (312S). Primary slots (312P) include primary slot inlets (320P) and primary slot outlets (3120) and the secondary slots (312S) include secondary slot inlets (312SI) and secondary slot outlets (312SO). Feedholes (317) extend within the die body (342), the feedholes (317) including feedhole outlets (319), wherein the feedhole outlets (319) intersect only with the primary slot inlets (320P). First surface indentation features (345) extend into side surfaces (332) of the plurality of pins (330) defining the primary slots (312P). The first surface indentation features (345) are spaced from the primary slot outlets (3120). The secondary slots (312S) are devoid of surface indentation features. Other die bodies, extruders, and methods are disclosed.

Abstract: Methods of applying an inorganic material to a metal substrate that includes a metallic material having an austenite transformation temperature. The method includes depositing inorganic particles onto a surface of the metal substrate. In some embodiments, methods may include depositing inorganic particles at a deposition temperature that does not cause the metallic material to exceed the austenite transformation temperature. The inorganic particles deposited onto the surface of the metal substrate may form an abrasion-resistant coating on the surface of the metal substrate. The difference between the coefficient of thermal expansion of the metallic material and the coefficient of thermal expansion of the abrasion-resistant coating may be 10×10?6/degrees C. or less.

Abstract: A skin-forming die includes an inlet face; an outlet face; one or more slots, each of the one or more slots comprising one or more slot inlets extending between the one or more slot inlets and the outlet face; a plurality of feedholes extending between the inlet face and the one or more slot inlets; and a central opening configured to receive a matrix die. Extrusion die apparatus and methods of manufacturing honeycomb bodies are also disclosed.

Abstract: An extrusion die (16) including a plurality of pins (38) having side surfaces defining an intersecting array of slots (30) extending axially into the die (16) from a discharge face (34) of the die (16). A plurality of feedholes (28) extend axially from an inlet face (32) of the die (16) opposite to the discharge face (34). The feedholes (28) connect with the slots (30) at intersections (35) within the die (16) to create a flow path from the inlet face (32) to the discharge face (34). A first coating (42) is on at least a portion of the feedholes (28) in a first zone (46) extending over a first axial length of the flow path. A second coating (44) that is different than the first coating (42) is on at least a portion of the side surfaces (37) of the pins (38) in a second zone (48) extending over a second axial length of the flow path. Methods of fabricating an extrusion die (16) and manufacturing a ceramic article (100), such as a honeycomb body, are also disclosed.

Abstract: A honeycomb extrusion die (120) includes a die body (302) including an inlet face (306) and an exit face. The die body (302) has slot inlets (309) and a plurality of pins (320, 500) disposed between the slot inlets (309) and the exit face. The plurality of pins (320, 500) include side surfaces (322, 500B) configured to define a matrix of intersecting slots (324), wherein the matrix of intersecting slots (324) has slot exit (509) widths at the exit face. Divots (526) extend into a plurality of the side surfaces (322, 500B) between the slot inlets (309) and the exit face. Each individual divot (526) has a divot depth (D55) extending into a side surface (500A, 500B, 502A, 502B) of the side surfaces (322, 500B). A ratio between a slot exit width (W53) W53 of an individual slot (324) and the divot depth (D55) of an individual divot (526) extending into a side surface (500A, 500B, 502A, 502B) of the individual slot (324) is greater than 1.2.

Abstract: Methods of depositing an inorganic material on an extrusion die including positioning an extrusion die within a vapor deposition chamber, positioning an impedance disk over a face of the extrusion die, the impedance disk having a plurality of through holes and the face of the extrusion die having a plurality of slots defined by a plurality of extrusion die pins, and flowing one or more deposition gases through the plurality of through holes and into the plurality of slots to deposit inorganic particles on side walls of the plurality of pins. The total impedance to the flow of the deposition gases across the impedance disk and the extrusion die may be equal to a disk impedance of the impedance disk plus a die impedance of the extrusion die, and the disk impedance may be at least 40% of the total impedance to the flow of the deposition gases.

Abstract: A method and extrusion die to form a laminar integral skin of a honeycomb structure is provided. The method includes extruding a ceramic precursor batch through a die with feedholes in entry side and slots in exit face of the die to form the honeycomb structure. In a region on the periphery of the die configured to form the cell matrix, a series of concentric slots around the matrix in the exit face of the die are configured to feed skin onto the matrix. Ring sections between concentric slots are angled away from the center and a mask is disposed on top of the periphery producing a channel for extruded skin to meet and bond to extruded matrix. Optionally, slots in the skin-forming ring sections enhance knitting between laminar skin layers.

