Patents by Inventor Tomoaki Nagai

Tomoaki Nagai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20070099798
    Abstract: The present invention provides a laser recording thermally sensitive recording medium comprising a thermally sensitive recording layer containing at least a photo absorbing material which absorbs laser ray and covert it to heat, an electron donning leuco dye and an electron accepting color developing agent on a substrate, wherein said electron donning leuco dye contains a leuco dye which absorbs the ray of visible range and a leuco dye having main wave length of absorption at the ray of 600 nm or longer.
    Type: Application
    Filed: November 2, 2006
    Publication date: May 3, 2007
    Inventors: Tomoaki Nagai, Takashi Date, Yuji Tsuzuki, Yoshihide Kimura
  • Publication number: 20040171485
    Abstract: The present invention provides a laser recording thermally sensitive recording medium comprising a thermally sensitive recording layer containing at least a photo absorbing material which absorbs laser ray and covert it to heat, an electron donning leuco dye and an electron accepting color developing agent on a substrate, wherein said electron donning leuco dye contains a leuco dye which absorbs the ray of visible range and a leuco dye having main wave length of absorption at the ray of 600 nm or longer.
    Type: Application
    Filed: November 12, 2003
    Publication date: September 2, 2004
    Inventors: Tomoaki Nagai, Takashi Date, Yuji Tsuzuki, Yoshihide Kimura
  • Patent number: 6303540
    Abstract: A thermally sensitive recording medium which has thermally sensitive recording layer containing colorless or pale colored basic leuco dye and organic color developer as main components on a substrate, wherein said thermally sensitive recording layer contains diphenylsulfone bridgeable type compound represented by general formula (1) and at least one compound represented by general formula (1). In general formula (2), X and Y can be different and indicates a saturated or an unsaturated liner or grafted hydrocarbon group of carbon number 1-12 which can possess ether bond, or indicates wherein R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1-4, and R1-R6 independently indicate a halogen atom, an alkyl group of carbon number 1-6, or an alkenyl group, further, m, n, p, q, r, t indicate an integer number of 0-4 and when are bigger than 2, R1-R6 can be different, and a is an integer of 0-10.
    Type: Grant
    Filed: November 1, 1999
    Date of Patent: October 16, 2001
    Assignee: Nippon Paper Industries Co Ltd
    Inventors: Tadakazu Fukuchi, Kaoru Hamada, Yuji Tsuzuki, Yoshihide Kimura, Tomoaki Nagai, Yutaka Wakita
  • Patent number: 6284707
    Abstract: The thermally sensitive recording medium having sufficient color developing density and develops navy blue or grayish blue color. The color difference L* value a* value and b* value of developed image of said thermally sensitive recording medium regulated by JIS-Z-8729 are within the regions of, A. L* value is 30˜50, a* value is −15˜0 and b* value is −30˜10, B. L* value is 30˜50, a* value is 0˜10 and b* value is −30˜0 or C. L* value is 30˜50, a* value is 10˜20 and b* value is −30˜15.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: September 4, 2001
    Assignee: Nopon Paper Industries Co Ltd
    Inventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
  • Patent number: 6284706
    Abstract: The thermally sensitive recording medium having sufficient color developing density and develops sepia color or light brown color. The color difference a* value of developed image of said thermally sensitive recording medium regulated by JIS-Z-8729 is within the region of 0˜40 and b* value is within the region of 0˜55.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: September 4, 2001
    Assignee: Nippon Paper Industries Co Ltd
    Inventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
  • Patent number: 6258747
    Abstract: A thermally sensitive recording medium having sufficient color developing density and which develops russet or wine red color. The recording medium incorporates a dye precursor which includes at least one red color developing leuco dye having a maximum absorption wavelength of 480 to 570 nm and at least one black color developing leuco dye with maximum absorption wavelengths at 420 to 480 nm and 550 to 640 nm. The color difference a* value of developed image of said thermally sensitive recording medium, measured according to JIS-Z-8729 is within the region of 0 to 50 and b* value is within the region of −15 to 10.
