Abstract: A three-dimensional memory device includes an alternating stack of insulating layers and electrically conductive layers located over a substrate and memory stack structures extending through the alternating stack. Each of the electrically conductive layers includes a stack of a compositionally graded diffusion barrier and a metal fill material portion, and the compositionally graded diffusion barrier includes a substantially amorphous region contacting the interface between the compositionally graded diffusion barrier and a substantially crystalline region that is spaced from the interface by the amorphous region. The substantially crystalline region effectively blocks atomic diffusion, and the amorphous region induces formation of large grains during deposition of the metal fill material portions.

Abstract: An alternating stack of insulating layers and sacrificial material layers is formed over a substrate. Memory openings are formed through the alternating stack. A layer stack including a charge storage layer, a tunneling dielectric layer, a semiconductor material layer, and a dielectric material layer is formed in the memory openings. The dielectric material layer may include a doped silicate glass layer. A doped silicate glass pillar can be formed at a bottom portion of each memory opening, and a bottom portion of the semiconductor material layer can be converted into a source region by outdiffusion of dopants from the doped silicate glass pillar. Alternatively, the semiconductor material layer can be heavily doped, and can be recessed to form a source region.

Abstract: An alternating stack of insulating layers and sacrificial material layers is formed over a substrate. Memory openings are formed through the alternating stack. A layer stack including a charge storage layer, a tunneling dielectric layer, a semiconductor material layer, and a dielectric material layer is formed in the memory openings. The dielectric material layer may include a doped silicate glass layer. A doped silicate glass pillar can be formed at a bottom portion of each memory opening, and a bottom portion of the semiconductor material layer can be converted into a source region by outdiffusion of dopants from the doped silicate glass pillar. Alternatively, the semiconductor material layer can be heavily doped, and can be recessed to form a source region.

Abstract: An alternating stack of insulating layers and sacrificial material layers is formed over a substrate. Memory openings are formed through the alternating stack. A layer stack including a charge storage layer, a tunneling dielectric layer, a semiconductor material layer, and a dielectric material layer is formed in the memory openings. The dielectric material layer may include a doped silicate glass layer. A doped silicate glass pillar can be formed at a bottom portion of each memory opening, and a bottom portion of the semiconductor material layer can be converted into a source region by outdiffusion of dopants from the doped silicate glass pillar. Alternatively, the semiconductor material layer can be heavily doped, and can be recessed to form a source region.

Abstract: An alternating stack of insulating layers and sacrificial material layers is formed over a substrate. Memory openings are formed through the alternating stack. A layer stack including a charge storage layer, a tunneling dielectric layer, a semiconductor material layer, and a dielectric material layer is formed in the memory openings. The dielectric material layer may include a doped silicate glass layer. A doped silicate glass pillar can be formed at a bottom portion of each memory opening, and a bottom portion of the semiconductor material layer can be converted into a source region by outdiffusion of dopants from the doped silicate glass pillar. Alternatively, the semiconductor material layer can be heavily doped, and can be recessed to form a source region.

Abstract: A three-dimensional memory device includes an alternating stack of insulating layers and electrically conductive layers located over a substrate and memory stack structures extending through the alternating stack. Each of the electrically conductive layers includes a stack of a compositionally graded diffusion barrier and a metal fill material portion, and the compositionally graded diffusion barrier includes a substantially amorphous region contacting the interface between the compositionally graded diffusion barrier and a substantially crystalline region that is spaced from the interface by the amorphous region. The substantially crystalline region effectively blocks atomic diffusion, and the amorphous region induces formation of large grains during deposition of the metal fill material portions.

Abstract: A three-dimensional memory device includes an alternating stack of insulating layers and electrically conductive layers located over a substrate and memory stack structures extending through the alternating stack. Each of the electrically conductive layers includes a stack of a compositionally graded diffusion barrier and a metal fill material portion, and the compositionally graded diffusion barrier includes a substantially amorphous region contacting the interface between the compositionally graded diffusion barrier and a substantially crystalline region that is spaced from the interface by the amorphous region. The substantially crystalline region effectively blocks atomic diffusion, and the amorphous region induces formation of large grains during deposition of the metal fill material portions.

