Patents by Inventor Tohru Shibata

Tohru Shibata has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5863652
    Abstract: A tobacco smoke filter material comprises a fibrillated cellulose ester fiber with an average fiber diameter of 15 to 250 .mu.m and a BET specific surface area of 0.5 to 4.5 m.sup.2 /g. The fibrous cellulose ester content of the material may for example be not less than 20 weight %. The cellulose ester fiber is provided by, for example, extruding a cellulose ester solution from a nozzle into a precipitating agent for the particular cellulose ester and subjecting the extrudate to a shear force. This filter material can be used in the form of, for example, a filament, web or sheet to provide a tobacco smoke filter which assures good smoking qualities and excellent wet disintegratability.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: January 26, 1999
    Assignee: Daicel Chemical Industries Ltd.
    Inventors: Hiroyuki Matsumura, Syu Shimamoto, Tohru Shibata
  • Patent number: 5856006
    Abstract: A tobacco filter material containing fibers which have a core and a surface layer which surrounds the core, wherein the core comprises a non-esterified cellulose and the surface layer comprises a cellulose ester. The fiber may be (A) a cellulose fiber coated with a cellulose ester or (B) a fibrous cellulose derivative with its surface layer esterified by an organic acid and having an average degree of substitution of not more than 1.5. Wood pulp can be used as the cellulose fiber and the amount of the cellulose ester in the coated cellulose (A) is 0.1% by weight or more. The cellulose derivative (B) has its surface layer esterified with an organic acid and retains a non-esterified core portion. This cellulose derivative may be obtained, for example, by the non-catalytic liquid phase treatment of a cellulose fiber with an organic acid and an organic acid anhydride or halide.
    Type: Grant
    Filed: September 22, 1995
    Date of Patent: January 5, 1999
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tanemi Asai, Syu Shimamoto, Hiroyuki Matsumura, Tohru Shibata
  • Patent number: 5705632
    Abstract: A process for the preparation of a cellulose acetate film comprises the steps of: cooling a mixture of cellulose acetate and an organic solvent to -100.degree. to -10.degree. C.; warming the cooled mixture to 0.degree. to 50.degree. C. to dissolve the cellulose acetate in the organic solvent; casting the obtained solution on a support; and evaporating the organic solvent to form the cellulose acetate film. The cellulose acetate has an average acetic acid content in the range of 58.0 to 62.5%. The organic solvent is acetone.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: January 6, 1998
    Assignees: Fuji Photo Film Co., Ltd., Daicel Chemical Industries, Ltd.
    Inventors: Kazuhiro Shimoda, Masahiko Murayama, Hidekazu Yamazaki, Tohru Shibata, Shu Shimamoto, Hiroyuki Takemoto, Naoto Habu
  • Patent number: 5692527
    Abstract: A tobacco smoke filter material has a fibrillated cellulose ester fiber with an average fiber diameter of 15 to 250 .mu.m and a BET specific surface area of 0.5 to 4.5 m.sup.2 /g. The fibrous cellulose ester content of the material may for example be not less than 20 weight %. The cellulose ester fiber is provided by, for example, extruding a cellulose ester solution from a nozzle into a precipitating agent for the particular cellulose ester and subjecting the extrudate to a shear force. This filter material can be used in the form of, for example, a filament, web or sheet to provide a tobacco smoke filter which assures good smoking qualities and excellent wet disintegratability.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: December 2, 1997
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hiroyuki Matsumura, Syu Shimamoto, Tohru Shibata
  • Patent number: 5690126
    Abstract: A tobacco filter is obtained by shaping a sheet material having a web structure and comprising (1) cellulose acetate or other cellulose ester short staple, and (2) a binder fiber selected from polysaccharides or their derivatives and biodegradable polymers, and having a binding property with respect to the short staple into a rod-form. The fiber (2) includes (2a) an esterified cellulose fiber, (2b) a cellulose fiber coated with a cellulose ester, (2c) a fibrillated cellulose ester fiber having a BET specific surface area of 0.5 to 4.5 m.sup.2 /g, and (2d) a cellulose fiber at least a part of its surface has been water-solubilized. The sheet material may further comprise a wood pulp or other beaten pulps.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: November 25, 1997
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hiroyuki Matsumura, Tohru Shibata
  • Patent number: 5678577
    Abstract: A tobacco filter is produced by wrapping up a sheet-like filter material having a web structure and comprising a cellulose ester short staple into a rod-form. As the cellulose ester short staple, a short staple that is non-crimped and/or has a modified cross section where a ratio D1/D2 of a diameter D1 of the circumscribed circle to a diameter D2 of the inscribed circle, each circle being of the cross section, of not less than 2 is used. The short staple includes e.g. a cellulose acetate fiber with an average fiber length of 1 to 10 mm and fineness of 1 to 10 deniers. The short staple may be incorporated with a beaten pulp with a Schopper-Riegler freeness of 20 to 90.degree. SR and/or a binder. The ratio of the short staple to the beaten pulp may for example be about 90/10 to 20/80 (by weight).
