Abstract: Provided is a surfacing film that includes a plurality of layers. The layers include a first clear coat layer made from a crosslinked polyurethane that is a reaction product of a reactive mixture including an isocyanate and a polyol containing a styrene repeat unit and a hydroxyl-containing (meth)acrylate repeat unit. The surfacing film further includes a bulk layer made from a thermoplastic polyurethane and an adhesive layer. Optionally, the surfacing film includes second clear coat layer, which can be made from a polyurethane that is at least partially crosslinked. The resulting surfacing film can display high stain resistance, high peel strength, superior scratch resistance and self-healing properties.

Abstract: A composite cooling film (100) comprises an antisoiling layer (160) secured to a first major surface of a reflective microporous layer (110). The reflective microporous layer (110) comprises a first fluoropolymer and is diffusely reflective of electromagnetic radiation over a majority of wavelengths in the range of 400 to 2500 nanometers. The antisoiling layer (160) has an outwardly facing antisoiling surface (162) opposite the micro-voided polymer film. An article (1100) comprising the composite cooling film (1112) secured to a substrate (1110) is also disclosed.

Abstract: Anti-reflective article includes a layer defining an anti-reflective surface. The anti-reflective surface includes a series of alternating micro-peaks and micro-spaces extending along an axis. The surface also includes a series of nano-peaks extending along an axis. The nano-peaks are disposed at least on the micro-spaces and, optionally, the micro-peaks. The article may be disposed on a photovoltaic module or skylight to reduce reflections and resist the collection of dust and dirt.

Abstract: A composite cooling film (100) comprises an ultraviolet-reflective multilayer optical film (120) and a reflective microporous layer (110) secured thereto. The ultraviolet-reflective multilayer optical film (120) hat is at least 50 percent reflective of ultraviolet radiation over a majority of the wavelength range of at least 340 but less than 400 nanometers. The reflective microporous layer (110) has a continuous phase comprising a nonfluorinated organic polymer and is diffusely reflective of solar radiation over a majority the wavelength range of 400 to 2500 nanometers, inclusive. The composite cooling film (100) has an average absorbance over the wavelength range 8-13 microns of at least 0.85. An article (1200) comprising the composite cooling film (100) adhered to a substrate (1210) is also disclosed.

Abstract: A composite cooling film (100) comprises an antisoiling layer (160) secured to a first major surface of a reflective microporous layer (110). The reflective microporous layer (110) comprises a first fluoropolymer and is diffusely reflective of electromagnetic radiation over a majority of wavelengths in the range of 400 to 2500 nanometers. The antisoiling layer (160) has an outwardly facing antisoiling surface (162) opposite the micro-voided polymer film. An article (1100) comprising the composite cooling film (1112) secured to a substrate (1110) is also disclosed.

Abstract: Anti-reflective article includes a layer defining an anti-reflective surface. The anti-reflective surface includes a series of alternating micro-peaks and micro-spaces extending along an axis. The surface also includes a series of nano-peaks extending along an axis. The nano-peaks are disposed at least on the micro-spaces and, optionally, the micro-peaks. The article may be disposed on a photovoltaic module or skylight to reduce reflections and resist the collection of dust and dirt.

Abstract: Various embodiments disclosed relate to multilayer films including hidden fluorescent features. The present disclosure includes a multilayer optical film including an isotropic multilayer optical film having first and second opposed major surfaces. The isotropic multilayer optical film reflects at least 50% of a light that is at least one of ultraviolet light or visible light, having an incident angle less than a cutoff angle from normal to the first major surface of the isotropic multilayer optical film, wherein the cutoff angle is in a range from 10° to 70°. The isotropic multilayer optical film allows at least 50% of the light having an incident angle of more than the cutoff angle from normal to the first major surface of the isotropic multilayer optical film to pass through the isotropic multilayer optical film. The isotropic multilayer optical film includes a marking on the second major surface of the isotropic multilayer optical film, the marking including at least one fluorescent compound.

Abstract: Various embodiments disclosed relate to multilayer films including hidden fluorescent features. The present disclosure includes a multilayer optical film including an isotropic multilayer optical film having first and second opposed major surfaces. The isotropic multilayer optical film reflects at least 50% of a light that is at least one of ultraviolet light or visible light, having an incident angle less than a cutoff angle from normal to the first major surface of the isotropic multilayer optical film, wherein the cutoff angle is in a range from 10° to 70°. The isotropic multilayer optical film allows at least 50% of the light having an incident angle of more than the cutoff angle from normal to the first major surface of the isotropic multilayer optical film to pass through the isotropic multilayer optical film. The isotropic multilayer optical film includes a marking on the second major surface of the isotropic multilayer optical film, the marking including at least one fluorescent compound.

