Patents by Inventor Tobias Schulz

Tobias Schulz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11965066
    Abstract: The present invention relates to a method of improving UV resistance of a vinylaro-maticmolding mass by means of compounding a thermoplastic polymer composition which comprises at least one graft copolymer with an organopolysiloxane compound and optionally further components.
    Type: Grant
    Filed: June 11, 2019
    Date of Patent: April 23, 2024
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Christian Ruthard
  • Patent number: 11958009
    Abstract: A filter device for ambient air filtration has a blower housing with air inlet and air outlet. A device for generating an air flow is arranged in the blower housing and generates an air flow in operation from air inlet to air outlet. A flexible air conducting hose is provided with a first open end connected to the air outlet of the blower housing and with a second closed end. The flexible air conducting hose has openings arranged between first open end and second closed end. Filter elements are arranged in the openings, respectively. The filter elements separate a raw side inside the air conducting hose from a clean side downstream of the filter element. The air conducting hose is inflated in operation of the device by the air flow. The flexible air conducting hose has a reduced air permeability compared to the air permeability of the filter elements.
    Type: Grant
    Filed: March 1, 2021
    Date of Patent: April 16, 2024
    Assignee: MANN+HUMMEL GmbH
    Inventors: Christoph Schulz, Tobias Warth, Marc Hittinger, Jens Gusek, Maximilian Bauch, Thilo Mueller, Anja Koronai-Bauer, Sylvain Michel Tchale, Roman Eder
  • Patent number: 11807752
    Abstract: A process for the production of a graft copolymer composition is presented, which is based on acrylonitrile-styrene-acrylate (ASA) or acrylonitrile-butadiene-styrene (ABS) graft copolymers. The graft copolymers obtained by emulsion polymerization and precipitation show improved dewatering behavior after precipitation. Based on this method ASA and ABS graft copolymers with low residual humidity can be obtained. Furthermore, the invention relates to a process for the production of a thermoplastic molding composition comprising at least one thermoplastic styrene copolymer, in particular a styrene-acrylonitrile copolymer, the graft copolymer obtained by the process, and optional further components.
    Type: Grant
    Filed: July 23, 2019
    Date of Patent: November 7, 2023
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Wolfgang Fischer
  • Patent number: 11680127
    Abstract: The present invention is directed to a process for the production of graft copolymer compositions which are based on acrylonitrile-styrene-acrylate (ASA) or acrylonitrile-butadiene-styrene (ABS) graft copolymers. The graft copolymers compositions are obtained by emulsion polymerization and afterwards precipitation, dewatering, drying and optionally cooling of the dried graft copolymer powder, wherein the graft copolymer B powder obtained is mixed with an aeration gas, preferably air and/or nitrogen, wherein the bulk density of the graft copolymer B powder is equal or less than 98.5% of the bulk density of the non-aerated graft copolymer B, during the whole aeration step. The graft copolymer powders show higher powder flowability and less tendency of caking during storage, for example in a silo.
    Type: Grant
    Filed: August 27, 2019
    Date of Patent: June 20, 2023
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Wolfgang Fischer, Ulrich Jansen, Gisbert Michels
  • Patent number: 11680161
    Abstract: The present invention relates to a process for producing a thermoplastic molding composition and articles made thereof having improved surface quality, in particular improved surface quality after exposure to warm-humid environmental conditions. The thermoplastic molding composition comprises a thermoplastic polymer A, a graft copolymer B obtained by emulsion graft polymerization and optionally a further polymer component P, as well as optional further components/additives K, wherein at least one crystallization additive C, selected from phosphate compounds having 1 to 25 phosphate units, organic acids and salts thereof, is added during or after the preparation of the graft copolymer B.
    Type: Grant
    Filed: November 12, 2018
    Date of Patent: June 20, 2023
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Nils Wittenberg, Gisbert Michels, Tobias Schulz, Wolfgang Fischer, Lena Grassberger
  • Patent number: 11667780
    Abstract: Thermoplastic polymer compositions (P) comprising at least one styrene-based polymer composition (A) comprising at least one graft copolymer (A-1), at least one organopolysiloxane compound, and optionally at least one colorant, dye or pigment, and/or at least one further additive, shows improved properties with respect to residual gloss after abrasion combined with improved melt flow characteristics while heat resistance is not affected.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: June 6, 2023
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Norbert Niessner, Janna Michaelis de Vasconcellos, Hans-Werner Schmidt, Tristan Kolb
  • Patent number: 11591462
    Abstract: The invention relates to polymer blends of a styrene copolymer A selected from the group consisting of styrene acrylonitrile copolymers (SAN), styrene acrylonitrile maleic anhydride terpolymers (SMA), styrene acrylic copolymers, acrylonitrile butadiene styrene terpolymers (ABS), acrylonitrile butadiene styrene terpolymers with polyamide (ABS/PA), and acrylonitrile styrene acrylate terpolymers (ASA); and at least one copolymer B selected from the group consisting of styrene-butadiene block copolymers (SBC) and styrene-isoprene block copolymers (SIS); wherein the mold shrinkage of the polymer blend is reduced by at least 5% compared to the mold shrinkage of the pure styrene copolymer A.A process for the preparation of the polymer blends and the uses of the polymer blends in an injection molding process are described.
