Patents by Inventor Tomoyuki Hirayama

Tomoyuki Hirayama has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20160085151
    Abstract: The present invention provides a photosensitive epoxy resin composition which contains: (A) a cresol novolak polyfunctional epoxy resin; (B) a liquid epoxy resin having a fluorene skeleton in its main chain; and (C) a photoacid generator; wherein the components (A) and (B) are present in a mixing weight ratio of (A)/(B)=40/60 to 60/40. Where the inventive photosensitive epoxy resin composition is used as an optical waveguide forming material, particularly as an optical waveguide core layer forming material for formation of a core layer, the optical waveguide core layer can be formed as having excellent reflow resistance and a lower loss through a coating process and a roll-to-roll process without altering the conventional production process.
    Type: Application
    Filed: March 11, 2014
    Publication date: March 24, 2016
    Applicant: NITTO DENKO CORPORATION
    Inventors: Tomoyuki Hirayama, Naoyuki Tanaka
  • Publication number: 20160070029
    Abstract: The present invention provides a photosensitive epoxy resin composition for an optical waveguide. The photosensitive epoxy resin composition contains: (A) a cresol novolak polyfunctional epoxy resin, the cresol novolak polyfunctional epoxy resin not being fluorene skeleton-containing epoxy resins (C) and (D); (B) a solid bisphenol-A epoxy resin; (C) a solid fluorene skeleton-containing epoxy resin; (D) a liquid fluorene skeleton-containing epoxy resin; and (E) a cationic curing initiator, wherein the components (A) to (E) are each present in a proportion falling within a predetermined range based on the amount of the overall epoxy resin component. Therefore, the photosensitive epoxy resin composition is excellent in coatability, patterning resolution, roll-to-roll process adaptability and the like, and has higher transparency and heat resistance.
    Type: Application
    Filed: March 11, 2014
    Publication date: March 10, 2016
    Applicant: NITTO DENKO CORPORATION
    Inventor: Tomoyuki Hirayama
  • Publication number: 20150354904
    Abstract: A clearance (C) is provided between the inner circumferential surface of cylindrical stubs (22) (which protrude toward the outlet-side and inlet-side water chambers (14, 15) of outlet-side and inlet-side tube plates (11a, 11b)) and the outer circumferential surface at the end part of heat transfer tubes (12) inserted into the stubs (22), and the end faces of the inside tube parts (24a) and the outside tube parts (24b) of grooved end pieces (24) are laser-welded to the end faces of the heat transfer tubes (12) and the stubs (22) from the inner-surface side of the heat transfer tube (12), with the weld height of the end faces of the outside tube parts (24b) and the end faces of the stubs (22) and the weld height of the end faces of the inside tube parts (24a) and the end faces of the heat transfer tubes (12) corresponding to each other, thereby enabling butt-welding to be performed in one pass.
    Type: Application
    Filed: February 7, 2014
    Publication date: December 10, 2015
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Shinya Ogumo, Yukinori Usui, Tomoyuki Hirayama, Kazuhiko Kamo
  • Patent number: 9086534
    Abstract: There are provided an optical waveguide forming resin composition, an optical waveguide and a light transmission flexible printed board both produced by using the composition, and a production method for the optical waveguide, wherein the resin composition is superior in coatability, capable of omitting a solvent drying step in coating film formation, and suitable as a material for forming an optical waveguide which allows only a low waveguide loss and which has a higher Tg and higher flexibility. An optical waveguide forming resin composition comprises the following components (A) through (D), wherein the optical waveguide forming resin composition is free from a solid resin component and the viscosity thereof under a 25° C. environment is within the range of 10 to 20 mPa·s: (A) a liquid oxetane compound; (B) a liquid epoxy compound; (C) an alkylene glycol; and (D) a photoacid generator.
