Abstract: The present invention relates to relates to a polymer formulation for three-dimensionally (3D) printing an article by stereolithography, the formulation comprising a functionalized polymer. The invention further relates to lithographic methods to form 3D objects that incorporate the aforementioned polymer formulation.

Abstract: The present invention relates to poly(amide imide) (PAI) precursor polymers which can for example be used in Vat photopolymerization processes like lithographic processes for the photofabrication of three-dimensional (3D) articles. The invention further relates to polymer compositions including these poly(amide imide) (PAI) precursor polymers. Still further, the invention relates to vat photopolymerization methods to form three-dimensional (3D) objects that incorporate the aforementioned polymer compositions.

Abstract: The present invention relates to relates to a polymer formulation for three-dimensionally (3D) printing an article by stereolithography, the formulation comprising a functionalized polymer. The invention further relates to lithographic methods to form 3D objects that incorporate the aforementioned polymer formulation.

Abstract: A polyimide oligomer of formula (1a), (1b), a copolymer thereof, or a combination thereof wherein each G1 is independently the same or different, and is a cation group; each G2 is independently the same or different, and is an anion group; each D is independently the same or different, and is a single bond or C1-20 divalent hydrocarbon group; each V is independently the same or different, and is a tetravalent C4-40 hydrocarbon group; each R is independently the same or different, and is a C1-20 divalent hydrocarbon group; each n is independently the same or different, and is 1 to 1000, provided that the total of all values of n is greater than 4; and t is 2 to 1000.

Abstract: A polyimide composition includes 1 to 99 weight percent, preferably 70 to 99 weight percent, more preferably 75 to 95 weight percent of a first polyimide; and 1 to 99 weight percent, preferably 1 to 30 weight percent, more preferably 2 to 25 weight percent of a second polyimide, wherein the first polyimide and the second polyimide are different, and wherein the polyimide composition has a melt flow rate that is greater than a melt flow rate of the first polyimide and less than a melt flow rate of the second polyimide; an apparent viscosity that is less than an apparent viscosity of the first polyimide and less than an apparent viscosity of the second polyimide; and a notched Izod impact strength that is greater than a notched Izod impact strength of the first polyimide and greater than a notched Izod impact strength of the second polyimide.

Abstract: The present invention relates to relates to a polymer formulation for three-dimensionally (3D) printing an article by stereolithography, the formulation comprising a functionalized polymer. The invention further relates to lithographic methods to form 3D objects that incorporate the aforementioned polymer formulation.

Abstract: A polyimide oligomer of the formula wherein G is a group having a valence of t and is connected by a covalent bond or an ionic bond, each Q is independently the same or different, and is a cation or a substituted or unsubstituted divalent C1-60 hydrocarbon group, each M is independently the same or different, and is a substituted or unsubstituted divalent C1-60 hydrocarbon group, —O—, —C(O)—, —OC(O)—, —OC(O)O—, —NHC(O)—, —(O)CNH—, —S—, —S(O)—, or —S(O)2—, D is a phenylene, each V is independently the same or different, and is a tetravalent C4-40 hydrocarbon group, each R is independently the same or different, and is a C1-20 divalent bridging group, a C1-20 alkylene-XA, or a C6-30 arylene-XA wherein XA is a cation-anion complex, provided that at least one R is C1-20 alkylene-XA or C6-30 arylene-XA, q, m, d, p, t, and n are as provided herein.

Abstract: A polyimide oligomer of formula (1a), (1b), a copolymer thereof, or a combination thereof wherein each G1 is independently the same or different, and is a cation group; each G2 is independently the same or different, and is an anion group; each D is independently the same or different, and is a single bond or C1-20 divalent hydrocarbon group; each V is independently the same or different, and is a tetravalent C4-40 hydrocarbon group; each R is independently the same or different, and is a C1-20 divalent hydrocarbon group; each n is independently the same or different, and is 1 to 1000, provided that the total of all values of n is greater than 4; and t is 2 to 1000.

