Patents by Inventor Tomoaki Shimoda

Tomoaki Shimoda has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5496921
    Abstract: Polycarbonates are prepared by inducing the melt polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of alkali metal compounds and/or alkaline earth metal compound droxy and adding to the polycarbonate which is the reaction product thereof: a sulfonic acid compound having the formula ##STR1## in an amount of 0.05-10 ppm, based on the polycarbonate, an epoxy compound in an amount of 1-2000 ppm, based on the polycarbonate and a phosphorus compound in an amount of 10-1000 ppm, based on the polycarbonate.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: March 5, 1996
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5489655
    Abstract: Thermosetting resin compositions with low shrinkage are provided, which when molded show low shrinkage rates, good dimensional stability (little cracking or warping), and excellent surface smoothness, mechanical strength, and dispersion stability.The thermosetting resin compositions with low shrinkage in accordance with the present invention comprise:(a) 100 wt. parts by weight thermosetting resins, and(b) 3 to 200 parts by weight polycarbonates containing constituent units derived from aromatic dihydroxy compounds.The polycarbonates preferably have at least 5% (of all the terminal groups) terminal hydroxyl groups derived from aromatic dihydroxy compounds. The polycarbonates also preferably have an intrinsic viscosity of 0.05 to 0.65 dL/g.
    Type: Grant
    Filed: July 26, 1993
    Date of Patent: February 6, 1996
    Assignee: General Electric Company
    Inventors: Tomoaki Shimoda, Kenichi Ishiwa
  • Patent number: 5484875
    Abstract: The present invention relates to a method for preparing copolymeric polycarbonates which comprises melt polycondensing a mixture of an aromatic dihydroxy compound containing an amount of 2-90 mol % of hydroquinone or substituted hydroquinones and a diester carbonate in the presence of a catalyst containing an alkali metal compound or an alkaline earth metal compound in an amount of 1.times.10.sup.-8 to 5.times.10.sup.-6 mole per mole of the total amount of the aromatic dihydroxy compound, then adding an acidic compound to the melt polycondensation product.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: January 16, 1996
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kotaro Kishimura, Shuichi Uchimura
  • Patent number: 5470938
    Abstract: A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: November 28, 1995
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kotaro Kishimura
  • Patent number: 5418315
    Abstract: The method of this invention prepares copolymeric polycarbonates which have excellent mechanical properties, heat resistance and transparency, and which also have improved chemical resistance, hue, and residence stability by inducing the melt polycondensation of an aromatic dihydroxy compound containing an amount of 2-90 mol % of hydroquinone and/or substituted hydroquinones with a diester carbonate in the presence of a catalyst containing alkali metal compounds and/or alkaline earth metal compounds in an amount of 1.times.10.sup.-8 to 5.times.10.sup.-6 mole per mole of the total amount of the aromatic dihydroxy compound.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: May 23, 1995
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kotaro Kishimura, Shuichi Uchimura
  • Patent number: 5405933
    Abstract: The present invention provides copolymerized polycarbonates having improved flow and formability, in addition to excellent mechanical properties, heat resistance, transparency, and water resistance obtained by copolymerization of two or more aromatic dihydroxy compounds and a compound capable of reacting with those aromatic dihydroxy compounds to form carbonate linkages, characterized in that, of all the constituent repeating units derived from aromatic dihydroxy compounds, 2-40 mole % are derived from resorcin and/or substituted resorcins.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: April 11, 1995
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5401826
    Abstract: A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
    Type: Grant
    Filed: December 21, 1993
    Date of Patent: March 28, 1995
    Assignee: General Electric Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kotaro Kishimura
  • Patent number: 5384388
    Abstract: [Purpose] The object of the present invention is to provide a method of product copolymerized polycarbonates having improved flow and formability, in addition to excellent mechanical properties, heat resistance, transparency, and color tone.[Constitution] A method of producing copolymerized polycarbonates by melt polycondensation of two or more aromatic dihydroxy compounds with a carbonate diester, characterized in that(i) resorcin and/or substituted resorcins are used as 2-90 mole % of the aromatic dihydroxy compounds, where the sum of all the aromatic dihydroxy compounds is taken as 100 mole %, and(ii) an alkali metal compound and/or an alkaline-earth metal compound (a) is used as the catalyst.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: January 24, 1995
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5371170
    Abstract: Polycarbonates are prepared by inducing the melt polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of alkali metal compounds and/or alkaline earth metal compound droxy and adding to the polycarbonate which is the reaction product thereof: a sulfonic acid compound having the formula ##STR1## in an amount to 0.05-10 ppm, based on the polycarbonate, and also an epoxy compound in an amount of 1-2000 ppm, based on the polycarbonate.