    Type: Grant
    Filed: November 6, 2013
    Date of Patent: July 21, 2015
    Assignee: NITTO DENKO CORPORATION
    Inventor: Tomoyuki Hirayama
  • Patent number: 9075303
    Abstract: An excellent optical waveguide forming epoxy resin composition is provided, comprising: (A) a liquid epoxy resin; (B) a solid resin; and (C) a photoacid generator; wherein the liquid epoxy resin (A) comprises a liquid epoxy resin represented by the following general formula (1) as a major component thereof in a proportion of 50 to 80 wt % based on an overall amount of a resin component of the resin composition: wherein R1 and R2 are each a hydrogen atom or a methyl group; R3 to R6 are each a hydrogen atom, a methyl group, a chlorine atom or a bromine atom; X is a C2 to C15 alkylene group, an ethyleneoxy group, a di(ethyleneoxy) group, a tri(ethyleneoxy) group, a propyleneoxy group, a propyleneoxypropyl group, a di(propyleneoxy) propyl group or a tri(propyleneoxy)propyl group; and n is a natural number and has an average value of 1.2 to 5.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: July 7, 2015
    Assignee: NITTO DENKO CORPORATION
    Inventor: Tomoyuki Hirayama
  • Patent number: 9034566
    Abstract: A resin composition for forming an optical waveguide brings together excellent bending resistance, a low refractive index, and low tackiness suitable for a roll-to-roll (R-to-R) process as a material for forming an optical waveguide, in particular, a material for forming a clad layer. The resin composition for forming an optical waveguide to be used in formation of an optical waveguide includes a polyvinyl acetal compound having a structural unit represented by the following general formula (1) as a main component: in the formula (1), R represents an alkyl group having 1 to 3 carbon atoms, and k, m, and n represent ratios of respective repeating units in a main chain and each represent an integer of 1 or more.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: May 19, 2015
    Assignee: NITTO DENKO CORPORATION
    Inventors: Tomoyuki Hirayama, Takami Hikita
  • Publication number: 20150075677
    Abstract: An aluminum alloy sheet which has high strength enabling application to automobile body sheet and which is excellent in press-formability and shape fixability and a method of production of the same are provided. Aluminum alloy sheet having a composition of ingredients which contains Mg, Fe, and Ti, restricts the impurity Si to less than 0.20 mass %, and has a balance of Al and unavoidable impurities and a metal structure with an average grain size of less than 15 ?m and having second phase particles with a circle equivalent diameter of 3 ?m or more in a number of less than 300/mm2 and having a tensile strength of 240 MPa or more, a yield strength of less than 130 MPa, an elongation of 30% or more, and a plane strain fracture limit at a strain rate of 20/sec of 0.20 or more.
    Type: Application
    Filed: January 10, 2013
    Publication date: March 19, 2015
    Inventors: Tomoyuki Hirayama, Takeshi Handa, Toshiya Anami
  • Patent number: 8901196
    Abstract: A liquid resin composition is provided which satisfies both a tackiness-free requirement and a curing sensitivity requirement for production of an optical waveguide by a roll-to-roll process. An optical waveguide produced by using the liquid resin composition and a production method of the optical waveguide are also provided. The liquid resin composition for the production of the optical waveguide comprises: (A) a (meth)acrylate polymer, as a major component, having a plurality of (meth)acryl groups in its molecule; (B) a liquid thiol monomer having a plurality of thiol groups in its molecule; and (C) a photopolymerization initiator.
    Type: Grant
    Filed: January 6, 2011
    Date of Patent: December 2, 2014
    Assignee: Nitto Denko Corporation
    Inventor: Tomoyuki Hirayama
  • Patent number: 8867885
    Abstract: An optical waveguide forming epoxy resin composition is free from a diluent component irrelevant to a curing reaction, and comprises: (A) a liquid epoxy resin; and (B) a photoacid generator; wherein the liquid epoxy resin (A) comprises a liquid epoxy resin represented by the following general formula (1) in a proportion of 40 to 75 wt % based on the overall amount of a resin component: wherein R1 and R2 are each a hydrogen atom or a methyl group; R3 to R6 are each a hydrogen atom, a methyl group, a chlorine atom or a bromine atom; X is a C2 to C15 alkylene group, an ethyleneoxy group, a di(ethyleneoxy) group, a tri(ethyleneoxy) group, a propyleneoxy group, a propyleneoxypropyl group, a di(propyleneoxy)propyl group or a tri(propyleneoxy)propyl group; and n is a natural number and has an average value of 1.2 to 5.
    Type: Grant
    Filed: March 12, 2013
    Date of Patent: October 21, 2014
    Assignee: Nitto Denko Corporation
    Inventor: Tomoyuki Hirayama
  • Publication number: 20140166162
    Abstract: An aluminum alloy sheet includes an aluminum alloy substrate having a composition containing, by mass percentage, 3.0 to 4.0% of magnesium, 0.2 to 0.4% of manganese, 0.1 to 0.5% of iron, not less than 0.03% but less than 0.10% of copper, and less than 0.20% of silicon, with the remainder being aluminum and unavoidable impurities. A peak concentration of a copper concentration distribution in a thickness direction in a region at a depth of 15 nm to 200 nm from the surface of the aluminum alloy substrate is equal to or more than 0.15%, and the aluminum alloy substrate has a recrystallized structure with an average grain size of 15 ?m or less.
