Abstract: Described herein is a composite comprising a fluorinated polymer and nanoparticles of lithium fluoride. The lithium fluoride has an average BET surface area of at least 10 m2/g. The fluorinated polymer includes a fluorinated polymer backbone chain and a plurality of groups represented by formula —SO2X, in which each X is independently —NZH, —NZSO2(CF2)1-6SO2X?, —NZ[SO2(CF2)dSO2NZ]1-10SO2(CF2)dSO2X?, or —OZ, and Z is independently a hydrogen, an alkali-metal cation, or a quaternary ammonium cation, X? is independently —NZH or —OZ, and each d is independently 1 to 6. A polymer electrolyte membrane, an electrode, and a membrane electrode assembly including the composite are also provided.

Abstract: The process produces a fluorinated olefin from a fluorinated copolymer having at least one of sulfonic acid groups, carboxylic acid groups, or salts thereof. The process includes heating the fluorinated copolymer at a first temperature not more than 450° C. to decompose at least one of the sulfonic acid groups, carboxylic acid groups, or salts thereof to form a partially pyrolyzed intermediate and subsequently heating the partially pyrolyzed intermediate at a second temperature of at least 550° C. to produce the fluorinated olefin.

Abstract: Methods of converting a variety of fluorinated materials into anhydrous hydrogen fluoride are described. The methods include thermally decomposing the fluorinated materials into a gaseous effluent comprising hydrogen fluoride and carbon dioxide. This gaseous effluent is then treated with carbon at a temperature of at least 830° C., converting the carbon dioxide to carbon monoxide (CO) and producing a gaseous product comprising the hydrogen fluoride, which can be condensed to generate anhydrous hydrogen fluoride. These methods can also be used to convert water contained in the gaseous effluent into hydrogen.

Abstract: Methods of converting a variety of fluorinated materials into anhydrous hydrogen fluoride are described. The methods include thermally decomposing the fluorinated materials into a gaseous effluent comprising hydrogen fluoride and carbon dioxide. This gaseous effluent is then treated with carbon at a temperature of at least 830° C., converting the carbon dioxide to carbon monoxide (CO) and producing a gaseous product comprising the hydrogen fluoride, which can be condensed to generate anhydrous hydrogen fluoride. These methods can also be used to convert water contained in the gaseous effluent into hydrogen.

Abstract: Mechanical stirred bed reactors that incorporate a screen are described. Methods of using such reactors to process perfluoropolymers to form perfluorinated olefin monomers are also described. The reactors and methods may be used to upcycle filled perfluorinated materials.

Abstract: Mechanical stirred bed reactors that incorporate a screen are described. Methods of using such reactors to process perfluoropolymers to form perfluorinated olefin monomers are also described. The reactors and methods may be used to upcycle filled perfluorinated materials.

Abstract: A composite includes a fluorinated polymer and nanoparticles of a metal salt. The metal salt has a solubility product of not more than 1×10?4. The fluorinated polymer includes a fluorinated polymer backbone chain and a plurality of groups represented by formula —SO2X, in which each X is independently —NZH, —NZSO2(CF2)1-6SO2X?, —NZ[SO2(CF2)dSO2NZ]1-10SO2(CF2)dSO2X? or —OZ, and Z is independently a hydrogen, an alkali-metal cation, or a quaternary ammonium cation, X? is independently —NZH or —OZ, and each d is independently 1 to 6. A polymer electrolyte membrane, an electrode, and a membrane electrode assembly including the composite are also provided.

Abstract: The process produces a fluorinated olefin from a fluorinated copolymer having at least one of sulfonic acid groups, carboxylic acid groups, or salts thereof. The process includes heating the fluorinated copolymer at a first temperature not more than 450° C. to decompose at least one of the sulfonic acid groups, carboxylic acid groups, or salts thereof to form a partially pyrolyzed intermediate and subsequently heating the partially pyrolyzed intermediate at a second temperature of at least 550° C. to produce the fluorinated olefin.

Abstract: The present invention relates to a battery separator containing a composite that in turn contains the following components: (A) 5 to 95 wt.-% of at least one carrier material that consists of glass fibers, the carrier material being selected from the group comprising nonwovens, laid scrims, knitted fabrics, woven fabrics and/or mixtures thereof; (B) 5 to 95 wt.-% of at least one glass platelet having an average thickness of 0.05 ?m to 30 ?m; and (C) 0 to 95 wt.-% of at least one binder; the components (A), (B) and (C) adding up to 100 wt.-% and the battery separator having a porosity in the range of 10 to 70% and a total thickness of 0.01 mm to 0.5 mm. The present invention further relates to methods for producing the battery separator and to the use thereof in a battery.

