Patents by Inventor Timothy J. Bunning

Timothy J. Bunning has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10955600
    Abstract: A spectrally-selective reflective optical film comprises at least two anisotropic layers, each of the layers having a phase retardation value and an optical axis orientation pattern within the layer; the optical axis orientation patterns exhibiting a discontinuity at the boundary of the at least two layers; and at least one substrate holding the film. At least a part of the anisotropic layers may be chiral. The materials comprising the anisotropic layers may be selected from liquid crystal polymers, azobenzene liquid crystal polymers, liquid crystals, azobenzene liquid crystals, polymer films with stressed birefringence, and combinations thereof. The materials comprising the anisotropic layers may be doped with at least one dopant from the list comprising nanorods, photorefractive nanoparticles, photovoltaic nanoparticles, lasing dyes, and combinations of thereof. The anisotropic layers may be transparent to infrared wavelengths.
    Type: Grant
    Filed: June 7, 2018
    Date of Patent: March 23, 2021
    Assignee: United States of America as represented by the Secretary of the Air Force
    Inventors: Dean R Evans, Ighodalo U Idehenre, Nelson V Tabiryan, Timothy J Bunning
  • Publication number: 20190072807
    Abstract: A dynamic self-organized helical superstructure device includes a chiral material and a liquid crystal material disposed between first and second substrates. The helical superstructure is reversibly switchable upon the application of at least one external stimulus from one state to another state among three states: a standing helix, a uniform lying helix, and an in-plane rotation state.
    Type: Application
    Filed: March 6, 2017
    Publication date: March 7, 2019
    Applicants: Kent State University, Government of the United States as Represented by the Secretary of the Air Force
    Inventors: Quan Li, Timothy J. Bunning, Zhi-gang Zheng, Yannian LIi, Hari Krishna Bisoyi, Ling Wang
  • Patent number: 7420733
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octancic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains.
    Type: Grant
    Filed: February 22, 2007
    Date of Patent: September 2, 2008
    Assignee: Science Applications International Corporation
    Inventors: Lalgudi V. Natarajan, Richard L. Sutherland, Vince P. Tondiglia, Timothy J. Bunning, Bob Epling, Donna M. Brandelik
  • Patent number: 7416818
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: August 26, 2008
    Assignee: Science Applications International Corporation
    Inventors: Richard L. Sutherland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 7413678
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains.
    Type: Grant
    Filed: April 3, 2006
    Date of Patent: August 19, 2008
    Assignee: Science Applications International Corporation
    Inventors: Lalgudi V. Natarajan, Richard L. Sutherland, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 7198737
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. A method for preparing a switchable grating can comprise the steps of placing a mixture between a first and second slide, wherein the mixture has a photopolymerizable monomer, a second phase material, a photoinitiator dye, and a chain extender or cross-linker. The mixture is exposed to a laser and optical intensity pattern is applied to induce photopolymerization. A method for recording slanted reflection gratings can comprise the steps of placing a sample between a first and second glass prism, the sample comprising a polymerizable monomer, a liquid crystal, a chain-extending monomer, a coinitiator, and a photoinitiator. An incident light is split into two beams, wherein the beams enter the sample from opposite sides. The first and second prism are rotated to adjust the slant of the grating.
    Type: Grant
    Filed: January 27, 2006
    Date of Patent: April 3, 2007
    Assignee: Science Applications International Corporation
    Inventors: Lalgudi V. Natarajan, Richard L. Sutherland, Vince P. Tondiglia, Timothy J. Bunning, Bob Epling, Donna M. Brandelik
  • Patent number: 7081215
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octancic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: August 12, 2004
    Date of Patent: July 25, 2006
    Assignee: Science Applications International Corporation
    Inventors: Lalgudi V. Natarajan, Richard L. Sutherland, Vince P. Tondiglia, Timothy J. Bunning, Bob Epling, Donna M. Brandelik
  • Patent number: 7077984
    Abstract: A method for preparing electro-optical polymer-liquid crystal photonic crystals, comprising: disposing between at least two optically transparent electrode plates, a polymer-dispersed liquid crystal material that comprises, before exposure: (a) a polymerizable monomer comprising at least one acrylate; (b) a liquid crystal; (c) a chain-extending monomer; (d) a coinitiator; (e) a photoinitiator; and (f) a long chain aliphatic acid; and exposing this polymer-dispersed liquid crystal material to light in an interference pattern.
    Type: Grant
    Filed: September 6, 2002
    Date of Patent: July 18, 2006
    Assignee: Science Applications International Corporation
    Inventors: Lalgudi V. Natarajan, Richard L. Sutherland, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 7018686
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: March 28, 2006
    Assignee: Science Applications International Corporation
    Inventors: Richard L. Sutehrland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 6878494
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: December 24, 2003
    Date of Patent: April 12, 2005
    Assignee: Science Applications International Corporation
    Inventors: Richard L. Sutehrland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 6821457
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octancic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: July 29, 1999
    Date of Patent: November 23, 2004
    Assignee: Science Applications International Corporation
    Inventors: Lalgudi V. Natarajan, Richard L. Sutherland, Vince P. Tondiglia, Timothy J. Bunning, Bob Epling, Donna M. Brandelik
  • Publication number: 20040137204
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Application
    Filed: December 24, 2003
    Publication date: July 15, 2004
    Inventors: Richard L. Sutehrland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Publication number: 20040089842
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Application
    Filed: October 24, 2003
    Publication date: May 13, 2004
    Inventors: Richard L. Sutehrland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Publication number: 20040091787
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Application
    Filed: October 24, 2003
    Publication date: May 13, 2004
    Inventors: Richard L. Sutehrland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 6706451
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: March 2, 1998
    Date of Patent: March 16, 2004
    Assignee: Science Applications International Corporation
    Inventors: Richard L. Sutherland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 6699407
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between early 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: March 2, 1998
    Date of Patent: March 2, 2004
    Assignee: Science Applications International Corporation
    Inventors: Richard L. Sutehrland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 6692666
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made is with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: July 2, 1999
    Date of Patent: February 17, 2004
    Assignee: Science Applications International Corporation
    Inventors: Richard L. Sutherland, Lalqudi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning, W. Wade Adams
  • Patent number: 6677086
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: March 2, 1998
    Date of Patent: January 13, 2004
    Assignee: Science Applications International Corporation
    Inventors: Richard L. Sutehrland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Patent number: 6667134
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside, the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Grant
    Filed: October 29, 1999
    Date of Patent: December 23, 2003
    Assignee: Science Applications International Corporation
    Inventors: Richard L. Sutehrland, Lalquidi V. Natarajan, Vince P. Tondiglia, Timothy J. Bunning
  • Publication number: 20030197157
    Abstract: A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.
    Type: Application
    Filed: July 2, 1999
    Publication date: October 23, 2003
    Inventors: RICHARD L. SUTHERLAND, LALQUDI V. NATARAJAN, VINCE P. TONDIGLIA, TIMOTHY J. BUNNING, W. WADE ADAMS