Abstract: Mesoporous carbon has a connecting structure in which primary particles made of carbon particles having primary pores with a primary pore diameter of less than 20 nm are connected. In the mesoporous carbon, the pore capacity of secondary pores with secondary pore diameters within a range of 20 nm to 100 nm, which is measured by a mercury intrusion method, is 0.42 cm3/g or more and 1.34 cm3/g or less. In addition, the mesoporous carbon has a linearity of 2.2 or more and 2.6 or less. An electrode catalyst for a fuel cell includes the mesoporous carbon and catalyst particles supported in the primary pores in the mesoporous carbon. Furthermore, a catalyst layer includes the electrode catalyst for the fuel cell and a catalyst layer ionomer.

Abstract: A cleaning liquid for removing a cerium compound contains (A) a six-membered ring compound having two or more hydroxy groups, and (B) an inorganic acid compound, and a mass ratio of the component (B) to the component (A) is 0.05 to 0.6. The component (A) may contain at least one selected from the group consisting of catechol, resorcinol, hydroquinone, pyrogallol, and methylcatechol.

Abstract: Mesoporous carbon has a beaded structure in which primary particles with mesopores are linked. In the mesoporous carbon, an average primary particle size is 7 nm or more and 300 nm or less, a pore diameter is 2 nm or more and 10 nm or less, an average thickness of pore walls is 3 nm or more and 15 nm or less, a pore volume is 0.2 mL/g or more and 3.0 mL/g or less, and a tap density is 0.03 g/cm3 or more and 0.3 g/cm3 or less. In a polymer electrolyte fuel cell, the mesoporous carbon is used as a catalyst carrier for at least an air electrode catalyst layer. The mesoporous carbon can be obtained by impregnating mesoporous silica satisfying a predetermined condition with a carbon source, performing polymerization and carbonization, and removing a template.

Abstract: [Problem] To provide a practical solid polymer fuel cell having high cell performance and excellent durability. [Means for solving] The polymer electrolyte fuel cell according to the present invention includes: a membrane electrode assembly in which electrodes each including a catalyst layer are joined to both surfaces of an electrolyte membrane; and a peroxide decomposition catalyst which is fixed to the electrolyte membrane and/or the electrodes and includes a hardly soluble carbide, a boride, and/or a silicide. The peroxide decomposition catalyst preferably contains a carbide, a boride and/or a silicide of a rare earth element, a transition metal element or a typical metal element.

Abstract: Mesoporous carbon has a beaded structure in which primary particles with mesopores are linked. In the mesoporous carbon, an average primary particle size is 7 nm or more and 300 nm or less, a pore diameter is 2 nm or more and 10 nm or less, an average thickness of pore walls is 3 nm or more and 15 nm or less, a pore volume is 0.2 mL/g or more and 3.0 mL/g or less, and a tap density is 0.03 g/cm3 or more and 0.3 g/cm3 or less. In a polymer electrolyte fuel cell, the mesoporous carbon is used as a catalyst carrier for at least an air electrode catalyst layer. The mesoporous carbon can be obtained by impregnating mesoporous silica satisfying a predetermined condition with a carbon source, performing polymerization and carbonization, and removing a template.

Abstract: To provide an electrocatalyst for fuel cells, which is configured to ensure both the initial performance and durability of fuel cells. An electrocatalyst for fuel cells, wherein the electrocatalyst comprises a carbon support including a mesopore and a catalyst alloy supported on the carbon support, and the catalyst alloy is a catalyst alloy of platinum and a transition metal; wherein the mesopore includes at least one throat; wherein an average effective diameter of the at least one throat is 1.8 nm or more and less than 3.2 nm; and wherein a transition metal ratio of the catalyst alloy supported on a deeper-side region than the at least one throat, is lower than the transition metal ratio of the catalyst alloy supported on a nearer-side region than the at least one throat.

Abstract: The present embodiment is a catalyst for a fuel cell including: a catalyst metal; and a carrier that supports the catalyst metal, in which an outer surface area of the carrier to an inner surface area of the carrier, which is a ratio between the inner and outer surface areas of the carrier, is 0.56 to 0.69, and a proportion of the catalyst metal supported on an outer surface of the carrier is 23% to 35%.

Abstract: Porous oxide semiconductor particles have a connected structure in which porous primary particles having an aggregate of crystallites composed of an oxide semiconductor are connected to each other and have a specific surface area of 60 m2/g or more. The porous oxide semiconductor particles have preferably a pore diameter of 1 nm or more and 20 nm or less. The porous oxide semiconductor particles have preferably a tap density of 0.005 g/cm3 or more and 1.0 g/cm3 or less. The oxide semiconductor is preferably SnO2 or SnO2 doped with at least one element selected from the group consisting of Nb, Sb, W, Ta, and Al.

Abstract: To provide a carbon support for catalysts for fuel cells, which increases the power generation performance of fuel cells, a catalyst for fuel cells, a catalyst layer for fuel cells, and a method for producing the carbon support. A carbon support for catalysts for fuel cells, wherein the carbon support includes at least one pore; wherein a thickness of a carbon wall of the carbon support, which is derived from a three-dimensional pore structure of a silica mold obtained by pore volume measurement of the silica mold by nitrogen adsorption analysis, is 3.3 nm or more and 11.2 nm or less; and wherein a carbon wall content is more than 60.3 ml/g and less than 190.8 ml/g.

