Abstract: The present invention relates to a solid solution comprising (a) at least one compound according to formula (I), and (b) at least one compound according to formula (II), or at least one compound according to formula (III), or a mixture of at least one compound according to formula (II) and at least one compound according to formula (III), wherein R1 and R2 may, independently of one another, stand for —(CH2)n—X, wherein X stands for hydrogen, methyl, a C1-C5 alkoxyl, hydroxy, phenyl, C1-C5 alkylphenyl, C1-C5 alkoxyphenyl, hydroxyphenyl, halogenated phenyl, pyridyl, C1-C5 alkylpyridyl, C1-C5 alkoxypyridyl, halogenated pyridyl, pyridylvinyl or naphthyl; wherein n stands for 0, 1, 2, 3, 4 or 5; R3 and R4 may, independently of one another, stand for phenylene, C1-C5 alkylphenylene, C1-C5 alkoxyphenylene, hydroxyphenylene, halogenated phenylene, pyridinediyl, C1-C5 alkylpyridinediyl, C1-C5 alkoxy-pyridinediyl, halogenated pyridinediyl, anthraquinonediyl or naphthalenediyl, wherein the 2 nitrogen atoms bound to R3 a

Abstract: The present invention relates to a solid solution comprising (a) at least one compound according to formula (I) and (b) at least one compound according to formula (II), or at least one compound according to formula (III), or a mixture of at least one compound according to formula (II) and at least one compound according to formula (III) wherein R1 and R2 may, independently of one another, stand for —(CH2)n—X, wherein X stands for hydrogen, methyl, a C1-C5 alkoxyl, hydroxy, phenyl, C1-C5 alkylphenyl, C1-C5 alkoxyphenyl, hydroxyphenyl, halogenated phenyl, pyridyl, C1-C5 alkylpyridyl, C1-C5 alkoxypyridyl, halogenated pyridyl, pyridylvinyl or naphthyl; wherein n stands for 0, 1, 2, 3, 4 or 5; R3 and R4 may, independently of one another, stand for phenylene, C1-C5 alkylphenylene, C1-C5 alkoxyphenylene, hydroxyphenylene, halogenated phenylene, pyridinediyl, C1-C5 alkylpyridinediyl, C1-C5 alkoxy-pyridinediyl, halogenated pyridinediyl, anthraquinonediyl or naphthalenediyl, wherein the 2 nitrogen atoms bound to R4 acc

Abstract: The invention relates to a method for producing aryl or heteroaryl amines, ethers or thioethers (III) by cross-coupling primary or secondary amities, alcohols or thioalcohols with substituted aryl or heteroaryl compounds (I) in the presence of a Brønsted base and a catalyst or a pre-catalyst containing a) a transition metal, a complex, a salt, or a compound of a transition metal from the group V, Mn, Fe, Co, Ni, Rh, Pd, Ir, Pt, and b) at least one sulfonated phosphane ligand in a solvent or a solvent mixture corresponding to Scheme 1 wherein Hal represents fluorine, chlorine, bromine, iodine, alkoxy, trifluoromethane sulfonate, nonafluorotrimethyl-methane sulfonate, methane sulfonate, 4-nitrobenzene sulfonate, benzene sulfonate, 2-naphthalene sulfonate, 3-nitrobenzene sulfonate, 4-nitrobenzene sulfonate, 4-chlorobenzene sulfonate, 2,4,6-triisopropylbenzene sulfonate or any other sulfonate, and X represents O, S or NR?. The invention also relates to novel phosphane ligands.

Abstract: Process for preparing compounds by cross-coupling of enolizable carbonyl compounds, nitriles or their analogues with substituted aryl or heteroaryl compounds in the presence of a Brönsted base and of a catalyst or precatalyst containing a.) a transition metal, a complex, a salt or a compound of this transition metal from the group V, Mn, Fe, Co, Ni, Rh, Pd, Ir, Pt) and b.) at least one sulphonated phosphane ligand in a solvent or solvent mixture.