    Type: Grant
    Filed: February 23, 1994
    Date of Patent: December 6, 1994
    Assignee: GE Plastics Japan
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5364926
    Abstract: Object: The present invention was conceived in light of the above-described prior art. The object of this invention is to provide a method for preparing optical-grade polycarbonate compositions, which method is able to prepare with good productivity optical-grade polycarbonate compositions that have not only excellent clarity and water resistance, but also excellent retention stability such as heat stability and hue stability when molten and a low content of inclusions and impurities, and that undergo little heat deterioration.Constitution: The method for preparing optical-grade polycarbonate compositions according to this invention, which method comprises the melt-polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of a catalyst, followed by the addition of additives [B] while the polycarbonate [A] obtained as the reaction product is in a molten state, and mixing.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: November 15, 1994
    Assignee: GE Plastics, Japan, Ltd. (GEP)
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kimiyoshi Miura, Kenichi Tominari, Akio Kanezawa
  • Patent number: 5324809
    Abstract: The present invention relates to a method of preparing a copolymeric polycarbonate which comprises melt-polycondensing a mixture of an aromatic dihydroxy compound comprising hydroquinone or substituted hydroquinones and a diester carbonate in the presence of a catalyst containing alkali metal compounds and/or alkaline earth metal compounds.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: June 28, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kotaro Kishimura, Shuichi Uchimura
  • Patent number: 5306801
    Abstract: The present invention relates to a polycarbonate production method. More specifically, it relates to a polycarbonate production method that is capable of preparing polycarbonates which have excellent residence stability such as hue stability and heat stability at the time of molding, and which have particularly outstanding water resistance.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: April 26, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5286834
    Abstract: A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: February 15, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kotaro Kishimura
  • Patent number: 5276109
    Abstract: The present invention relates to an optical polycarbonate composition comprising a polycarbonate resin and a boron compound wherein the resulting composition undergoes little coloration during molding, and is capable of forming molded products having excellent transparency.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: January 4, 1994
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5276129
    Abstract: Disclosed herein are processes for the production of polycarbonates by melt polycondensation of an aromatic dihydroxy compound and a carbonic acid diester or a diphenyl carbonate compound wherein said polycondensation is carried out in the presence of from 0.05 to 15 mol %, based on 1 mole of the aromatic dihydroxy compound, of a phenol having from 10 to 40 carbon atoms, a carbonic acid diester having from 17 to 50 carbon atoms or a carbonic acid diester having from 13 to 16 carbon atoms, using a catalyst comprising (a) a nitrogen containing basic compound, (b) from 10.sup.-8 to 10.sup.-3 mole, based on 1 mole of the aromatic dihydroxy compound, of an alkali metal or alkaline earth metal compound, and (c) boric acid or boric ester. Also disclosed is a polycarbonate in which from 5 to 30% of its terminal groups are hydroxy groups and it has a sodium content of not more than 1 ppm and a chlorine content of not more than 20 ppm.
    Type: Grant
    Filed: June 19, 1992
    Date of Patent: January 4, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5187242
    Abstract: A polycarbonate composition which contains 60-95 parts by weight of a polycarbonate with a terminal hydroxyl group concentration of 5-95 mol % and 40-5 parts by weight of polyester.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: February 16, 1993
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai, Kotarou Kishimura
  • Patent number: 5151491
    Abstract: Disclosed herein are processes for the production of polycarbonates by melt polycondensation of an aromatic dihydroxy compound and a carbonic acid diester or a diphenyl carbonate compound wherein said polycondensation is carried out in the presence of from 0.05 to 15 mol %, based on 1 mole of the aromatic dihydroxy compound, of a phenol having from 10 to 40 carbon atoms, a carbonic acid diester having from 17 to 50 carbon atoms, or a carbonic acid diester having from 13 to 16 carbon atoms, using a catalyst comprising (a) a nitrogen containing basic compound, (b) from 10.sup.-8 to 10.sup.-3 mole, based on 1 mole of the aromatic dihydroxy compound, of an alkali metal or alkaline earth metal compound, and (c) boric acid or boric ester. Also disclosed is a polycarbonate in which from 5 to 30% of its terminal groups are hydroxy groups and it has a sodium content of not more than 1 ppm and a chlorine content of not more than 20 ppm.
    Type: Grant
    Filed: September 21, 1989
    Date of Patent: September 29, 1992
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5142018
    Abstract: A process for preparing polycarbonates according to the invention by melt polycondensation of aromatic dihydroxy compounds and carbonic acid diesters, is characterized by using an aromatic dihydroxy compound and a carbonic acid diester, wherein the combined content of hydrolyzable chlorine in those monomers falls within the particular range. Another process for preparing polycarbonates according to the invention by melt polycondensation of aromatic dihydroxy compounds and carbonic acid diesters, is characterized by using a catalyst comprising (a) a nitrogen containing basic compound and (b) aromatic dihydroxy compound of an alkali metal or alkaline earth metal compound, or (a) and (b) and (c) boric acid or boric ester.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: August 25, 1992
    Assignee: GE Plastics Japan Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5097002
    Abstract: A process for preparing polycarbonates according to the invention by melt polycondensation of aromatic dihydroxy compounds and carbonic acid diesters, is characterized by using an aromatic dihydroxy compound and a carbonic acid diester, wherein the combined content of hydrolyzable chlorine in those monomers falls within the particular range. Another process for preparing polycarbonates according to the invention by melt polycondensation of aromatic dihydroxy compounds and carbonic acid diesters, is characterized by using a catalyst comprising (a) a nitrogen containing basic compound and (b) aromatic dihydroxy compound of an alkali metal or alkaline earth metal compound, or (a) and (b) and (c) boric acid or boric ester.
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: March 17, 1992
    Assignee: GE Plastics Japan Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5068400
    Abstract: The novel fluorine-containing mono- or poly-alkylene glycol of this invention is a mono- or poly-alkylene glycol of the formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.
    Type: Grant
    Filed: June 29, 1988
    Date of Patent: November 26, 1991
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masahide Tanaka, Tokinori Agou, Masahiro Kuwahara, Takeshi Sakashita, Tomoaki Shimoda, Masaru Sudou