Patents by Inventor Tianyi Li

Tianyi Li has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7351778
    Abstract: The present invention provides a catalyst component for polymerization of olefin CH2?CHR, in which R is hydrogen or C1-C12 alkyl or aryl, comprising magnesium, titanium, a halogen and an electron donor compound (a) which is at least one selected from the group consisting of dibasic ester compounds of the formula (I), and said catalyst component optionally further comprising an electron donor compound (b) selected from the group consisting of aliphatic dicarboxylic esters and aromatic dicarboxylic esters, and/or an electron donor compound (c) selected from the group consisting of 1,3-diether compounds of formula (IV): wherein, R1, R? and A are as defined in the description, wherein RI-RVIII are as defined in the description, and a catalyst comprising the catalyst component.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: April 1, 2008
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
    Inventors: Mingzhi Gao, Haitao Liu, Tianyi Li, Xianzhong Li, Changxiu Li, Jiyu Li, Lingyan Xing, Juxiu Yang, Jing Ma, Xiaodong Wang, Chunmin Ding
  • Patent number: 7323431
    Abstract: The present application discloses a catalyst for olefin polymerization, comprising a product of the following components: (A) solid titanium-containing catalyst component comprising magnesium, titanium and halogen as essential components; (B) organo-aluminum compound catalyst component, and (C) silicon ether compound catalyst component, the silicon ether compound being represented by a general formula (I): wherein R1-R12 and A are as defined in the description.
    Type: Grant
    Filed: December 23, 2004
    Date of Patent: January 29, 2008
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Mingzhi Gao, Lunjia Xie, Xiaodong Wang, Siyuan Zhao, Jing Ma, Haitao Liu, Tianyi Li, Zhufang Sun
  • Publication number: 20070155616
    Abstract: The invention relates to a catalyst component for olefin (co)polymerization, to preparation thereof, to a catalyst comprising the same, and to use thereof in olefin (co)polymerization. The catalyst component of the invention comprises magnesium, titanium, halogen, inner electron donor compound, and alkoxy group derived from a surface modifier, wherein the content of the alkoxy group derived from the surface modifier is in a range of from 0.01 to 3 percent by weight, based on the weight of the catalyst component.
    Type: Application
    Filed: January 4, 2006
    Publication date: July 5, 2007
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry
    Inventors: Zhiwu Wang, Zhong Tan, Zhengyang Guo, Kai Zhang, Tianyi Li, Jun Xiao, Peng Kou, Liang Pan, Li'an Yan, Xingbo Li, Huijuan Xu, Haixiang Cui, Yu Wang, Ling Yang
  • Publication number: 20060287446
    Abstract: The present invention provides a catalyst component for polymerization of olefin CH2=CHR, in which R is hydrogen or C1-C12 alkyl or aryl, comprising magnesium, titanium, a halogen and an electron donor compound (a) which is at least one selected from the group consisting of dibasic ester compounds of the formula (I), and said catalyst component optionally further comprising an electron donor compound (b) selected from the group consisting of aliphatic dicarboxylic esters and aromatic dicarboxylic esters, and/or an electron donor compound (c) selected from the group consisting of 1,3-diether compounds of formula (IV): wherein, R1, R? and A are as defined in the description, wherein RI-RVIII are as defined in the description, and a catalyst comprising the catalyst component.
    Type: Application
    Filed: April 28, 2005
    Publication date: December 21, 2006
    Inventors: Mingzhi Gao, Haitao Liu, Tianyi Li, Xianzhong Li, Changxiu Li, Jiyu Li, Lingyan Xing, Juxiu Yang, Jing Ma, Xiaodong Wang, Chunmin Ding
  • Publication number: 20060183873
    Abstract: The present invention relates to silicon ether compounds having a general formula (I), a method for the preparation thereof and use thereof as a component of catalysts for polymerization of olefins. In particular, in propylene polymerization, catalyst systems comprising the silicon ether compounds as external electron donor component exhibit good hydrogen response, and can be used to prepare polymer having high isotacticity at high yield. wherein R1-R10 groups are as defined in the description.