Abstract: A honeycomb extrusion die body (401) including inlet (414) and exit (402) faces, and a plurality of pins (406) on the exit face (402) defining a matrix of intersecting wide slots (425) and narrow slots (427). The wide slots (425) have an exit width (W1) greater than an exit width (W2) of the narrow slots (427). The die body (401) further includes feedholes (422) at the inlet face (414) and intersecting with inlet portions (416) to the wide slots (425) and/or the narrow slots (427). Some of the pins (406) defining the wide slots (425) include a first surface indentation feature (430) that is (i) located between the inlet portion (416) and the wide slot exit and (ii) spaced away from the wide slot exit. Some of the pins (406) defining the narrow slots (427) include a second surface indentation feature (434) that is (i) located between the inlet portion and the narrow slot exit and (ii) spaced away from the narrow slot exit.

Abstract: A honeycomb extrusion die (120) includes a die body (342) including an inlet face (315) and an outlet face (341). A plurality of pins (330) extend from the die body (342), wherein the pins (330) are arranged to define primary (312P) and secondary slots (312S). Primary slots (312P) include primary slot inlets (320P) and primary slot outlets (3120) and the secondary slots (312S) include secondary slot inlets (312SI) and secondary slot outlets (312SO). Feedholes (317) extend within the die body (342), the feedholes (317) including feedhole outlets (319), wherein the feedhole outlets (319) intersect only with the primary slot inlets (320P). First surface indentation features (345) extend into side surfaces (332) of the plurality of pins (330) defining the primary slots (312P). The first surface indentation features (345) are spaced from the primary slot outlets (3120). The secondary slots (312S) are devoid of surface indentation features. Other die bodies, extruders, and methods are disclosed.

Abstract: A honeycomb structure (110) includes intersecting porous walls (106). Inlet channels (108i) and outlet channels (108o) are formed by the intersecting porous walls (106), wherein the inlet channels (108i) comprise inlet hydraulic diameters (HDi) and the outlet channels (108o) comprise outlet hydraulic diameters (HDo). The inlet channels (108i) comprise inlet corners (220i) with inlet corner radii (Ri) and the outlet channels (108o) comprise outlet corners (2200) with outlet corner radii (Ro). A centerpost (124) is defined by adjacent opposing inlet corners (220i) of two of the inlet channels (108i) and adjacent opposing outlet corners (2200) of two of the outlet channels (108o). A first diagonal length (D1) is a shortest distance between the opposing outlet corners (220o) of the two outlet channels (108o) and a second diagonal length (D2) is a shortest distance between the opposing inlet corners (220i) of the two inlet channels (108i).

Abstract: An extrusion die (100) for a honeycomb body, the die (100) including: an input surface (102); an opposing output surface (104); feed holes (108) extending from the input surface (102) toward the output surface (104); discharge slots (106) having a slot width (SW) and a slot length (SL), and extending from the output surface (104) toward the input surface (102); and a plenum (130) fluidly connecting the feed holes (108) and the discharge slots (106). The plenum (130) may include chambers (132) connected to the feed holes (108) and including tapered outlets (134) connected to the discharge slots (106). The plenum (133) may include first chambers (132A) connected to the feed holes (108) and including first tapered outlets (134A), and second chambers (132B) connected to the first outlets and including second tapered outlets (134B) connected to the discharge slots (106).

Abstract: Methods of depositing an inorganic material on an extrusion die including positioning an extrusion die within a vapor deposition chamber, positioning an impedance disk over a face of the extrusion die, the impedance disk having a plurality of through holes and the face of the extrusion die having a plurality of slots defined by a plurality of extrusion die pins, and flowing one or more deposition gases through the plurality of through holes and into the plurality of slots to deposit inorganic particles on side walls of the plurality of pins. The total impedance to the flow of the deposition gases across the impedance disk and the extrusion die may be equal to a disk impedance of the impedance disk plus a die impedance of the extrusion die, and the disk impedance may be at least 40% of the total impedance to the flow of the deposition gases.