Abstract: A ureido-pyrimidinone oligomer having the formula (I) wherein each Z? is independently the same or different, and is a substituted or unsubstituted straight or branched chain C1-10 alkyl, each R1 is independently the same or different, and is a substituted or unsubstituted straight or branched chain C1-20 alkylene, substituted or unsubstituted C2-20 alkenylene, substituted or unsubstituted C3-8 cycloalkylene, or substituted or unsubstituted C6-18 arylene, each V is independently the same or different, and is a substituted or unsubstituted tetravalent C4-40 hydrocarbon group, each R is independently the same or different, and is a substituted or unsubstituted C1-24 divalent hydrocarbon group; and n has an average value of 2 to 50, preferably 3 to 40, more preferably 5 to 30.

Abstract: A branched polyimide of the formula (I) wherein G is a group having a valence of t present in an amount 0.01 to 20 mol %, each Q is independently the same or different, and is a divalent C1-60 hydrocarbon group, each M is independently the same or different, and is —O—, —C(O)—, —OC(O)—, —OC(O)O—, —NHC(O), —(O)CNH—, —S—, —S(O)—, or —S(O)2—, D is a phenylene, each V is independently the same or different, and is a tetravalent C4-40 hydrocarbon group, each R is independently the same or different, and is a C1-20 divalent hydrocarbon group, q is 0 or 1, m is 0 or 1, d is 0 or 1, p is 1 or 2, t is 2 to 6, and each n is independently the same or different, and is 1 to 1,000, provided that the total of all values of n is greater than 4.

Abstract: A polyimide oligomer of the formula wherein G is a group having a valence of t, each R is independently a C1-30 divalent bridging group, a C1-20 alkylene-X, or a C6-30 arylene-X wherein —X is —O-M?, —C(O)O-M?, —OC(O)O-M?, —S-M?, —S(O)2-M?, —S(O)3-M?, —OS(O)3-M?, or —OP(O)3-M? wherein each M? is independently Li, Na, K, Cs, Mg, Ca, Sr, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, B, Al, Ga, In, Ge, Sn, Pb, As, or Sb, provided that at least one R is C1-20 alkylene-X or C6-30 arylene-X, q is 0 or 1, m is 0 or 1, d is 0 or 1, p is 1 or 2, t is 1 to 6, and each n is independently 1 to 1,000, the total of all values of n is greater than 4, the polyimide oligomer is thermoplastic, and Q, M, D, and V are as provided herein.

Abstract: A polyimide composition includes 1 to 99 weight percent, preferably 70 to 99 weight percent, more preferably 75 to 95 weight percent of a first polyimide; and 1 to 99 weight percent, preferably 1 to 30 weight percent, more preferably 2 to 25 weight percent of a second polyimide, wherein the first polyimide and the second polyimide are different, and wherein the polyimide composition has a melt flow rate that is greater than a melt flow rate of the first polyimide and less than a melt flow rate of the second polyimide; an apparent viscosity that is less than an apparent viscosity of the first polyimide and less than an apparent viscosity of the second polyimide; and a notched Izod impact strength that is greater than a notched Izod impact strength of the first polyimide and greater than a notched Izod impact strength of the second polyimide.

Abstract: A ureido-pyrimidinone oligomer having the formula (I) wherein each Z? is independently the same or different, and is a substituted or unsubstituted straight or branched chain C1-10 alkyl, each R1 is independently the same or different, and is a substituted or unsubstituted straight or branched chain C1-20 alkylene, substituted or unsubstituted C2-20 alkenylene, substituted or unsubstituted C3-8 cycloalkylene, or substituted or unsubstituted C6-18 arylene, each V is independently the same or different, and is a substituted or unsubstituted tetravalent C4-40 hydrocarbon group, each R is independently the same or different, and is a substituted or unsubstituted C1-24 divalent hydrocarbon group; and n has an average value of 2 to 50, preferably 3 to 40, more preferably 5 to 30.

Abstract: A polyimide oligomer of the formula wherein G is a group having a valence of t, each R is independently a C1-30 divalent bridging group, a C1-20 alkylene-X, or a C6-30 arylene-X wherein —X is —O-M?, —C(O)O-M?, —OC(O)O-M?, —S-M?, —S(O)2-M?, —S(O)3-M?, —OS(O)3-M?, or —OP(O)3-M? wherein each M? is independently Li, Na, K, Cs, Mg, Ca, Sr, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, B, Al, Ga, In, Ge, Sn, Pb, As, or Sb, provided that at least one R is C1-20 alkylene-X or C6-30 arylene-X, q is 0 or 1, m is 0 or 1, d is 0 or 1, p is 1 or 2, t is 1 to 6, and each n is independently 1 to 1,000, the total of all values of n is greater than 4, the polyimide oligomer is thermoplastic, and Q, M, D, and V are as provided herein.