    Type: Grant
    Filed: June 16, 1999
    Date of Patent: July 10, 2001
    Assignee: Nippon Paper Industries Co Ltd
    Inventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
  • Patent number: 6093678
    Abstract: A thermal sensitive recording medium which has a feature to change the color of recorded pattern slowly and spontaneously after development, and the recorded pattern which has several days passed can be easily distinguished from that of just after development. Said thermal sensitive recording medium contains 4-hydroxybenzoic acid ester represented by general formula (I) as a color developer and uses triphenylmethane-based leuco dye and reddish color developing leuco dye whose maximum absorption wave length is 450.about.560 nm as a dye precursor. ##STR1## In this formula, R represents unsubstituted or substituted lower alkyl group of carbon number 1-7 or benzyl group.
    Type: Grant
    Filed: August 18, 1998
    Date of Patent: July 25, 2000
    Assignee: Nippon Paper Industries Co. Ltd.
    Inventors: Kaoru Hamada, Tadakazu Fukuchi, Tomoaki Nagai, Reiko Sato, Yutaka Wakita
  • Patent number: 5919928
    Abstract: A phenanthridine derivative metal complex of formula 1 having a large absorption in the near-infrared range and a reduced absorption in the visible range, which phenanthridine derivative metal complex is used in a transparent recording medium: ##STR1## where M is a metal atom, and X is a negative ion.
    Type: Grant
    Filed: September 18, 1997
    Date of Patent: July 6, 1999
    Assignee: Nippon Paper Industries, Co., Ltd.
    Inventors: Reiji Ohashi, Yukiko Ryu, Tomoaki Nagai, Hidetoshi Yoshioka
  • Patent number: 5892042
    Abstract: An acridine derivative metal complex of formula 2 having a large absorption in the near-infrared range and a reduced absorption in the visible range, which acridine derivative metal complex is used in a transparent recording medium: ##STR1## where M is a metal atom, and X is a negative ion.
    Type: Grant
    Filed: September 18, 1997
    Date of Patent: April 6, 1999
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Reiji Ohashi, Yukiko Ryu, Tomoaki Nagai, Hidetoshi Yoshioka
  • Patent number: 5811369
    Abstract: A thermal recording medium comprising a substrate having thereon a recording layer containing a colorless or pale colored dye precursor, and a color developer reactable with the dye precursor to develop a color as main ingredients, wherein the color developer includes at least one compound of Formula (1): and the recording layer contains at least one methylolated fatty acid amide of Formula (2): ##STR1## (wherein X denotes oxygen atom or sulfur atom; and R denotes substituted or unsubstituted phenyl group, naphthyl group, aralkyl group, a lower alkyl group of 1 to 6 carbon atoms, a cycloalkyl group of 3 to 6 carbon atoms, or a lower alkenyl group of 2 to 6 carbon atoms. Z denotes a lower alkyl group of 1 to 6 carbon atoms or an electron attracting group. n is an integer from 0 to 4, and p is an integer from 1 to 5, satisfying n+p .ltoreq.5.).R.sub.1 -CONHCH.sub.2 OH (2)(wherein R.sub.1 denotes an alkyl group of 11 to 21 carbon atoms).
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: September 22, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Tomoaki Nagai, Kaoru Hamada, Akio Sekine
  • Patent number: 5811368
    Abstract: In a thermal sensitive recording medium comprising a thermal sensitive color developing layer which includes a basic leuco dye and an organic color developer on a substrate, characterized by the said thermal color developing layer includes 0.01-0.9 parts of aminobenzenesulfonamide derivatives indicated by general formula (I) based on 1 part of color developer and also includes at least one kind of methylolated fatty acid amide indicated by general formula (II) in proportion of 0.01-2 parts based on 1 part of color developer. ##STR1## (wherein, "X" indicates an oxygen or sulfur atom, "R" indicates non-substituted or substituted phenyl group, naphthyl group, aralkyl group, lower alkyl group of carbon number 1-6, cycloalkyl group of carbon number 3-6 or lower alkenyl group of carbon number 2-6. "Z" indicates lower alkyl group of carbon number 1-6 or electron attractive group. "n" indicates an integer from 0 to 4 and "P" indicates an integer from 1 to 5, wherein satisfies the numerical formula of n+p.ltoreq.5)R.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: September 22, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Tadakazu Fukuchi, Kaoru Hamada, Tomoaki Nagai, Nobuhiro Kudoh, Akio Sekine
  • Patent number: 5792863
    Abstract: An acridine derivative metal complex of formula 1 or formula 2 having a large absorption in the near-infrared range and a reduced absorption in the visible range, which acridine derivative metal complex is used in a transparent recording medium: ##STR1## where M is a metal atom, and X is a negative ion.