    Type: Application
    Filed: February 16, 2005
    Publication date: August 17, 2006
    Inventors: Lunjia Xie, Mingzhi Gao, Siyuan Zhao, Jing Ma, Zhufang Sun, Haitao Liu, Tianyi Li, Mingsen Zhang, Changjiang Wu
  • Patent number: 7091289
    Abstract: The present invention provides a catalyst component used for homopolymerization or co-polymerization of ethylene, comprising at least one suitable electron donor compound supported on a composition containing magnesium and titanium, wherein the electron donor compound is selected from the group consisting of aliphatic ethers, alicyclic ethers, aromatic ethers, aliphatic ketones and alicyclic ketones, and wherein the composition containing magnesium and titanium is prepared by dissolving a magnesium compound into a solvent system to form a homogeneous solution and then contacting the solution with a titanium compound in the presence of a precipitation aid to precipitate the composition. The present invention also relates to a method for the preparation of said catalyst component and a catalyst comprising thereof, and to use of the catalyst in homopolymerization of ethylene or co-polymerization of ethylene with at least one C3–C8 ?-olefin.
    Type: Grant
    Filed: June 5, 2003
    Date of Patent: August 15, 2006
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Zhiwu Wang, Zhong Tan, Tianyi Li, Xingbo Li, Kai Zhang, Peng Kou, Haixiang Cui, Zhengyang Guo, Liang Pan
  • Publication number: 20060142146
    Abstract: The present application discloses a catalyst for olefin polymerization, comprising a product of the following components: (A) solid titanium-containing catalyst component comprising magnesium, titanium and halogen as essential components; (B) organo-aluminum compound catalyst component, and (C) silicon ether compound catalyst component, the silicon ether compound being represented by a general formula (I): wherein R1-R12 and A are as defined in the description.
    Type: Application
    Filed: December 23, 2004
    Publication date: June 29, 2006
    Inventors: Mingzhi Gao, Lunjia Xie, Xiaodong Wang, Siyuan Zhao, Jing Ma, Haitao Liu, Tianyi Li, Zhufang Sun
  • Publication number: 20060003888
    Abstract: The present invention provides a spheric catalyst component as well as a catalyst for olefin polymerization. The spheric catalyst component comprises at least one titanium compound and optionally at least one electron donor compound supported on an active magnesium halide spheric carrier, wherein the active magnesium halide spheric carrier is solid particles obtained by dispersing a melt of magnesium halide/alcohol adduct by rotation under high-gravity field. The catalyst has good particle morphology and narrow particle size distribution, and when used in olefin polymerization, especially in propylene polymerization, exhibits relatively high activity and stereoelectivity, and gives polymers having good particle morphology and high bulk density.
    Type: Application
    Filed: July 1, 2005
    Publication date: January 5, 2006
    Inventors: Yuanyi Yang, Hongbin Du, Zhenhu Li, Zhiwu Wang, Zhong Tan, Kai Zhang, Xianzahi Xia, Tianyi Li, Xinsheng Wang, Tianyi Zhang, Wei Chen, Xuan Zheng
  • Publication number: 20050239636
    Abstract: The present invention provides a solid catalyst component for the polymerization of olefins, comprising magnesium, titanium, a halogen and an electron donor, wherein said electron donor comprises at least one selected from the group consisting of polyol ester compounds of the formula (I): R1CO—O—CR3R4-A-CR5R6—O—CO—R2 (I) wherein, R1 and R2 groups, which may be identical or different, can be substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R3-R6 groups, which may be identical or different, can be selected from the group consisting of hydrogen, halogen or substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R1-R6 groups optionally contain one or more hetero-atoms replacing carbon, hydrogen atom or the both, said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom, two or more of R3-R6 groups can be linked to form saturated or unsaturated monocyclic or polycyclic ring; A is a single bond or bivalent linking grou
    Type: Application
    Filed: January 30, 2003
    Publication date: October 27, 2005
    Inventors: Mingzhi Gao, Haitao Liu, Zhulan Li, Jun Wang, Juxiu Yang, Tianyi Li, Xiaodong Wang, Changxiu Li, Chunming Ding
  • Publication number: 20050209097
    Abstract: The present invention provides a process for preparing particles of magnesium halide/alcohol adduct, said process comprising: preparing a melt of magnesium halide/alcohol adduct in an inert liquid medium, dispersing the mixture of the inert liquid medium and the melt of the magnesium halide/alcohol adduct by high-speed rotation under a high-gravity field to obtain a dispersion of magnesium halide/alcohol adduct melt; and the cooling the dispersion of the melt to form the particles of magnesium halide/alcohol adduct. The present invention further relates to the particles of magnesium halide/alcohol adduct prepared by the process of the present invention and the use thereof in the preparation of catalysts for olefin polymerization.
