Abstract: Aspects of the present disclosure provide a system for a carbon oxide electrolysis plant incorporating advanced electrochemical reactors incorporating membrane electrode assemblies as well as control mechanisms. The system provides efficient transport and production rates while minimizing the competing hydrogen formation reaction. The system may use multiple electrochemical reactors, scaling up production with high energy efficiency, while providing flexibility in the types of chemical product outputs.

Abstract: Provided herein are methods for operating carbon oxide (COx) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: Various COx electrolyzer multi-cell architectures are provided, including various frame, flow field, gas diffusion layer, and repeat unit designs that may be particularly useful in the context of multi-cell COx electrolyzer cells.

Abstract: Provided herein are methods for operating carbon oxide (COx) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: A method of forming a gas diffusion layer includes causing, at least in part, a stack of layers to be arranged between compressing surfaces of a press, the stack of layers including a plurality of gas diffusion layers. The method also includes causing, at least in part, the press to apply one or more compression cycles to the stack of layers to reduce a combined, uncompressed thickness of the plurality of gas diffusion layers between about 2% and about 30%.

Abstract: Provided herein are methods for operating carbon oxide (COX) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: Methods and/or systems for operating a carbon oxide reduction electrolyzer may involve (a) performing normal operation at the electrolyzer; (b) performing a recovery or protection process including: (i) applying a modified current and/or voltage to the electrolyzer, and (ii) while applying the reverse current to the electrolyzer, flowing a recovery gas to the cathode; and (c) resuming normal operation at the electrolyzer. Applying a modified current and/or voltage may involve applying a short circuit to the electrolyzer, holding the electrolyzer electrodes at open circuit voltage, and/or applying a reverse current to the electrolyzer.

Abstract: Provided herein are methods for operating carbon oxide (COx) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: Various COx electrolyzer cell architectures are provided, including various flow field designs and gas diffusion layer designs that may be particularly useful in the context of COx electrolyzer cells.

Abstract: A system optionally including a carbon oxide reactor. A method for carbon oxide reactor control, optionally including selecting carbon oxide reactor aspects based on a desired output composition, running a carbon oxide reactor under controlled process conditions to produce a desired output composition, and/or altering the process conditions to alter the output composition.

Abstract: A system optionally including a carbon oxide reactor. A method for carbon oxide reactor control, optionally including selecting carbon oxide reactor aspects based on a desired output composition, running a carbon oxide reactor under controlled process conditions to produce a desired output composition, and/or altering the process conditions to alter the output composition.

Abstract: Provided herein are methods for operating carbon oxide (COx) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: Metal-halogen flow battery cell, stack, system, and method, the stack including flow battery cells that each include an impermeable first electrode, an insert disposed on the first electrode and comprising sloped channels, a cell frame disposed around the insert and including a cell inlet manifold configured to provide a metal halide electrolyte and an opposing cell outlet manifold configured to receive the electrolyte, a porous second electrode disposed on the insert, such that sloped separation zones are formed between the second electrode and the channels, conductive connectors electrically connecting the first and second electrodes, and ribs disposed on the second electrode and extending substantially parallel to the channels of the insert. A depth of the channels increases as proximity to the cell outlet manifold increases.

Abstract: Metal-halogen flow battery cell, stack, system, and method, the stack including flow battery cells that each include an impermeable first electrode, an insert disposed on the first electrode and comprising sloped channels, a cell frame disposed around the insert and including a cell inlet manifold configured to provide a metal halide electrolyte and an opposing cell outlet manifold configured to receive the electrolyte, a porous second electrode disposed on the insert, such that sloped separation zones are formed between the second electrode and the channels, conductive connectors electrically connecting the first and second electrodes, and ribs disposed on the second electrode and extending substantially parallel to the channels of the insert. A depth of the channels increases as proximity to the cell outlet manifold increases.