    Type: Grant
    Filed: April 15, 1996
    Date of Patent: August 11, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Reiji Ohashi, Yukiko Ryu, Tomoaki Nagai, Hidetoshi Yoshioka
  • Patent number: 5753586
    Abstract: A thermal sensitive recording sheet comprising a substrate having thereon a thermal sensitive color developing layer mainly composed of basic leuco dye and an organic color developer, characterized by said thermal sensitive developing layer includes derivatives of amino benzene sulfone amide indicated by general formula (I) as an organic color developer, and includes sulfone amide compound indicated by general formula (II) as a sensitizer by amount of 0.01-2 parts based on 1 part of the color developer indicated by general formula (I). ##STR1## wherein "X" indicates an oxygen or sulfur atom, "Y" indicates a lower alkyl group of carbon number 1-4 or electron attracting group and "m" indicates an integral number from 0 to 4. "R" indicates a non-substituted or a substituted phenyl group, aralkyl group, lower alkyl group of carbon number 1-6, cycloalkyl group of carbon number 3-6, lower alkenyl group of carbon number 2-6 or naphthyl group.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: May 19, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Kaoru Hamada, Yoshimi Midorikawa, Yutaka Wakita, Tomoaki Nagai, Akio Sekine, Hiroshi Ueda
  • Patent number: 5733843
    Abstract: Discloses a thermal sensitive recording sheet which has features of high sensitivity, excellent heat resistance, excellent water proof and excellent durability to oil. The thermal sensitive color developing layer is mainly composed of a basic achromatic dye including the compound indicated by general formula (I) or (II), an organic color developer and a stabilizer indicated by general formula (III). And the said layer is arranged on a substrate and forms the thermal sensitive recording sheet.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: March 31, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Toshiaki Minami, Tomoaki Nagai, Kaoru Hamada, Akio Sekine
  • Patent number: 5710094
    Abstract: To provide a reversible multi-color thermal recording medium or a reversible multi-color optical recording medium which uses novel urea and thiourea derivatives and has excellent heat resistance.A reversible multi-color thermal recording medium having an irreversible thermal composition containing a colorless or pale basic achromatic dye and an organic color developer as main components and a reversible thermal composition containing a colorless or pale basic achromatic dye and an organic color developer as main components laminated on a support, the organic color developer contained in the irreversible thermal composition being an irreversible heat-resistant color developer and the organic color developer contained in the reversible thermal composition being a reversible heat-resistant color developer.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: January 20, 1998
    Assignee: Nippon Paper Industries Co. Ltd.
    Inventors: Toshiaki Minami, Tomoaki Nagai, Kaoru Hamada, Akio Sekine
  • Patent number: 5707778
    Abstract: An optical recording medium including a substrate having thereon a recording layer containing a dye precursor, a color developer reactable with the dye precursor to develop a color, and a light absorbent for converting light to heat, characterized in that the color developer is at least one compound of Formula (1):(R--NH (C.dbd.S) NH)n--Z (1)(wherein R denotes a substituted or unsubstituted alkyl, cycloalkyl, aryl, aralkyl, or alkenyl. n is an integer of 2 or more, and Z denotes a group having a valence of 2 or more.). The optical recording medium is superior in heat resistance and plasticizer resistance of the recorded image, heat resistance of background, water resistance, and moisture resistance.).