    Type: Application
    Filed: August 6, 2004
    Publication date: September 22, 2005
    Inventors: Yuanyi Yang, Zhenhu Li, Hongbin Du, Zhiwu Wang, Zhong Tan, Tianyi Li, Qi Chen, Wei Chen
  • Publication number: 20050096389
    Abstract: The present application relates to polyol ester compounds, having general formula (I): R1CO—O—CR3R4-A-CR5R6—O—CO—R2 (I) wherein, R, and R2 groups, which may be identical or different, can be substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R3-R6 groups, which may be identical or different, can be selected from the group consisting of hydrogen, halogen or substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R1-R6 groups optionally contain one or more hetero-atoms replacing carbon, hydrogen atom or the both, said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom, two or more of R3-R6 groups can be linked to form saturated or unsaturated monocyclic or polycyclic ring; A is a single bond or bivalent linking group with chain length between two free radicals being 1-10 atoms, wherein said bivalent linking group is selected from the group consisting of aliphatic, alicyclic and aromatic bivalent radicals, and can c
    Type: Application
    Filed: January 30, 2003
    Publication date: May 5, 2005
    Applicant: CHINA PETROLEUM & CHEMICAL
    Inventors: Mingzhi Gao, Jun Wang, Changxiu Li, Jiyu Li, Tianyi Li, Xianzhong Li, Jing Ma, Lingyan Xing, Haitao Liu
  • Patent number: 6822109
    Abstract: The present invention relates to a silicon ether compound having general formula (I): wherein, R and R1-R10 groups, which may be Identical or different, represent hydrogen, halogen, C1-C20 linear or branched alkyl, C3-C20 cycloalkyl, C8-C20 aryl, C7-C20 alkaryl or C7-C20 aralkyl group, and two or more R groups can be linked to form saturated or unsaturated condensed ring structure which is optionally substituted by a group having the same meanings with that of R1, R and R1-R10 groups optionally contain one or more hetero-atoms replacing carbon atom, hydrogen atom or the both, said heteroatom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom, and A represents carbon atom or silicon atom. The present invention also relates to a method for the preparation of the silicon ether compounds of general formula (I) and a process for polymerization of olefins.
    Type: Grant
    Filed: July 16, 2003
    Date of Patent: November 23, 2004
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Lunjia Xie, Mingzhi Gao, Tianyi Li, Siyuan Zhao, Mingsen Zhang, Changjiang Wu
  • Publication number: 20040106814
    Abstract: The present invention relates to a silicon ether compound having general formula (I): 1
    Type: Application
    Filed: July 16, 2003
    Publication date: June 3, 2004
    Inventors: Lunjia Xie, Mingzhi Gao, Tianyi Li, Siyuan Zhao, Mingsen Zhang, Changjiang Wu
  • Publication number: 20040030064
    Abstract: The present invention provides a catalyst component used for homopolymerization or co-polymerization of ethylene, comprising at least one suitable electron donor compound supported on a composition containing magnesium and titanium, wherein the electron donor compound is selected from the group consisting of aliphatic ethers, alicyclic ethers, aromatic ethers, aliphatic ketones and alicyclic ketones, and wherein the composition containing magnesium and titanium is prepared by dissolving a magnesium compound into a solvent system to form a homogeneous solution and then contacting the solution with a titanium compound in the presence of a precipitation aid to precipitate the composition. The present invention also relates to a method for the preparation of said catalyst component and a catalyst comprising thereof, and to use of the catalyst in homopolymerization of ethylene or co-polymerization of ethylene with at least one C3-C8 &agr;-olefln.
    Type: Application
    Filed: June 5, 2003
    Publication date: February 12, 2004
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY
    Inventors: Zhiwu Wang, Zhong Tan, Tianyi Li, Xingbo Li, Kai Zhang, Peng Kou, Haixiang Cui, Zhengyang Guo, Liang Pan