Abstract: This invention relates to powders of substantially spherical particles that consist essentially of at least about 10% by weight rhenium optionally alloyed with up to about 90% by weight tungsten or up to about 60% by weight molybdenum. In one embodiment, the spherical particles have an average diameter of less than about 150 microns, and more preferably, an average diameter within the range of from about 10 to about 50 microns. The powders according to the invention exhibit good flow characteristics and can be used to fabricate components having complicated shapes and configurations using conventional powder metallurgy techniques.