Abstract: A three-dimensional memory device includes an alternating stack of insulating layers and electrically conductive layers located over a substrate and memory stack structures extending through the alternating stack. Each of the electrically conductive layers includes a stack of a compositionally graded diffusion barrier and a metal fill material portion, and the compositionally graded diffusion barrier includes a substantially amorphous region contacting the interface between the compositionally graded diffusion barrier and a substantially crystalline region that is spaced from the interface by the amorphous region. The substantially crystalline region effectively blocks atomic diffusion, and the amorphous region induces formation of large grains during deposition of the metal fill material portions.

Abstract: A first field effect transistor and a second field effect transistor are formed on a substrate. A silicon nitride liner is formed over the first field effect transistor and the second field effect transistor. An upper portion of the silicon nitride liner is converted into a thermal silicon oxide liner. A lower portion of the silicon nitride liner remains as a silicon nitride material portion. A first portion of the thermal silicon oxide liner is removed from above the second field effect transistor, and a second portion of the thermal silicon oxide liner remains above the first field effect transistor. Selective presence of the silicon oxide liner provides differential stress within the channels of the first and second field effect transistors, which can be employed to optimize performance of different types of field effect transistors.

Abstract: A method of forming a three-dimensional memory device includes forming an alternating stack of insulating layers and sacrificial material layers over a substrate, forming memory stack structures through the alternating stack, such that each of the memory stack structures includes a memory film and a vertical semiconductor channel, forming backside recesses by removing the sacrificial material layers selective to the insulating layers and the memory stack structures, forming a backside blocking dielectric layer in the backside recesses, forming an amorphous titanium oxide layer on surfaces of the backside blocking dielectric layer in the backside recesses, and forming tungsten word lines in the backside recesses using a fluorine-free tungsten-containing precursor gas.

Abstract: An alternating stack of insulating layers and spacer material layers is formed over a semiconductor substrate. Memory openings are formed through the alternating stack. An optional silicon-containing epitaxial pedestal and a memory film are formed in each memory opening. After forming an opening through a bottom portion of the memory film within each memory opening, a germanium-containing semiconductor layer and a dielectric layer is formed in each memory opening. Employing the memory film and the dielectric layer as a crucible, a liquid phase epitaxy anneal is performed to convert the germanium-containing semiconductor layer into a germanium-containing epitaxial channel layer. A dielectric core and a drain region can be formed over the dielectric layer. The germanium-containing epitaxial channel layer is single crystalline, and can provide a higher charge carrier mobility than a polysilicon channel.

Abstract: A method is provided that includes forming a word line above a substrate, the word line disposed in a first direction, forming a bit line above the substrate, the bit line disposed in a second direction perpendicular to the first direction, forming a nonvolatile memory material between the word line and the bit line by selectively forming a conductive oxide material layer adjacent the word line, and forming a semiconductor material layer adjacent the bit line, and forming a memory cell comprising the nonvolatile memory material at an intersection of the bit line and the word line.

Abstract: An alternating stack of insulating layers and spacer material layers is formed over a semiconductor substrate. Memory openings are formed through the alternating stack. An optional silicon-containing epitaxial pedestal and a memory film are formed in each memory opening. After forming an opening through a bottom portion of the memory film within each memory opening, a germanium-containing semiconductor layer and a dielectric layer is formed in each memory opening. Employing the memory film and the dielectric layer as a crucible, a liquid phase epitaxy anneal is performed to convert the germanium-containing semiconductor layer into a germanium-containing epitaxial channel layer. A dielectric core and a drain region can be formed over the dielectric layer. The germanium-containing epitaxial channel layer is single crystalline, and can provide a higher charge carrier mobility than a polysilicon channel.