    Type: Application
    Filed: July 10, 2012
    Publication date: June 19, 2014
    Inventors: Tomoyuki Hirayama, Pizhi Zhao, Takeshi Handa, Toshiya Anami, Yusuke Nagaishi, Koji Itakura, Hirokazu Miyagawa, Tsutomu Hattori, Shigenori Yoshizawa, Akio Yoshizawa
  • Patent number: 8741399
    Abstract: The birefringent film of the present invention contains an aromatic polyester having a repeating unit represented by the following general formula (1). In the general formula (1), A(s), B(s), C(s), and D(s) are each independently represent a group selected from a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Also, a and b each represent an integer of 0 to 4, and c and d each represent an integer of 0 to 3. R1 represents a hydrogen atom, or an alkyl group which has 1 to 10 carbon atoms. R2 represents an alkyl group which has 2 to 10 carbon atoms. R3 to R6 each independently represent a group or atom selected from a hydrogen atom, a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Furthermore, l and m each represent an integer of 2 or more.
    Type: Grant
    Filed: March 25, 2009
    Date of Patent: June 3, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Tomoyuki Hirayama, Toshiyuki Iida, Yutaka Ohmori, Satoru Suzuki, Miyuki Kurogi, Hisae Shimizu
  • Publication number: 20140140672
    Abstract: There are provided an optical waveguide forming resin composition, an optical waveguide and a light transmission flexible printed board both produced by using the composition, and a production method for the optical waveguide, wherein the resin composition is superior in coatability, capable of omitting a solvent drying step in coating film formation, and suitable as a material for forming an optical waveguide which allows only a low waveguide loss and which has a higher Tg and higher flexibility. An optical waveguide forming resin composition comprises the following components (A) through (D), wherein the optical waveguide forming resin composition is free from a solid resin component and the viscosity thereof under a 25° C. environment is within the range of 10 to 20 mPa·s: (A) a liquid oxetane compound; (B) a liquid epoxy compound; (C) an alkylene glycol; and (D) a photoacid generator.
    Type: Application
    Filed: November 6, 2013
    Publication date: May 22, 2014
    Applicant: NITTO DENKO CORPORATION
    Inventor: Tomoyuki Hirayama
  • Patent number: 8652569
    Abstract: An optical waveguide production method is provided which reduces a transmission loss, improves alignment mark visual detectability, and ensures excellent productivity. In the optical waveguide production method, an under-cladding layer, a core and an alignment mark are formed on a surface of a metal substrate. On the other hand, a molding die is prepared which includes a cavity and an alignment mark to be associated with the alignment mark. In turn, light emitted from the side of the molding die is utilized for positioning the metal substrate and the molding die with reference to the pair of associated alignment marks. Then, an over-cladding layer is formed over the core. The alignment mark is formed from a photo-curable composition comprising the following components (A) and (B): (A) a polymerizable composition having a (meth)acrylate group; and (B) a photoradical polymerization initiator.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: February 18, 2014
    Assignee: Nitto Denko Corporation
    Inventor: Tomoyuki Hirayama
  • Patent number: 8642250
    Abstract: A resin composition for an optical waveguide is provided, which has excellent adhesiveness to a cladding layer of the optical waveguide and excellent patternability for formation of a core portion of the optical waveguide and reduces the optical waveguide loss. An optical waveguide produced by using the resin composition is also provided. The resin composition comprises: (A) a multifunctional partially-acrylated epoxy resin, as a major component, having an epoxy group and a (meth)acrylate group in the same main chain thereof; and (B) a photopolymerization initiator as a curing component. The optical waveguide includes: a substrate; a cladding layer provided on the substrate; and a core portion provided on the cladding layer for transmission of an optical signal; wherein the core portion is formed from the resin composition.
    Type: Grant
    Filed: November 15, 2011
    Date of Patent: February 4, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Tomoyuki Hirayama, Junichi Fujisawa
  • Patent number: 8593599
    Abstract: [Object] The present invention provides a liquid crystal panel with which a display with extremely small change in color depending on a viewing direction can be realized, and a liquid crystal display including the same. [Solution to Problem] The liquid crystal panel includes: a first polarizer 30; a second polarizer 50; a first optical compensation layer 60; a second optical compensation layer 70; and a liquid crystal cell 40. The first polarizer 30 is arranged on one surface of the liquid crystal cell 40. The second polarizer 50 is arranged on the other surface of the liquid crystal cell 40. The first optical compensation layer 60 is arranged between the liquid crystal cell 40 and the first polarizer 30. The second optical compensation layer 70 is arranged between the liquid crystal cell 40 and the second polarizer 50. The first optical compensation layer 60 satisfies the following mathematical formulae (1) and (2).
