Abstract: Described are compounds of the structure R4-a—Si-((Sp-Y)—Zb)a, wherein “a” is an integer from 1 to 3; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”=0, is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl, C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl, or wherein each “R” is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl or C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C1-15 linear or branched alkylenyl or C1-15 linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Abstract: Described are compounds of the structure R4-a—Si-(Sp-Y)a—Zb, wherein “a” is an integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”=0, is “R” or wherein each “R” is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl or C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C1-15 linear or branched alkylenyl or C1-15 linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Abstract: Described are electrolyte compositions and electrochemical devices containing the electrolyte compositions. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250° C.

Abstract: Described are compounds of the structure R4-a—Si-(Sp-Y)a—Zb, wherein “a” is an integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”=0, is “R” or wherein each “R” is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl or C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C1-15 linear or branched alkylenyl or C1-15 linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Abstract: Described are compounds of the structure R4-a—Si-(Sp-Y)a—Zb, wherein “a” is integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b “R” or formula (II), wherein each “R” is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl or C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C1-15 linear or branched alkylenyl or CMS linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Abstract: Described are electrolyte compositions and electrochemical devices containing the electrolyte compositions. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250° C.

Abstract: Described are electrolyte compositions and electrochemical devices containing the electrolyte compositions. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250° C.

Abstract: Described are compounds of the structure R4—a—Si—(Sp-Y)a—Zb, wherein “a” is integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”“R” or formula (II), wherein each “R” is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl or C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C1-15 linear or branched alkylenyl or CMS linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Abstract: Described are electrolyte compositions and electrochemical devices containing the electrolyte compositions. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250° C.

Abstract: Described are electrolyte compositions and electrochemical devices containing them. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250 C. An electrolyte composition comprising, in combination: an organosilicon compound and an imide salt and optionally UPF6; wherein when subjected to cyclic voltammetry at a plurality of cycles ranging from about 3V to about 5V and using a cathode current collector comprising aluminum versus Li/Lit electrodes the composition exhibits an oxidative corrosion current of about 0.10 mA/cm2 or less for a second and subsequent cycles.

Abstract: Described are electrolyte compositions and electrochemical devices containing them. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250 C. An electrolyte composition comprising, in combination: an organosilicon compound and an imide salt and optionally UPF6; wherein when subjected to cyclic voltammetry at a plurality of cycles ranging from about 3V to about 5V and using a cathode current collector comprising aluminum versus Li/Lit electrodes the composition exhibits an oxidative corrosion current of about 0.10 mA/cm2 or less for a second and subsequent cycles.

Abstract: Disclosed herein are lithium or lithium-ion batteries that employ an aluminum or aluminum alloy current collector protected by conductive coating in combination with electrolyte containing aluminum corrosion inhibitor and a fluorinated lithium imide or methide electrolyte which exhibit surprisingly long cycle life at high temperature.

Abstract: Disclosed herein are lithium or lithium-ion batteries that employ an aluminum or aluminum alloy current collector protected by conductive coating in combination with electrolyte containing aluminum corrosion inhibitor and a fluorinated lithium imide or methide electrolyte which exhibit surprisingly long cycle life at high temperature.

Abstract: Disclosed herein are lithium or lithium-ion batteries that employ an aluminum or aluminum alloy current collector protected by conductive coating in combination with electrolyte containing aluminum corrosion inhibitor and a fluorinated lithium imide or methide electrolyte which exhibit surprisingly long cycle life at high temperature.

Abstract: Disclosed herein are lithium or lithium-ion batteries that employ an aluminum or aluminum alloy current collector protected by conductive coating in combination with electrolyte containing aluminum corrosion inhibitor and a fluorinated lithium imide or methide electrolyte which exhibit surprisingly long cycle life at high temperature.