    Type: Grant
    Filed: March 14, 2018
    Date of Patent: February 28, 2023
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventor: Tobias Schulz
  • Patent number: 11549008
    Abstract: Thermoplastic resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one pigment B, (c) at least one hindered amine UV light stabilizer C, and (d) optionally further polymer additives D, other than components B and C, wherein the UV stabilizing component(s) present in the thermoplastic resin are only hindered amine UV light stabilizer(s) C.
    Type: Grant
    Filed: July 3, 2018
    Date of Patent: January 10, 2023
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Felix Rattay
  • Patent number: 11525052
    Abstract: Thermoplastic styrene copolymer resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one transition metal oxide pigment B, (cl) at least one hindered amine UV light stabilizer C1, (c2) optionally at least one UV absorber C2 different from Cl, (d) optionally further polymer additives D, other than components B, C1, C2, and E, and (e) optionally one metal scavenger component E, wherein at least 99.0 wt.-% of the transition metal oxide pigment B consist of transition metal atoms and oxygen atoms.
    Type: Grant
    Filed: July 3, 2018
    Date of Patent: December 13, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Felix Rattay
  • Patent number: 11505688
    Abstract: A scratch-resistant thermoplastic polymer composition (P) comprising 88 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 5 wt.-% of at least one modified organopolysiloxane compound, and optionally at least one colorant, dye or pigment, and/or at least one further additive, provides with improved properties.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: November 22, 2022
    Inventors: Tobias Schulz, Norbert Niessner, Eike Jahnke, Hans-Werner Schmidt, Tristan Kolb
  • Patent number: 11441014
    Abstract: The present invention relates to a fibre composite material W of increased translucency and/or mechanical strength, comprising a copolymer C encompassing monomers A-1, where A-1 form covalent bonds with functional groups B-1 on the surface of fibres B embedded in the fibre composite material W, and this fibre composite material W has greater translucency and/or mechanical strength than a fibre composite material Win which the copolymer C contains no A-1. The present invention further embraces a method for producing a fibre composite material W of increased translucency and/or mechanical strength.
    Type: Grant
    Filed: January 14, 2020
    Date of Patent: September 13, 2022
    Assignee: ENSINGER GMBH
    Inventors: Norbert Niessner, Philipp Deitmerg, Eike Jahnke, Marko Blinzler, Achim Bernhardt, Tobias Schulz
  • Patent number: 11352490
    Abstract: The present invention relates to a process for producing a thermoplastic moulding composition comprising a thermoplastic copolymer A, a graft copolymer B and optionally a further polymer component C as well as optional further additives K, wherein the preparation of the graft copolymer B is carried out via emulsion polymerization, and wherein at least one surfactant S2 is used in grafting step of emulsion polymerization in a volume concentration in the range of 0.46 to 0.75 mol/m3, based on the volume of the graft copolymer B latex particles obtained; and wherein the mean particle diameter Dw of the latex particles of graft copolymer B is in the range of 60 to 800 nm.
    Type: Grant
    Filed: December 10, 2018
    Date of Patent: June 7, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Gisbert Michels
  • Patent number: 11274198
    Abstract: A scratch-resistant thermoplastic polymer composition (P) comprising 40 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 20 wt.-% of at least one inorganic metal compound nanoparticle, and optionally at least one polymeric compatibilizing agent, at least one modified polysiloxane compound, at least one colorant, dye or pigment, and/or at least one further additive has improved scratch properties.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: March 15, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Norbert Niessner, Hans-Werner Schmidt, Tristan Kolb, Sascha Ehlert, Stephan Foerster
  • Patent number: 11255386
    Abstract: A clutch actuator (1) for actuating a vehicle clutch includes a cylinder (3) filled with pressure medium. An annular piston (4) is axially displaceably arranged in the cylinder. The annular piston (4) is fixedly operatively connected to a sliding sleeve (5) slidably mounted on a guide sleeve (6). A radially inner casing surface (16) of the annular piston (4) has an inner radius (Ri) and is arranged radially next to the guide sleeve (6). A sliding ring (18; 19) supports the sliding sleeve (5) on the guide sleeve (6). The sliding ring (18; 19; 18a) is inserted into a groove (27; 28) in the radially inner casing surface (16). In order to be able to mount undivided sliding rings, the groove (27; 28) has a single radially extending groove wall (29; 32) and is open toward an axially outer or inner end face (30; 33) of the annular piston (4).