Abstract: The present disclosure provides articles that include polymer coatings on substrates primed with a primer coating containing silica nanoparticles, and methods of coating. The polymer coating is preferably a silicone-based polymeric material.

Abstract: The present disclosure provides articles that include polymer coatings on substrates primed with a primer coating containing silica nanoparticles, and methods of coating. The polymer coating is preferably a silicone-based polymeric material.

Abstract: Surface-structured, cross-linked silicone-based material and method for making the same. Embodiments of silicone-based materials described herein are useful, for example, in applications of light capture, anti-reflection, light redirection, light diffusion, hydrophobic surfaces, hydrophilic surfaces, light guiding, light collimation, light concentration, Fresnel lens, retro-reflection, drag reduction, air bleed adhesives, release liner, abrasion resistance, and anti-fouling.

Abstract: It has now been determined that an internal optical defect can be eliminated by controlling the relative speed mismatch between the resilient roll and the casting roll in a film extrusion coating process. In particular, slowing down the surface speed of the resilient roll relative to the casting roll when coating a biaxially orientated film was found to remove the optical defect. Conversely, speeding up the surface speed of the resilient roll relative to the casting roll when coating a uniaxially orientated film was found to remove the optical defect.

Abstract: A transparent anti-reflective structured film comprising a structured film substrate having a structured face, with anti-reflective structures defining a structured surface. The structured face is anti-reflective to light, with at least a substantial portion of the structured surface comprising a glass-like surface. At least the anti-reflective structures comprise a cross-linked silicone elastomeric material, and the glass-like surface comprises an SiO2 stoichiometry. The glass-like surface is coated with a coating of at least one layer of agglomerates of silica nanoparticles, with the agglomerates comprising a three-dimensional porous network of silica nanoparticles, and the silica nanoparticles being bonded to adjacent silica nanoparticles. A light energy absorbing device comprising the transparent anti-reflective structured film disposed so as to be between a source of light energy and a light energy receiving face of a light absorber, when light energy is being absorbed by the light absorber.

Abstract: A transparent anti-reflective structured film (10) comprising a structured film substrate (12) having a structured face (14), with anti-reflective structures, for example, in the form of prismatic riblets (16) defining a structured surface. The structured face is anti-reflective to light, with at least a substantial portion of the structured surface comprising a glass-like surface. At least the anti-reflective structures comprise a cross-linked silicone elastomeric material and the glass-like surface comprises an Si02 stoichiometry. A solar light energy absorbing device is disclosed, comprising the transparent anti-reflective structured film disposed so as to be between a source of light energy and a light energy receiving face of a light absorber, when light energy is being absorbed by the light absorber.

Abstract: It has now been determined that an internal optical defect can be eliminated by controlling the relative speed mismatch between the resilient roll and the casting roll in a film extrusion coating process. In particular, slowing down the surface speed of the resilient roll relative to the casting roll when coating a biaxially orientated film was found to remove the optical defect. Conversely, speeding up the surface speed of the resilient roll relative to the casting roll when coating a uniaxially orientated film was found to remove the optical defect.

Abstract: Surface-structured, cross-linked silicone-based material and method for making the same. Embodiments of silicone-based materials described herein are useful, for example, in applications of light capture, anti-reflection, light redirection, light diffusion, hydrophobic surfaces, hydrophilic surfaces, light guiding, light collimation, light concentration, Fresnel lens, retro-reflection, drag reduction, air bleed adhesives, release liner, abrasion resistance, and anti-fouling.

Abstract: The present disclosure provides articles that include polymer coatings on substrates primed with a primer coating containing silica nanoparticles, and methods of coating. The polymer coating is preferably a silicone-based polymeric material.

Abstract: A transparent anti-reflective structured film comprising a structured film substrate having a structured face, with anti-reflective structures defining a structured surface. The structured film substrate comprises a silicone elastomeric material. The structured face is anti-reflective to light. The structured surface has a silicone elastomer cross-link density that is higher than a remainder of the transparent anti-reflective structured film (e.g., a remainder of the structured film substrate). A light energy absorbing device comprising the transparent anti-reflective structured film disposed so as to be between a source of light energy and a light energy receiving face of a light absorber, when light energy is being absorbed by the light absorber.