Abstract: The present disclosure relates to a method that includes polymerizing a nitrile with an acrylate ester to form a copolymer, in a mixture that includes water and an alcohol (R2—OH), according to the following reaction where R1 includes at least one of a first aliphatic group or hydrogen, R2 comprises at least one of a second aliphatic group or hydrogen, 100?m?4000, and 1?n?4000. In some embodiments of the present disclosure, the mixture may be an emulsion.

Abstract: An aspect of the present disclosure is a method that includes a first reacting a molecule from at least one of a carboxylic acid, an ester of a carboxylic acid, and/or an anhydride with ammonia to form a nitrile, where the first reacting is catalyzed using an acid catalyst. In some embodiments of the present disclosure, the molecule may include at least one of acetic acid, lactic acid, and/or 3-hydroxyproprionic acid (3-HPA). In some embodiments of the present disclosure, the molecule may include at least one of methyl acetate, ethyl lactate, and/or ethyl 3-hydroxypropanoate (ethyl 3-HP). In some embodiments of the present disclosure, the anhydride may be acetic anhydride.

Abstract: An aspect of the present disclosure is a method that includes a first reacting a molecule from at least one of a carboxylic acid, an ester of a carboxylic acid, and/or an anhydride with ammonia to form a nitrile, where the first reacting is catalyzed using an acid catalyst. In some embodiments of the present disclosure, the molecule may include at least one of acetic acid, lactic acid, and/or 3-hydroxyproprionic acid (3-HPA). In some embodiments of the present disclosure, the molecule may include at least one of methyl acetate, ethyl lactate, and/or ethyl 3-hydroxypropanoate (ethyl 3-HP). In some embodiments of the present disclosure, the anhydride may be acetic anhydride.

Abstract: An aspect of the present disclosure is a method that includes a first reacting a molecule from at least one of a carboxylic acid, an ester of a carboxylic acid, and/or an anhydride with ammonia to form a nitrile, where the first reacting is catalyzed using an acid catalyst. In some embodiments of the present disclosure, the molecule may include at least one of acetic acid, lactic acid, and/or 3-hydroxyproprionic acid (3-HPA). In some embodiments of the present disclosure, the molecule may include at least one of methyl acetate, ethyl lactate, and/or ethyl 3-hydroxypropanoate (ethyl 3-HP). In some embodiments of the present disclosure, the anhydride may be acetic anhydride.

Abstract: Catalysts, catalytic systems and related synthetic methods for in situ production of H2O2 and use thereof in reaction with oxidizable substrates.

Abstract: Catalysts, catalytic systems and related synthetic methods for in situ production of H2O2 and use thereof in reaction with oxidizable substrates.

Abstract: Catalysts, catalytic systems and related synthetic methods for in situ production of H2O2 and use thereof in reaction with oxidizable substrates.

Abstract: An aspect of the present disclosure is a catalyst that includes a solid support, a first metal that includes at least one of ruthenium (Ru), platinum (Pt), palladium (Pd) deposited on the solid support, and a second metal comprising at least one of tin (Sn), rhenium (Re), cobalt (Co), molybdenum (Mo), or tungsten (W) deposited on the solid support, where the first metal and the second metal are present at a first metal to second metal mass ratio between about 1.0:2.0 and about 1.0:0.5.

Abstract: The present disclosure relates to a method that includes polymerizing a nitrile with an acrylate ester to form a copolymer, in a mixture that includes water and an alcohol (R2—OH), according to the following reaction where R1 includes at least one of a first aliphatic group or hydrogen, R2 comprises at least one of a second aliphatic group or hydrogen, 100?m?4000, and 1?n?4000. In some embodiments of the present disclosure, the mixture may be an emulsion.

Abstract: An aspect of the present disclosure is a catalyst that includes a solid support, a first metal that includes at least one of ruthenium (Ru), platinum (Pt), palladium (Pd) deposited on the solid support, and a second metal comprising at least one of tin (Sn), rhenium (Re), cobalt (Co), molybdenum (Mo), or tungsten (W) deposited on the solid support, where the first metal and the second metal are present at a first metal to second metal mass ratio between about 1.0:2.0 and about 1.0:0.5.

Abstract: An aspect of the present disclosure is a method that includes a first reacting a molecule from at least one of a carboxylic acid, an ester of a carboxylic acid, and/or an anhydride with ammonia to form a nitrile, where the first reacting is catalyzed using an acid catalyst. In some embodiments of the present disclosure, the molecule may include at least one of acetic acid, lactic acid, and/or 3-hydroxyproprionic acid (3-HPA). In some embodiments of the present disclosure, the molecule may include at least one of methyl acetate, ethyl lactate, and/or ethyl 3-hydroxypropanoate (ethyl 3-HP). In some embodiments of the present disclosure, the anhydride may be acetic anhydride.

Abstract: Catalysts, catalytic systems and related synthetic methods for in situ production of H2O2 and use thereof in reaction with oxidizable substrates.