Abstract: An article including a metal having an austenite transformation temperature of 850 degrees C. or more. The metal may be a steel, such as a stainless steel, a martensitic steel, or a martensitic stainless steel. In some embodiments, the metal is a steel including iron, molybdenum, and tungsten, and at least one of the following: manganese, nickel, chromium, and vanadium, where the manganese, nickel, chromium, and vanadium are in the following ranges: manganese: less than 0.1 wt %, nickel: less than 0.7 wt %, chromium: more than 12.5 wt %, and vanadium: more than 0.3 wt %. The article may have a surface coated with inorganic particles. In some embodiments, the article is an extrusion die, such as a honeycomb extrusion die.

Abstract: A skin-forming die includes an inlet face; an outlet face; one or more slots, each of the one or more slots comprising one or more slot inlets extending between the one or more slot inlets and the outlet face; a plurality of feedholes extending between the inlet face and the one or more slot inlets; and a central opening configured to receive a matrix die. Extrusion die apparatus and methods of manufacturing honeycomb bodies are also disclosed.

Abstract: Methods of applying an inorganic material to a metal substrate that includes a metallic material having an austenite transformation temperature. The method includes depositing inorganic particles onto a surface of the metal substrate. In some embodiments, methods may include depositing inorganic particles at a deposition temperature that does not cause the metallic material to exceed the austenite transformation temperature. The inorganic particles deposited onto the surface of the metal substrate may form an abrasion-resistant coating on the surface of the metal substrate. The difference between the coefficient of thermal expansion of the metallic material and the coefficient of thermal expansion of the abrasion-resistant coating may be 10×10?6/degrees C. or less.

Abstract: A method and extrusion die to form a laminar integral skin of a honeycomb structure is provided. The method includes extruding a ceramic precursor batch through a die with feedholes in entry side and slots in exit face of the die to form the honeycomb structure. In a region on the periphery of the die configured to form the cell matrix, a series of concentric slots around the matrix in the exit face of the die are configured to feed skin onto the matrix. Ring sections between concentric slots are angled away from the center and a mask is disposed on top of the periphery producing a channel for extruded skin to meet and bond to extruded matrix. Optionally, slots in the skin-forming ring sections enhance knitting between laminar skin layers.

Abstract: A honeycomb extrusion die (120) includes a die body (302) including an inlet face (306) and an exit face. The die body (302) has slot inlets (309) and a plurality of pins (320, 500) disposed between the slot inlets (309) and the exit face. The plurality of pins (320, 500) include side surfaces (322, 500B) configured to define a matrix of intersecting slots (324), wherein the matrix of intersecting slots (324) has slot exit (509) widths at the exit face. Divots (526) extend into a plurality of the side surfaces (322, 500B) between the slot inlets (309) and the exit face. Each individual divot (526) has a divot san depth (D55) extending into a side surface (500A, 500B, 502A, 502B) of the side surfaces (322, 500B). A ratio between a slot exit width (W53) W53 of an individual slot (324) and the divot depth (D55) of an individual divot (526) extending into a side surface (500A, 500B, 502A, 502B) of the individual slot (324) is greater than 1.2.

Abstract: A method to form a laminar integral skin of a honeycomb structure is provided. The method includes extruding a ceramic precursor batch through a die with feedholes in entry side and slots in exit face of the die to form the honeycomb structure. In a region on the periphery of the die configured to form the cell matrix, a series of concentric slots around the matrix in the exit face of the die are configured to feed skin onto the matrix. Ring sections between concentric slots are angled away from the center and a mask is disposed on top of the periphery producing a channel for extruded skin to meet and bond to extruded matrix. Optionally, slots in the skin-forming ring sections enhance knitting between laminar skin layers. The die and honeycomb body having uniform integral skin are also provided.

Abstract: A honeycomb structure (110) includes intersecting porous walls (106). Inlet channels (108i) and outlet channels (108o) are formed by the intersecting porous walls (106), wherein the inlet channels (108i) comprise inlet hydraulic diameters (HDi) and the outlet channels (108o) comprise outlet hydraulic diameters (HDo). The inlet channels (108i) comprise inlet corners (220i) with inlet corner radii (Ri) and the outlet channels (108o) comprise outlet corners (2200) with outlet corner radii (Ro). A centerpost (124) is defined by adjacent opposing inlet corners (220i) of two of the inlet channels (108i) and adjacent opposing outlet corners (2200) of two of the outlet channels (108o). A first diagonal length (D1) is a shortest distance between the opposing outlet corners (220o) of the two outlet channels (108o) and a second diagonal length (D2) is a shortest distance between the opposing inlet corners (220i) of the two inlet channels (108i).