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: January 13, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Toshiaki Minami, Tomoaki Nagai, Kaoru Hamada, Akio Sekine, Toshimi Satake, Toshiyuki Takano, Hideki Hayasaka
  • Patent number: 5665675
    Abstract: In a thermal recording medium or an optically recordable thermal recording medium including a substrate having thereon a recording layer containing a colorless or pale colored dye precursor and a color developer reactable with the dye precursor to develop a color as main ingredients, the color developer includes at least one aminobenzenesulfonamide derivative of Formula (1): ##STR1## (wherein X denotes oxygen atom or sulfur atom; and R denotes substituted or unsubstituted phenyl group, naphthyl group, aralkyl group, a lower alkyl group of 1 to 6 carbon atoms, cycloalkyl group, or a lower alkenyl group of 2 to 6 carbon atoms. Z denotes a lower alkyl group of 1 to 6 carbon atoms or an electron attracting group. n is an integer from 0 to 4.).
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: September 9, 1997
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Tomoaki Nagai, Kaoru Hamada, Akio Sekine
  • Patent number: 5661100
    Abstract: A thermal recording sheet wherein a compound of Formula (I) or (II) is contained in a thermal color developing layer including a basic colorless dye and an organic color developer as main ingredients: ##STR1## (wherein A denotes hydrogen atom, an alkyl group of C.sub.1 to C.sub.4, an alkoxy group of C.sub.1 to C.sub.4, hydroxy group, or nitro group. R.sub.1, R.sub.2, and R.sub.3 are hydrogen atom, an alkyl group of C.sub.1 to C.sub.4, an alkoxy group of C.sub.1 to C.sub.4, hydroxy group, or nitro group. R.sub.1 and R.sub.2 may combine with each other to form an aromatic ring. Y is sulfur or oxygen atom.), ##STR2## (wherein B denotes hydrogen atom, an alkyl group of C.sub.1 to C.sub.4, an alkoxy group of C.sub.1 to C.sub.4, hydroxy group, or nitro group. R.sub.1, R.sub.2, and R.sub.3 are hydrogen atom, an alkyl group of C.sub.1 to C.sub.4, an alkoxy group of C.sub.1 to C.sub.4, hydroxy group, or nitro group. R.sub.1 and R.sub.2 may combine with each other to form an aromatic ring. Y is sulfur or oxygen atom.).
    Type: Grant
    Filed: August 29, 1995
    Date of Patent: August 26, 1997
    Assignees: Nippon Paper Industries Co., Ltd., Yoshitomi Pharmaceutical Industries, Ltd.
    Inventors: Toshiaki Minami, Tomoaki Nagai, Kaoru Hamada, Akio Sekine, Ryoichi Kinishi, Ryuzo Minakami
  • Patent number: 5612279
    Abstract: In an optical recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with the dye precursor upon heating to develop a color, a dimerized or trimerized urea compound is used as the color developer to obtain an optical recording sheet which is superior in ground color stability and an optical recording sheet having a reversible recordability.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: March 18, 1997
    Assignee: Nippon Paper Industries, Ltd.
    Inventors: Toshimi Satake, Toshiyuki Takano, Hideki Hayasaka, Yukiko Uehori, Tomoaki Nagai
  • Patent number: 5494882
    Abstract: It is provided with a thermal recording material having a support coated with a coating solution as a color developing layer. The color developing layer has a colorless dye precursor which is normally colorless or light-colored, and a developer which reacts with the dye precursor to cause color development thereof upon heating. The developer is a bisthiourea compound represented by, for example, a formula (A-2): ##STR1## and the thermal color developing layer contains no sensitizer. In the thermal recording materials of the present invention, substantially no color is developed at a temperature of 120.degree. C. while color development can be caused in response to heating with a thermal head or a laser beam. The developed color on the material can be erased upon contacting with alcoholic solvents, depending on the thiourea compound contained in the color developing layer. After erasure of the image, the material can be used again for recording with a thermal head or a laser beam.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: February 27, 1996
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Toshimi Satake, Hideki Hayasaka, Toshiyuki Takano, Tomoaki Nagai, Akio Sekine