    Type: Grant
    Filed: October 31, 1995
    Date of Patent: October 21, 1997
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hiroyuki Matsumura, Syu Shimamoto, Tohru Shibata
  • Patent number: 5663310
    Abstract: A cellulose acetate solution has cellulose acetate in a solvent. The cellulose acetate has an average acetic acid content in the range of 58.0 to 62.5%. In the first embodiment of the invention, the solvent is a mixture of acetone and another organic solvent. The organic solvent is an ether having 3 to 12 carbon atoms, a ketone having 4 to 12 carbon atom, an ester having 3 to 12 carbon atoms, or an alcohol having 1 to 6 carbon atoms. In the second embodiment, the solvent is the ether, the ketone or the ester. Processes for the preparation of the solution and a cellulose acetate film are also disclosed.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: September 2, 1997
    Assignees: Fuji Photo Film Co., Ltd., Daicel Chemical Industries, Ltd.
    Inventors: Kazuhiro Shimoda, Masahiko Murayama, Hidekazu Yamazaki, Tohru Shibata, Shu Shimamoto, Hiroyuki Takemoto, Naoto Habu
  • Patent number: 5489387
    Abstract: Separation of a chemical substance is effected by treating a mixture thereof with a polysaccharide having a substituent for hydroxyl group an acyl group of the formula (1) or a carbamoyl group of the formula (2): ##STR1## wherein R represents an atomic group having a nucleus comprising a conjugated .pi.-bond system in which the number of bonds interposed between an atom contained therein and bonded with the carbonyl or amino group and an atom contained in the .pi.-bond system and most distant from said atom is at least 5 even in the shortest route.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: February 6, 1996
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hajime Namikoshi, Tohru Shibata, Ichiro Okamoto
  • Patent number: 5472599
    Abstract: A separation agent essentially comprises an aliphatic or aromatic ester of a polysaccharide, except for cellulose acetate and an aromatic ester of cellulose. It is useful for separation of various chemical substances, especially optical resolution of optical isomers.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: December 5, 1995
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tohru Shibata, Hajime Namikoshi, Ichiro Okamoto
  • Patent number: 5415769
    Abstract: A separation agent essentially comprises an aliphatic or aromatic ester of a polysaccharide, except for cellulose acetate and an aromatic ester of cellulose. It is useful for separation of various chemical substances, especially optical resolution of optical isomers.
    Type: Grant
    Filed: April 19, 1994
    Date of Patent: May 16, 1995
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tohru Shibata, Hajime Namikoshi, Ichiro Okamoto
  • Patent number: 5415780
    Abstract: Separation of a chemical substance is effected by treating a mixture thereof with a polysaccharide having a substituent for hydroxyl group an acyl group of the formula (1) or a carbamoyl group of the formula (2): ##STR1## wherein R represents an atomic group having a nucleus comprising a conjugated .pi.-bond system in which the number of bonds interposed between an atom contained therein and bonded with the carbonyl or amino group and an atom contained in the .pi.-bond system and most distant from said atom is at least 5 even in the shortest route.
