Patents by Inventor Tokuo Makishima
Tokuo Makishima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4921901Abstract: A novel block copolymer is disclosed which includes a random ethylene-propylene copolymer segment (A) and a methacrylate segment (B). The block copolymer has a number-average molecular weight of about 1,000 to about 600,000 and a ratio of (A) to (B) of 15/85 to 97/3 by weight.Type: GrantFiled: July 5, 1988Date of Patent: May 1, 1990Assignee: Toa Nenryo Kogyo KKInventors: Satoshi Ueki, Tokuo Makishima, deceased, Chihiro Imai
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Patent number: 4912170Abstract: This invention relates to a p-methyl styrene polymer represented by the following formula: ##STR1## Z denotes a group such as a functional group. Poly p-methylstyrene (PPMS) is lithiated by reaction with n-butyllithium. The lithiated PPMS is used to prepare polymers containing functional groups. As an example, a solution of PPMS (MW 260,000), 1.0 g in 20 ml of cyclohexane, was reacted with n-butyllithium, 8.5 mmol, and tetramethylethylenediamine, 8.7 mmol, for 20 hours to obtain a precipitate. The precipitate was dissolved in THF, and CO.sub.2 was blown into the solution. The solution was washed with an aqueous solution of HCl and dropped into methanol to obtain a solid polymer having carboxyl group functionality.Type: GrantFiled: December 22, 1988Date of Patent: March 27, 1990Assignee: Toa Nenryo Kogyo K.K.Inventors: Tadashi Niwa, Masayuki Kato, Yoshio Taguchi, Chihiro Imai, Tokuo Makishima, deceased, by Nobuko Makishima, legal representative
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Patent number: 4849483Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) a magnesium alkoxide, contacting the resulting contact product with (c) a halogen-containing compound, and finally contacting the resulting contact product with (d) a titanium compound.Type: GrantFiled: April 16, 1987Date of Patent: July 18, 1989Assignee: Toa Nenryo Kogyo K.K.Inventors: Mamoru Tachikawa, Masato Sakuma, Satoshi Ueki, Chihiro Imai, Tokuo Makishima
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Patent number: 4801654Abstract: A block copolymer is disclosed which includes an ethylene-propylene copolymer segment (A) and a tetrahydrofuran segment (B). The weight ratio of (A) to (B) is 5/95 to 95/5, and the block copolymer has a number-average molecular weight of about 1,000 to about 1,000,000.Type: GrantFiled: June 12, 1987Date of Patent: January 31, 1989Assignee: Toa Nenryo Kogyo K.K.Inventors: Tokuo Makishima, deceased, by Nobuko Makishima, legal representative, Satoshi Ueki, Chihiro Imai
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Patent number: 4737555Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) an organomagnesium compound represented by the formula RMgR' wherein R denotes a hydrocarbyl group and R' denotes a hydrocarbyl group or a halogen atom, contacting the resulting contacting product with (c) carbon dioxide, and further contacting the resulting contact product with (d) a titanium compound. Optionally, the carbon dioxide contacted contact product can be treated with the halogen-containing compound prior to contact with the titanium compound.Type: GrantFiled: April 22, 1987Date of Patent: April 12, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Mamoru Tachikawa, Satoshi Ueki, Masato Sakuma, Chihiro Imai, Tokuo Makishima
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Patent number: 4705830Abstract: A block copolymer is disclosed which includes an ethylene-propylene copolymer segment (A) and a tetrahydrofuran segment (B). The weight ratio of (A) to (B) is 5/95 to 95/5, and the block copolymer has a number-average molecular weight of about 1,000 to about 1,000,000.Type: GrantFiled: May 24, 1985Date of Patent: November 10, 1987Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Tokuo Makishima, deceased, by Nobuko Makishima, legal representative, by Satoshi Ueki, legal representative, by Chichiro Imai, legal representative
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Patent number: 4704433Abstract: A novel block copolymer is disclosed which includes a random ethylene-propylene copolymer segment (A) and a methacrylate segment (B). The block copolymer has a number-average molecular weight of about 1,000 to about 600,000 and a ratio of (A) to (B) of 15/85 to 97/3 by weight.Type: GrantFiled: May 24, 1985Date of Patent: November 3, 1987Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Satoshi Ueki, Chihiro Imai, Tokuo Makishima, deceased
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Patent number: 4686199Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) a magnesium alkoxide, contacting the resulting contact product with (c) a halogen-containing compound, and finally contacting the resulting contact product with (d) a titanium compound.Type: GrantFiled: November 27, 1985Date of Patent: August 11, 1987Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Mamoru Tachikawa, Masato Sakuma, Satoshi Ueki, Chihiro Imai, Tokuo Makishima
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Patent number: 4683275Abstract: A copolymer of p-methylstyrene and N-substituted maleimide exhibits high temperature stability.Type: GrantFiled: September 20, 1985Date of Patent: July 28, 1987Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Masayuki Kato, Yoshio Taguchi, Chihiro Imai, Tokuo Makishima, deceased
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Patent number: 4678767Abstract: A process for producing a catalyst component for polymerization of olefins which comprises contacting (a) a metal oxide with (b) an organomagnesium compound represented by the formula RMgR' wherein R denotes a hydrocarbyl group and R' denotes a hydrocarbyl group or a halogen atom, contacting the resulting contacting product with (c) carbon dioxide, and further contacting the resulting contact product with (d) a titanium compound. Optionally, the carbon dioxide contacted product can be treated with the halogen-containing compound prior to contact with the titanium compound.Type: GrantFiled: November 27, 1985Date of Patent: July 7, 1987Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Mamoru Tachikawa, Satoshi Ueki, Masato Sakuma, Chihiro Imai, Tokuo Makishima