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: November 26, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Toshiyuki Iida, Tomoyuki Hirayama, Yutaka Ohmori, Miyuki Kurogi, Hisae Shimizu, Junichi Nagase
  • Patent number: 8586286
    Abstract: A resin composition for an optical waveguide is provided, which permits easy formation of a core pattern using an alkali developing liquid and suppresses degradation of the alkali developing liquid. An optical waveguide produced by using the resin composition is provided. The resin composition comprises: (A) an alkali soluble resin, as a major component, having a structural unit represented by formula (1): wherein R1, R2 and R3, which may be the same or different, are each a hydrogen atom or a methyl group; R5 and R6, which may be the same or different, are each a hydrogen atom or a methyl group; R4 is and m+n+p=1, m>0, n>0 and p>0; and (B) a photopolymerization initiator. The optical waveguide includes a substrate, a cladding layer provided thereon, and a core portion provided in the cladding layer for transmitting an optical signal.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: November 19, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Junichi Fujisawa, Tomoyuki Hirayama
  • Publication number: 20130287351
    Abstract: An optical waveguide forming epoxy resin composition is free from a diluent component irrelevant to a curing reaction, and comprises: (A) a liquid epoxy resin; and (B) a photoacid generator; wherein the liquid epoxy resin (A) comprises a liquid epoxy resin represented by the following general formula (1) in a proportion of 40 to 75 wt % based on the overall amount of a resin component: wherein R1 and R2 are each a hydrogen atom or a methyl group; R3 to R6 are each a hydrogen atom, a methyl group, a chlorine atom or a bromine atom; X is a C2 to C15 alkylene group, an ethyleneoxy group, a di(ethyleneoxy) group, a tri(ethyleneoxy) group, a propyleneoxy group, a propyleneoxypropyl group, a di(propyleneoxy)propyl group or a tri(propyleneoxy)propyl group; and n is a natural number and has an average value of 1.2 to 5.
    Type: Application
    Filed: March 12, 2013
    Publication date: October 31, 2013
    Applicant: NITTO DENKO CORPORATION
    Inventor: Tomoyuki Hirayama
  • Patent number: 8568893
    Abstract: An ester-based polymer to be used in the present invention has at least a repeating unit represented with the general formula (I). A and B are substituents substituted on a stilbene group. R1 is a hydrogen atom, a linear or branched alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group. R2 is a linear or branched alkyl group having 2 to 10 carbon atoms. R3 to R6 each independently represents a hydrogen atom, a halogen atom, a linear or branched alkyl group having 1 to 6 carbon atoms, or a substituted or unsubstituted aryl group. n is an integer of 2 or more.
    Type: Grant
    Filed: January 27, 2009
    Date of Patent: October 29, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Tomoyuki Hirayama, Toshiyuki Iida, Yutaka Ohmori, Satoru Suzuki, Miyuki Kurogi, Hisae Shimizu
  • Publication number: 20130236149
    Abstract: An excellent optical waveguide forming epoxy resin composition is provided, comprising: (A) a liquid epoxy resin; (B) a solid resin; and (C) a photoacid generator; wherein the liquid epoxy resin (A) comprises a liquid epoxy resin represented by the following general formula (1) as a major component thereof in a proportion of 50 to 80 wt % based on an overall amount of a resin component of the resin composition: wherein R1 and R2 are each a hydrogen atom or a methyl group; R3 to R6 are each a hydrogen atom, a methyl group, a chlorine atom or a bromine atom; X is a C2 to C15 alkylene group, an ethyleneoxy group, a di(ethyleneoxy) group, a tri(ethyleneoxy) group, a propyleneoxy group, a propyleneoxypropyl group, a di(propyleneoxy) propyl group or a tri(propyleneoxy)propyl group; and n is a natural number and has an average value of 1.2 to 5.
    Type: Application
    Filed: March 5, 2013
    Publication date: September 12, 2013
    Applicant: NITTO DENKO CORPORATION
    Inventor: Tomoyuki Hirayama
  • Patent number: 8518552
    Abstract: The invention relates to an optical film containing polymers having different repeating units, and methods for production thereof. Further, the invention also relates to an optical laminate, a polarizing plate, and an image display device each using the optical film. The optical film of the invention advantageously has not only high solubility in solvents but also a high level of transparency since the polymers used in the optical film are compatible with each other. Further, wavelength dispersion of the birefringence of the optical film can be controlled by merely changing a ratio of polymers.
    Type: Grant
    Filed: March 11, 2010
    Date of Patent: August 27, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Toshiyuki Iida, Tomoyuki Hirayama, Yutaka Ohmori, Miyuki Kurogi, Hisae Shimizu, Junichi Nagase