Abstract: Systems, methods, and devices of the various embodiments provide a hardware and software architecture enabling electrochemical impedance spectroscopy (“EIS”) to be performed on multiple electrochemical devices, such as fuel cells, at the same time without human interaction with the electrochemical devices. In an embodiment, a matrix switch may connect each cell of a fuel cell stack individually to an EIS analyzer enabling EIS to be performed on any fuel cell in the fuel cell stack. In a further embodiment, the EIS analyzer may be a multi-channel EIS analyzer, and the combination of the matrix switch and multi-channel EIS analyzer may enable EIS to be performed on multiple fuel cells simultaneously.

Abstract: Systems, methods, and devices of the various embodiments provide a hardware and software architecture enabling electrochemical impedance spectroscopy (“EIS”) to be performed on multiple electrochemical devices, such as fuel cells, at the same time without human interaction with the electrochemical devices. In an embodiment, a matrix switch may connect each cell of a fuel cell stack individually to an EIS analyzer enabling EIS to be performed on any fuel cell in the fuel cell stack.

Abstract: A fuel cell power plant (10) includes a fuel cell (12) having a membrane electrode assembly (MEA) (16), disposed between an anode support plate (14) and a cathode support plate (18), the anode and/or cathode support plates include a hydrophilic substrate layer (80, 82) having a predetermined pore size. The pressure of the reactant gas streams (22, 24) is greater than the pressure of the coolant stream (26), such that a greater percentage of the pores within the hydrophilic substrate layer contain reactant gas rather than water. Any water that forms on the cathode side of the MEA will migrate through the cathode support plate and away from the MEA. Controlling the pressure also ensures that the coolant water will continually migrate from the coolant stream toward the anode side of the MEA, thereby preventing the membrane from becoming dry. Proper pore size and a pressure differential between coolant and reactants improves the electrical efficiency of the fuel cell.

Abstract: A fuel cell power plant (10) includes a fuel cell (12) having a membrane electrode assembly (MEA) (16), disposed between an anode support plate (14) and a cathode support plate (18), the anode and/or cathode support plates include a hydrophilic substrate layer (80, 82) having a predetermined pore size. The pressure of the reactant gas streams (22, 24) is greater than the pressure of the coolant stream (26), such that a greater percentage of the pores within the hydrophilic substrate layer contain reactant gas rather than water. Any water that forms on the cathode side of the MEA will migrate through the cathode support plate and away from the MEA. Controlling the pressure also ensures that the coolant water will continually migrate from the coolant stream toward the anode side of the MEA, thereby preventing the membrane from becoming dry. Proper pore size and a pressure differential between coolant and reactants improves the electrical efficiency of the fuel cell.

Abstract: A fuel cell power plant includes a fuel cell having a membrane electrode assembly (MEA), disposed between an anode support plate and a cathode support plate, the anode and/or cathode support plates include a hydrophilic substrate layer having a predetermined pore size. The pressure of the reactant gas streams is greater than the pressure of the coolant stream, such that a greater percentage of the pores within the hydrophilic substrate layer contain reactant gas rather than water. Any water that forms on the cathode side of the MEA will migrate through the cathode support plate and away from the MEA. Controlling the pressure also ensures that the coolant water will continually migrate from the coolant stream toward the anode side of the MEA, thereby preventing the membrane from becoming dry. Proper pore size and a pressure differential between coolant and reactants improves the electrical efficiency of the fuel cell.

Abstract: Each cell of a fuel cell stack is provided, between the anode 37 and cathodes 38, with either (a) a permanent shunt (20) which may be a discrete resistor (42-44), a diode (95), a strip of compliant carbon cloth (65), or a small amount of conductive carbon black (22) in the ionomer polymer mixture of which the proton exchange membrane (39) is formed, or (b) a removeable shunt such as a conductor (69) which may be rotated into and out of contact with the fuel cell anodes and cathodes, or a conductor (85) which may be urged into contact by means of a shape memory alloy actuator spring (90, 91), which may be heated.