Abstract: A catalyst layer includes an electrode catalyst and an ionomer. The electrode catalyst includes: tin oxide-based particles having a structure (connected structure) in which porous primary particles are connected to each other in a bead shape and having a specific surface area of 30 m2/g or more; and Pt-based fine particles supported on the surface of the tin oxide-based particles. The conductivity of a green compact composed of the tin oxide-based particles is desirably 1×10?3 S/cm or more. As the tin oxide-based particles, those composed of Sb-doped SnO2 and having a specific surface area of 90 m2/g or more and a pore diameter of 5 nm or more and 8 nm or less are desired.

Abstract: Mesoporous carbon includes a linked structure in which carbon particles are linked. The carbon particles have primary pores and are primary particles. An average entrance diameter of the primary pores is 2.0 nm or more and 3.0 nm or less. An average constriction diameter of the primary pores is 1.6 nm or more and 2.4 nm or less. An electrode catalyst for a fuel cell includes the mesoporous carbon and catalyst particles supported in the primary pores of the mesoporous carbon. A catalyst layer includes the electrode catalyst for a fuel cell and a catalyst layer ionomer.

Abstract: Mesoporous carbon has a connecting structure in which primary particles made of carbon particles having primary pores with a primary pore diameter of less than 20 nm are connected. In the mesoporous carbon, the pore capacity of secondary pores with secondary pore diameters within a range of 20 nm to 100 nm, which is measured by a mercury intrusion method, is 0.42 cm3/g or more and 1.34 cm3/g or less. In addition, the mesoporous carbon has a linearity of 2.2 or more and 2.6 or less. An electrode catalyst for a fuel cell includes the mesoporous carbon and catalyst particles supported in the primary pores in the mesoporous carbon. Furthermore, a catalyst layer includes the electrode catalyst for the fuel cell and a catalyst layer ionomer.

Abstract: To provide an electrocatalyst for fuel cells, which is configured to ensure both the initial performance and durability of fuel cells. An electrocatalyst for fuel cells, wherein the electrocatalyst comprises a carbon support including a mesopore and a catalyst alloy supported on the carbon support, and the catalyst alloy is a catalyst alloy of platinum and a transition metal; wherein the mesopore includes at least one throat; wherein an average effective diameter of the at least one throat is 1.8 nm or more and less than 3.2 nm; and wherein a transition metal ratio of the catalyst alloy supported on a deeper-side region than the at least one throat, is lower than the transition metal ratio of the catalyst alloy supported on a nearer-side region than the at least one throat.

Abstract: Mesoporous carbon has a beaded structure in which primary particles with mesopores are linked. In the mesoporous carbon, an average primary particle size is 7 nm or more and 300 nm or less, a pore diameter is 2 nm or more and 10 nm or less, an average thickness of pore walls is 3 nm or more and 15 nm or less, a pore volume is 0.2 mL/g or more and 3.0 mL/g or less, and a tap density is 0.03 g/cm3 or more and 0.3 g/cm3 or less. In a polymer electrolyte fuel cell, the mesoporous carbon is used as a catalyst carrier for at least an air electrode catalyst layer. The mesoporous carbon can be obtained by impregnating mesoporous silica satisfying a predetermined condition with a carbon source, performing polymerization and carbonization, and removing a template.

Abstract: Disclosed herein is a solid polymer electrolyte wherein protons of cation exchange groups contained in a perfluorinated electrolyte are partially replaced by metal ions. The metal ion is at least one metal ion selected from vanadium (V), manganese (Mn), niobium (Nb), tantalum (Ta), chromium (Cr), molybdenum (Mo), tungsten (W), iron (Fe), ruthenium (Ru), nickel (Ni), palladium (Pd), platinum (Pt), silver (Ag), cerium (Ce), neodymium (Nd), praseodymium (Pr), samarium (Sm), cobalt (Co), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), and erbium (Er) ions. Further disclosed is a solid polymer fuel cell using the solid polymer electrolyte.

Abstract: Disclosed herein is a solid polymer electrolyte wherein protons of cation exchange groups contained in a perfluorinated electrolyte are partially replaced by metal ions. The metal ion is at least one metal ion selected from vanadium (V), manganese (Mn), niobium (Nb), tantalum (Ta), chromium (Cr), molybdenum (Mo), tungsten (W), iron (Fe), ruthenium (Ru), nickel (Ni), palladium (Pd), platinum (Pt), silver (Ag), cerium (Ce), neodymium (Nd), praseodymium (Pr), samarium (Sm), cobalt (Co), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), and erbium (Er) ions. Further disclosed is a solid polymer fuel cell using the solid polymer electrolyte.

Abstract: To improve oxidation resistance of an electrolyte membrane and durability thereof by a low-cost method, thereby improving durability of a polymer electrolyte fuel cell. According to the present invention, in the polymer electrolyte fuel cell having a membrane-electrode assembly including a polymer electrolyte membrane and electrodes bonded to both sides of the polymer electrolyte membrane, phosphate containing at least one metallic element selected from a rare earth element, Ti, Fe, Al and Bi is fixed to at least one of the polymer electrolyte membrane and the electrodes.