Patents by Inventor Tomijiro Naito

Tomijiro Naito has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6174573
    Abstract: A novel tolan compound of the formula (I): wherein A is C1-10 alkyl, C1-10 alkoxy, cyclohexyl substituted by C1-10 alkyl at 4 position, cyclohexyl substituted by C1-10 alkoxy group at 4 position or a group of the formula: wherein Y is hydrogen or halogen and Z is C1-10 alkyl or halogen; B is a single bond or —CO—O— or —O—CO—; D is hydrogen, C1-10 alkyl, cyclohexyl substituted by C1-10 alkyl at 4 position; and Z represents a hydrogen atom or a halogen atom. The tolan compound can increase the N-I point, decrease the viscosity, and increase the double refractive index of a liquid crystal composition without affecting the viscosity and threshold voltage Vth, and is mutually soluble with various other liquid crystal compounds, so that the compound can be used as a constituent of a liquid crystal composition in combination with these other liquid crystal materials to improve the properties of the composition.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: January 16, 2001
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Tomijiro Naito, Kikuo Yamamoto, Katsuji Niino, Yumiko Sakamaki
  • Patent number: 5972244
    Abstract: A novel tolan compound of the formula (I): ##STR1## wherein A is C.sub.1-10 alkyl, C.sub.1-10 alkoxy, cyclohexyl substituted by C.sub.1-10 alkyl at 4 position, cyclohexyl substituted by C.sub.1-10 alkoxy group at 4 position or a group of the formula: ##STR2## wherein Y is hydrogen or halogen and Z is C.sub.1-10 alkyl or halogen; B is a single bond or --CO--O-- or --O--CO--; D is hydrogen, C.sub.1-10 alkyl, cyclohexyl substituted by C.sub.1-10 alkyl at 4 position; and Z represents a hydrogen atom or a halogen atom. The tolan compound can increase the N-I point, decrease the viscosity, and increase the double refractive index of a liquid crystal composition without affecting the viscosity and threshold voltage Vth, and is mutually soluble with various other liquid crystal compounds, so that the compound can be used as a constituent of a liquid crystal composition in combination with these other liquid crystal materials to improve the properties of the composition.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: October 26, 1999
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Tomijiro Naito, Kikuo Yamamoto, Katsuji Niino, Yumiko Sakamaki
  • Patent number: 5656198
    Abstract: A novel tolan compound of the formula (I): ##STR1## wherein A is a substituted or unsubstituted cyclohexyl or phenyl group; B is --CO--O-- or --O--CO--; X is a hydrogen atom, a halogen atom, a cyano group, a C.sub.1 -C.sub.10 alkyl group, or a C.sub.1 -C.sub.10 alkoxy group; Y is a hydrogen atom or a halogen atom; and m and n are an integer of 0 or 1, provided that m+n=0 or 1. The tolan compound can raise the N-I point and increase the double refractive index (.DELTA.n) of liquid crystal compositions. The liquid crystal composition containing this tolan compound has excellent characteristics as a liquid crystal material, and the liquid crystal display device using this liquid crystal composition has a wide temperature range and a wide visible angle and can be operated at a low driving voltage.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: August 12, 1997
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Tomijiro Naito, Yumiko Sakamaki, Katsuji Niino, Kikuo Yamamoto
  • Patent number: 5651919
    Abstract: Disclosed are a benzyl ether derivative represented by the following formula (I), useful as a liquid crystal display material, and a liquid crystal composition containing the same and a liquid crystal display device utilizing the composition. ##STR1## [wherein A represents a 4-alkylcyclohexyl group or an alkyl group, B represents a di- or tri-fluorophenyl group, a 4-(di- or tri-fluorophenyl)phenyl group, a 4-alkylphenyl group or a 4-alkoxyphenyl group].The compound (I) of the present invention has good compatibility with other compounds, and can be used in a liquid crystal composition by combining with many liquid crystal materials as a constitutional component of the liquid crystal composition. It has functions of lowering a C-N point of a liquid crystal composition, lowering a threshold voltage by enlarging a dielectric anisotropy, and also lowering a viscosity and increasing a N-I point of the liquid crystal composition.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: July 29, 1997
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Tomijiro Naito, Yumiko Sakamaki, Hisato Sato
  • Patent number: 5364558
    Abstract: An ester derivative represented by the following formula (I). ##STR1## In the formula, V, W, X, Y and Z represent a hydrogen atom or a halogen atom, respectively. The present invention also comprises a liquid crystal composition containing the ester derivative. The ester derivative can optimize the n value, lower the viscosity and reduce the threshold voltage Vth of the liquid crystal composition.
    Type: Grant
    Filed: July 20, 1993
    Date of Patent: November 15, 1994
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Yumiko Sakamaki, Tomijiro Naito, Toshiro Yukinari
  • Patent number: 5342544
    Abstract: A nematic liquid crystal composition comprising at least one member selected from 4-alkyl- or 4-alkoxy-benzoic acids represented by the following general formula (I) , particularly a nematic liquid crystal composition comprising a carboxylic acid mixture composed of at least one member selected from 4-alkyl- or 4-alkoxy-benzoic acids represented by the following general formula (I) and at least one member selected from 4-alkylcyclohexanecarboxylic acids represented by the following general formula (IV): ##STR1## wherein R.sub.1 stands for an alkyl or alkoxy group having 1 to 12 carbon atoms and R.sub.4 stands for an alkyl group having 1 to 12 carbon atoms.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: August 30, 1994
    Assignees: Asahi Denka Kogyo Kabushiki Kaisha, Citizen Watch Co., Ltd.
    Inventors: Tomijiro Naito, Yumiko Sato, Toshiro Yukinari, Toshihiro Shibata, Masaki Kimura, Yukari Shinada
  • Patent number: 5342546
    Abstract: Particular 1,4-substituted dihydrobenzene derivatives are useful as liquid crystalline materials. They are represented by the following formula (I): ##STR1## wherein A means a 1,4-dihydrophenylene group, R denotes a hydrogen atom or an alkyl or trans-4-alkylcyclohexyl group, R' represents a hydrogen or halogen atom, a trifluoromethyl, trifluoromethoxy, cyano, alkyl, alkoxyl or carboxyl group or a group --COO--B--R" in which B stands for an unsubstituted or halogen-substituted 1,4-phenylene or 1,4-cyclohexenylene group and R" represents a halogen atom or a cyano, alkyl or alkoxyl group, and X, Y and Z individually mean a hydrogen or halogen atom.
    Type: Grant
    Filed: May 27, 1992
    Date of Patent: August 30, 1994
    Assignees: L.C.C. Consultants Co., Ltd., Citizen Watch Co., Ltd.
    Inventors: Hisato Sato, Tomijiro Naito, Yasunobu Tuji