Abstract: Embodiments of this disclosure, among others, encompass methods for generating alkenes under mild thermolytic conditions that can provide almost total conversion of a precursor compound to an alkene without isomerization or the need to chromatographically purify the final product By selectively blocking the amino and carboxy groups of the derivatized amino acid, the methods of the disclosure provide for the synthesis of a peptide having the vinylglycine moiety at either the carboxy or the amino terminus of the peptide The mild conditions for the thermolytic removal of an o-NO2-phenyl substituted aryl group ensure that there is minimal if any damage to thermally sensitive conjugates such as a peptide bearing the vinylglycine The methods of the present disclosure have practical applications for the preparation of unsaturated compounds under mild, thermolytic conditions.

Abstract: Embodiments of this disclosure, among others, encompass methods for generating alkenes under mild thermolytic conditions that can provide almost total conversion of a precursor compound to an alkene without isomerization or the need to chromatographically purify the final product By selectively blocking the amino and carboxy groups of the de?vatized amino acid, the methods of the disclosure provide for the synthesis of a peptide having the vinylglycine moiety at either the carboxy or the amino terminus of the peptide The mild conditions for the thermolytic removal of an o-NO2-phenyl substituted aryl group ensure that there is minimal if any damage to thermally sensitive conjugates such as a peptide bearing the vinylglycine The methods of the present disclosure have practical applications for the preparation of unsaturated compounds under mild, thermolytic conditions.

Abstract: Disclosed is a select class of liquid crystalline polyesters and molding compositions comprising the polyesters and glass fiber. The liquid crystalline polyesters consist essentially of (1) diacid residues consisting essentially of (i) cyclohexanedicarboxylic acid residues and (ii) other diacid residues selected from terephthalic acid residues, 2,6-naphthalene-dicarboxylic acid residues, or a mixture thereof; (2) diol residues consisting essentially of hydroquinone residues, 4,4′-biphenol residues or a mixture thereof; and, optionally, (3) p-hydroxybenzoic acid residues. In the above definition, the moles of diol residues are equal to the moles of diacid residues and the total of the (1), (2) and (3) mole percentages is equal to 100. The liquid crystalline polyesters have melting points determined by differential scanning calorimetry equal to or less than 360° C.

Abstract: Disclosed are novel compositions containing an LCP and one or more aromatic phosphonites. Also disclosed is a novel process for preparing LCPs in the presence of one or more aromatic phosphonites. The process enables the preparation of LCPs in a more controlled manner so that the LCPs have excellent thermal/oxidative stability. The LCPs are useful where the combination of good mechanical properties, excellent thermal resistance properties, and excellent thermal stability are desired, such as in electrical/electronic applications and electrical connectors.

Abstract: To increase the melt strength and increase high shear thinning of a polyester composition, a polar chain terminator that contains a nonionic group or an ionic group neutralized with a counterion is added at a level of 0.05 to 20 mole percent. Optionally, up to 2.0 mole percent of a tri-functional or greater branching agent is added to the polyester composition. Optionally, up to 30 mole percent of a polar midchain difunctional monomer that contains a nonionic group or an ionic group neutralized with a counterion is added. The polyester composition is based on 100 mole percent diacid component and 100 mole percent glycol component.

Abstract: Disclosed is a select class of liquid crystalline polyesters and molding compositions comprising the polyesters and glass fiber. The liquid crystalline polyesters consist essentially of (1) diacid residues consisting essentially of (i) cyclohexanedicarboxylic acid residues and (ii) other diacid residues selected from terephthalic acid residues, 2,6-naphthalenedicarboxylic acid residues, or a mixture thereof; (2) diol residues consisting essentially of hydroquinone residues, 4,4′-biphenol residues or a mixture thereof; and, optionally, (3) p-hydroxybenzoic acid residues. In the above definition, the moles of diol residues are equal to the moles of diacid residues and the total of the (1), (2) and (3) mole percentages is equal to 100. The liquid crystalline polyesters have melting points determined by differential scanning calorimetry equal to or less than 360° C.