Abstract: The present invention relates to a battery separator containing a composite that in turn contains the following components: (A) 5 to 95 wt.-% of at least one carrier material that consists of glass fibers, the carrier material being selected from the group comprising nonwovens, laid scrims, knitted fabrics, woven fabrics and/or mixtures thereof; (B) 5 to 95 wt.-% of at least one glass platelet having an average thickness of 0.05 ?m to 30 ?m; and (C) 0 to 95 wt.-% of at least one binder; the components (A), (B) and (C) adding up to 100 wt.-% and the battery separator having a porosity in the range of 10 to 70% and a total thickness of 0.01 mm to 0.5 mm. The present invention further relates to methods for producing the battery separator and to the use thereof in a battery.

Abstract: A process for generating calcium fluoride particles having a particle size (d50) of from about 15 ?m to about 300 ?m. The process features contacting a gas stream having gaseous hydrogen fluoride (HF) with a fluidized bed of calcium carbonate particles in a fluidized bed reactor.

Abstract: Provided is a process for producing fluorinated alkenes by providing a microwave plasma in a reactor chamber, introducing a protective gas feed into the reactor chamber, and contacting a conversion feed comprising at least one fluorinated linear or branched alkane with the plasma. Also provided are an apparatus and the use of the process and the apparatus.

Abstract: Provided is a process for producing fluorinated alkenes by providing a microwave plasma in a reactor chamber, introducing a protective gas feed into the reactor chamber, and contacting a conversion feed comprising at least one fluorinated linear or branched alkane with the plasma. Also provided are an apparatus and the use of the process and the apparatus.

Abstract: The invention relates to a process for producing free-flowing calcium fluoride particles from a diluted aqueous solution of hydrogen fluoride comprising the step of reacting the diluted aqueous solution of hydrogen fluoride with calcium carbonate particles at a temperature of less than 50° C. The invention further relates to the use of the free-flowing calcium fluoride particles for the manufacturing of anhydrous hydrogen fluoride.

Abstract: The invention relates to a process for producing free-flowing calcium fluoride particles from a diluted aqueous solution of hydrogen fluoride comprising the step of reacting the diluted aqueous solution of hydrogen fluoride with calcium carbonate particles at a temperature of less than 50° C. The invention further relates to the use of the free-flowing calcium fluoride particles for the manufacturing of anhydrous hydrogen fluoride.

Abstract: Process for producing fluorinated olefins from fluorinated materials, the process comprising thermally decomposing the fluoropolymers into fluoroolefins in a reactor having a feeding zone where the fluorinated materials are fed into the reactor and a decomposition zone where the fluorinated materials are thermally decomposed and wherein the thermal decomposition is carried out in the presence of microwave irradiation.

Abstract: Process for producing fluorinated olefins from fluorinated materials, the process comprising thermally decomposing the fluoropolymers into fluoroolefins in a reactor having a feeding zone where the fluorinated materials are fed into the reactor and a decomposition zone where the fluorinated materials are thermally decomposed and wherein the thermal decomposition is carried out in the presence of microwave irradiation.

Abstract: This invention relates to a method for the thermal treatment of granular solids in a reactor (1) with swirl chamber (4), which in particular constitutes an flash reactor or suspension reactor, wherein the microwave radiation from a microwave source (2) is fed into the reactor (1) through a wave guide, and to a corresponding plant. To avoid deposits in the wave guide, the same constitutes a gas supply tube (3), a gas stream being additionally fed through the gas supply tube (3) into the swirl chamber (4).

Abstract: This invention relates to a method for the thermal treatment of granular solids in a fluidized-bed reactor (1), in which microwave radiation from a microwave source (2) is fed into the reactor (1), and to a corresponding plant. To improve the utilization of energy and the introduction of the microwave radiation, a first gas or gas mixture is introduced from below through a preferably central gas supply tube (3) into a mixing chamber (7) of the reactor, the gas supply tube (3) being at least partly surrounded by a stationary annular fluidized bed (8) which is fluidized by supplying fluidizing gas. The microwave radiation is supplied to the mixing chamber (7) through the same gas supply tube (3).

Abstract: This invention relates to a method for the thermal treatment of granular solids in a fluidized bed (3, 3a) which is located in a fluidized-bed reactor (1, 1a), wherein microwave radiation is fed into the fluidized-bed reactor (1, 1a) through at least one wave guide (5), and to a corresponding plant. To improve the efficiency of the microwave irradiation, the irradiation angle of the microwaves is inclined by an angle of 10° to 50°, in particular 10° to 20°, with respect to the principal axis (11) of the fluidized-bed reactor (1, 1a).