Abstract: The present disclosure provides compositions, articles, and methods related to altering electromagnetic radiation. An actinic radiation curable precursor composition of a three-dimensional article includes a) a resin comprising an actinic radiation curable component, wherein the resin has a viscosity no greater than 500 cP; b) hollow glass microspheres having a density no greater than 2 g/mL and an average diameter no greater than 200 micrometers; and c) a photoinitiator. At least part of the surface of the hollow glass microspheres comprises a surface coating or modification. An article includes a photo(co)polymerization reaction product of the composition. A method of manufacturing a three-dimensional article includes the steps of a) providing an actinic radiation curable precursor composition; and b) selectively exposing a portion of the composition to a source of actinic radiation to at least partially cure the exposed portion of the composition, thereby forming a cured layer.

Abstract: The present disclosure provides methods, articles, and apparatuses related to altering electromagnetic radiation. A method of making articles includes a) forming an electromagnetic radiation altering material by providing a polymer matrix and optionally embedding dielectric particles in the polymer matrix and b) obtaining initial dielectric properties of the electromagnetic radiation altering material. The method further includes c) modeling electromagnetic radiation altering features of the material suitable for the article obtained from the material to have target electromagnetic radiation altering properties, thereby obtaining a simulation of the electromagnetic radiation altering article; and d) additive manufacturing the electromagnetic radiation altering article based on the simulation of the electromagnetic radiation altering article. An electromagnetic radiation altering article obtained by the method is also provided.