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Patent number: 4647550Abstract: A catalyst component for the polymerization of olefins which is prepared by contacting a contact reaction product of (a) a metal oxide, (b) an organic magnesium compound, and (c) an alkoxy group-containing compound held in contact with (d) a titanium compound.Type: GrantFiled: July 31, 1985Date of Patent: March 3, 1987Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Tadanao Kohora, Satoshi Ueki, Mamoru Tachikawa, Chihiro Imai, Tokuo Makishima, deceased
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Patent number: 4634740Abstract: A polypropylene composition having superior clarity and good low-temperature impact resistance, said composition comprising 65 wt % to 95 wt % crystalline polypropylene and 5 wt % to 35 wt % of ethylene-propylene random copolymer containing higher than 70 wt % to 85 wt % of ethylene.Type: GrantFiled: April 8, 1985Date of Patent: January 6, 1987Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Yuji Fujita, Tadao Ikeda, Tokuo Makishima, deceased
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Patent number: 4401799Abstract: A titanium trichloride catalytic complex is produced by reducing titanium tetrachloride with an organo-metal compound and then treating the resulting reduced solids product with a chlorinated saturated aliphatic hydrocarbon having three to eight carbon atoms in the presence of a complexing agent. The resulting titanium trichloride complex composition, when employed as a co-catalyst with an organo-metal compound for Ziegler-type catalysts in polymerization of .alpha.-olefins, results in uniform polymer grains with unexpectedly high polymerization activity and high stereoregular polymer yielding ratios.Type: GrantFiled: July 20, 1979Date of Patent: August 30, 1983Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Hiroshi Ueno, Eiji Sezaki, Naomi Inaba, Tokuo Makishima, Koh Watanabe, Shozo Wada
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Patent number: 4183826Abstract: A titanium trichloride catalytic complex is produced by reducing titanium tetrachloride with an organo-metal compound and then treating the resulting reduced solids product with a chlorinated saturated aliphatic hydrocarbon having three to eight carbon atoms in the presence of a complexing agent. The resulting titanium trichloride complex composition, when employed as a co-catalyst with an organo-metal compound for Ziegler-type catalysts in polymerization of .alpha.-olefins, results in uniform polymer grains with unexpectedly high polymerization activity and high stereoregular polymer yielding ratios.Type: GrantFiled: February 9, 1979Date of Patent: January 15, 1980Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Hiroshi Ueno, Eiji Sezaki, Naomi Inaba, Tokuo Makishima, Koh Watanabe, Shozo Wada
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Patent number: 4127504Abstract: A process for the production of a catalyst component for use in the polymerization of .alpha.-olefins, which comprises reducing titanium tetrachloride with an organo aluminum compound having the general formula Al Rn X.sub.3-n wherein R represents a hydrocarbon group having 1 to 18 carbon atoms, x represents a halogen atom and n represents a suitable numeral between o<n.ltoreq.3, to thus obtain a reduced solid, then removing aluminum compounds contained in said reduced solid and activating with a mixture or a complex of titanium tetrachloride and a dialkyl ether of the general formula R'OR" wherein R' and R" are (a) alkyl groups having 1-4 carbon atoms, (b) normal alkyl groups having five carbon atoms, or (c) alkyl groups having 6-20 carbon atoms.Type: GrantFiled: November 24, 1976Date of Patent: November 28, 1978Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Hiroshi Ueno, Naomi Inaba, Tokuo Makishima, Shozo Wada
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Patent number: 4064069Abstract: This invention relates to a catalyst composition for polymerization of propylene, having high activity and producing polypropylene of high stereoregularity and having a low particle size distribution, which comprises;1. reducing TiCl.sub.4 by diethylaluminum chloride (DEAC), thereby forming a reduced solid (TiCl.sub.3),2. removing the aluminum compounds from the reduced catalyst,3. treating the said reduced solid with the mixture or complex of TiCl.sub.4 and diisoamylether (IAE) and4. separating the solid catalyst from the mixture.The aluminum compounds may be removed by washing with a complexing agent therefor; in a preferred embodiment the complexing agent is di-n-butyl ether.Type: GrantFiled: July 6, 1976Date of Patent: December 20, 1977Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Hiroshi Ueno, Naomi Inaba, Tokuo Makishima, Shozo Wada
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Patent number: 4062804Abstract: The invention relates to a method for preparing a catalyst composition for polymerization of propylene, having high activity and producing polypropylene of high stereoregularity in narrow particle size distribution, which comprises:1. reducing TiCl.sub.4 by a mixture of diethylaluminum chloride (DEAC) and ethylaluminum dichloride (EADC), thereby forming a reduced solid (TiCl.sub.3),2. removing the aluminum compound from the reduced solid;3. treating the said reduced solid with a mixture or complex of TiCl.sub.4 and diisoamylether (IAE), and4. separating the solid catalyst from the solution.Preferably step 2 is performed by washing with a complexing agent for the aluminum compound.Type: GrantFiled: July 8, 1976Date of Patent: December 13, 1977Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Hiroshi Ueno, Naomi Inaba, Tokuo Makishima, Shozo Wada