Abstract: A method of forming a laminated film includes forming a silicon oxide film on a plurality of target objects loaded in a reaction chamber, and forming a silicon oxynitride film on the plurality of target objects by supplying a silicon source, an oxidizing agent and a nitride agent to the reaction chamber, wherein forming the silicon oxide film and forming the silicon oxynitride film are repeatedly performed for a predetermined number of times on the plurality of target objects to form a laminated film including the silicon oxynitride film and the silicon oxide film.

Abstract: Electrically conductive layers for control gate electrodes of a vertical memory device can be vertically spaced by cavities to reduce capacitive coupling between neighboring electrically conductive gate electrodes. An alternating stack of first material layers and second material layers can be provided. After replacing the second material layers with electrically conductive layers, the first material layers can be removed to form cavities between the electrically conductive layers. A dielectric material can be deposited with high anisotropic deposition rate to form an insulating spacer. For example, a plasma assisted atomic layer deposition process can be employed to deposit a dielectric spacer that include laterally protruding portions that encapsulate the cavities at each level between neighboring pairs of electrically conductive layers. A contact via structure can be formed in the insulating spacer to provide electrical contact to a source region.

Abstract: According to an embodiment of present disclosure, a method of forming a carbon film on a substrate to be processed is provided. The method includes loading a substrate to be processed with a carbon film formed thereon into a processing chamber of a film forming apparatus (Process 1), and thermally decomposing a hydrocarbon-based carbon source gas in the processing chamber to form a carbon film on the substrate to be processed (Process 2). In Process 2, a film forming temperature of the carbon film is set to a temperature less than a thermal decomposition temperature of a simple substance of the hydrocarbon-based carbon source gas without plasma assistance, the hydrocarbon-based carbon source gas and a thermal decomposition temperature drop gas containing a halogen element are introduced into the processing chamber, and a non-plasma thermal CVD method is performed.

Abstract: Provided is a method of manufacturing a stacked semiconductor device, which includes forming a stacked film on a semiconductor substrate, the stacked film including a plurality of silicon oxide films and a plurality of silicon nitride films, which are alternately arranged on top of each other, and the stacked film being obtained by repeatedly performing a series of operations of forming the silicon oxide film on the semiconductor substrate using one of triethoxysilane, octamethylcyclotetrasiloxane, hexamethyldisilazane and diethylsilane gases, and forming the silicon nitride film on the formed silicon oxide film; etching the silicon nitride films in the stacked film; removing carbons contained in the silicon oxide films, which are not removed in the etching, to reduce a concentration of the carbons; and forming electrodes in regions where the silicon nitride films are etched in the etching.

Abstract: Provided is a method of forming a film including a silicon film on a base, including: forming a seed layer on a surface of the base by heating the base and supplying an aminosilane-based gas onto the surface of the heated base; and forming the silicon film on the seed layer by heating the base and supplying a silane-based gas containing no amino group onto the seed layer of the surface of the heated base, wherein a molecule of the aminosilane-based gas used in forming a seed layer comprises two or more silicon atoms.

Abstract: Provided is a method of forming a seed layer as a seed of a thin film on an underlayer, which includes: forming a first seed layer on a surface of the underlayer by heating the underlayer, followed by supplying an aminosilane-based gas onto the surface of the heated underlayer; and forming a second seed layer on the surface of the underlayer with the first seed layer formed thereon by heating the underlayer, followed by supplying a disilane or higher order silane-based gas onto the surface of the heated underlayer.

Abstract: A method of forming a silicone oxide film includes: forming a silicon oxide film on a plurality of target objects by supplying a chlorine-containing silicon source into a reaction chamber accommodating the plurality of target objects; and modifying the silicon oxide film, which is formed by forming the silicon oxide film, by supplying hydrogen and oxygen or hydrogen and nitrous oxide into the reaction chamber and making an interior of the reaction chamber be under a hydrogen-oxygen atmosphere or a hydrogen-nitrous oxide atmosphere.