    Type: Grant
    Filed: September 10, 2018
    Date of Patent: February 22, 2022
    Assignee: WABCO GmbH
    Inventors: Frank-Peter Klück, Sankar Prasad Mishra, Tobias Schulz
  • Patent number: 11225570
    Abstract: Thermoplastic resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one pigment B, (c) at least one hindered amine UV light stabilizer C1 and at least one UV absorber C2 different from C1, and (d) optionally further polymer additives D, other than components B, C1, C2, and E, (e) at least one metal scavenger component E.
    Type: Grant
    Filed: July 3, 2018
    Date of Patent: January 18, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Felix Rattay, Bianca Wilhelmus
  • Patent number: 11225571
    Abstract: Thermoplastic polymer compositions (P) comprising 90 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 10 wt.-% of at least one copolymer at least comprising repeating units derived from at least one ?-olefin monomer and at least one vinyl-aromatic monomer, at least one inorganic phosphate compound, at least one polyolefin wax and optionally at least one colorant, dye or pigment, and/or at least one further additive show improved properties with respect to residual gloss after abrasion combined with improved melt flow characteristics while heat resistance is not affected.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: January 18, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Norbert Niessner, Eike Jahnke, Hans-Werner Schmidt, Tristan Kolb
  • Patent number: 11220594
    Abstract: Scratch-resistant thermoplastic polymer compositions (P) comprising 90 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 10 wt.-% of an aliphatic amide wax additive comprising at least one aliphatic amide wax composition having a melting point in the range of 80° C. to 115° C., and optionally at least one colorant, dye, pigment and/or further additive, have improved properties.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: January 11, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Norbert Niessner, Eike Jahnke, Hans-Werner Schmidt, Tristan Kolb
  • Publication number: 20210292459
    Abstract: Polyacrylate graft rubber copolymer B and an impact modified thermoplastic molding composition thereof, where the graft copolymer B is composed of: B1: 50 to 70 wt.-% crosslinked acrylate polymer graft base B1 B2: 30 to 50 wt.-% graft shell B2 comprising a first layer B21 of vinylaromatic monomers, and a second layer B22 of vinylaromatic monomers B21-1 and nitrile monomers B22-2; wherein the particle diameter dw of the graft base B1 is 255 to 290 nm; the fraction of B21 is 10 to 26 wt.-%; and the amount of B22-2, is 20 to 30 wt.-%.
    Type: Application
    Filed: July 22, 2019
    Publication date: September 23, 2021
    Inventors: Tobias SCHULZ, Wolfgang FISCHER, Norbert NIESSNER, Christian RUTHARD, Hannes KERSCHBAUMER
  • Publication number: 20210292460
    Abstract: Thermoplastic molding composition comprising a graft copolymer B with core-shell structure having a particle diameter dw of 280 to 450 nm, comprising a core B1 and three layers B2 to B4: B1: 6 to 19 wt.-% of a core B1 comprising crosslinked polystyrene; B2: 41 to 54 wt.-% of a first layer B2 of a crosslinked acrylate polymer; B3: 1 to 19 wt.-% of a second layer B3 of polystyrene; and B4: 21 to 39 wt.-% of a third layer B4 consisting of SAN copolymer.
    Type: Application
    Filed: July 22, 2019
    Publication date: September 23, 2021
    Inventors: Tobias SCHULZ, Wolfgang FISCHER, Norbert NIESSNER, Christian RUTHARD, Hannes KERSCHBAUMER
  • Publication number: 20210269631
    Abstract: A process for the production of a graft copolymer composition is presented, which is based on acrylonitrile-styrene-acrylate (ASA) or acrylonitrile-butadiene-styrene (ABS) graft copolymers. The graft copolymers obtained by emulsion polymerization and precipitation show improved dewatering behavior after precipitation. Based on this method ASA and ABS graft copolymers with low residual humidity can be obtained. Furthermore, the invention relates to a process for the production of a thermoplastic molding composition comprising at least one thermoplastic styrene copolymer, in particular a styrene-acrylonitrile copolymer, the graft copolymer obtained by the process, and optional further components.
    Type: Application
    Filed: July 23, 2019
    Publication date: September 2, 2021
    Inventors: Tobias SCHULZ, Wolfgang FISCHER