    Type: Grant
    Filed: August 4, 1994
    Date of Patent: May 16, 1995
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hajime Namikoshi, Tohru Shibata, Ichiro Okamoto
  • Patent number: 5368737
    Abstract: Separation of a chemical substance is effected by treating a mixture thereof with a polysaccharide having a substituent for hydroxyl group an acyl group of the formula (1) or a carbamoyl group of the formula (2): ##STR1## wherein R represents an atomic group having a nucleus comprising a conjugated .pi.-bond system in which the number of bonds interposed between an atom contained therein and bonded with the carbonyl or amino group and an atom contained in the .pi.-bond system and most distant from said atom is at least 5 even in the shortest route.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: November 29, 1994
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hajime Namikoshi, Tohru Shibata, Ichiro Okamoto
  • Patent number: 5334311
    Abstract: A separation agent essentially comprises an aliphatic or aromatic ester of a polysaccharide, except for cellulose acetate and an aromatic ester of cellulose. It is useful for separation of various chemical substances, especially optical resolution of optical isomers.
    Type: Grant
    Filed: September 15, 1993
    Date of Patent: August 2, 1994
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tohru Shibata, Hajime Namikoshi, Ichiro Okamoto
  • Patent number: 5268098
    Abstract: A separation agent essentially comprises an aliphatic or aromatic ester of a polysaccharide, except for cellulose acetate and an aromatic ester of cellulose. It is useful for separation of various chemical substances, especially optical resolution of opticl isomers.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: December 7, 1993
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tohru Shibata, Hajime Namikoshi, Ichiro Okamoto
  • Patent number: 5229002
    Abstract: Separation of a chemical substance is effected by treating a mixture thereof with a polysaccharide having a substituent for hydroxyl group an acyl group of the formula (1) or a carbamoyl group of the formula (2): ##STR1## wherein R represents an atomic group having a nucleus comprising a conjugated .pi.-bond system in which the number of bonds interposed between an atom contained therein and bonded with the carbonyl or amino group and an atom contained in the .pi.-bond system and most distant from said atom is at least 5 even in the shortest route.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: July 20, 1993
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hajime Nakikoshi, Tohru Shibata, Ichiro Okamoto
  • Patent number: 5192444
    Abstract: A separation agent essentially comprises an aliphatic or aromatic ester of a polysaccharide, except for cellulose acetate and an aromatic ester of cellulose. It is useful for separation of various chemical substances, especially optical resolution of optical isomers.
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: March 9, 1993
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tohru Shibata, Hajime Namikoshi, Ichiro Okamoto
  • Patent number: 5137638
    Abstract: Separation of a chemical substance is effected by treating a mixture thereof with a polysaccharide having a substituent for hydroxyl group an acyl group of the formula (1) or a carbamoyl group of the formula (2): ##STR1## wherein R represents an atomic group having a nucleus comprising a conjugated .pi.-bond system in which the number of bonds interposed between in atom contained therein and bonded with the carbonyl or amino group and an atom contained in the .pi.-bond system and most distant from said atom is at least 5 even in the shortest route.
    Type: Grant
    Filed: October 16, 1991
    Date of Patent: August 11, 1992
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hajime Namikoshi, Tohru Shibata, Ichiro Okamoto
  • Patent number: 5135653
    Abstract: A separation agent essentially comprises an aliphatic or aromatic ester of a polysaccharide, except for cellulose acetate and an aromatic ester of cellulose. It is useful for separation of various chemical substances, especially optical resolution of optical isomers.
    Type: Grant
    Filed: April 10, 1991
    Date of Patent: August 4, 1992
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Yoshio Okamoto, Koichi Hatada, Tohru Shibata, Hajime Namikoshi, Ichiro Okamoto
  • Patent number: 5089138
    Abstract: A separation agent essentially comprises an aliphatic or aromatic ester of a polysaccharide, except for cellulose acetate and an aromatic ester of cellulose. It is useful for separation of various chemical substances, especially optical resolution of optical isomers.
    Type: Grant
    Filed: January 11, 1991
    Date of Patent: February 18, 1992
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tohru Shibata, Hajime Namikoshi, Ichiro Okamoto
  • Patent number: RE34457
    Abstract: A mixture of chemical substances such as optical isomers, geometrical isomers and polymers having different molecular weight ranges is separated to each ingredient by use of a cellulose derivative having an aromatic ring in the chromatographic method.
    Type: Grant
    Filed: November 24, 1992
    Date of Patent: November 30, 1993
    Assignee: Daicel Chemical Industries, Inc.
    Inventors: Yoshio Okamoto, Koichi Hatada, Tohru Shibata, Ichiro Okamoto, Hiroyuki Nakamura