Abstract: An all-solid secondary battery includes: a cathode layer including a cathode active material; an anode layer; and a solid electrolyte layer disposed between the cathode layer and the anode layer, wherein at least one of the cathode layer, the anode layer, or the solid electrolyte layer includes a phase-transition solid electrolyte material, wherein upon heating, the phase-transition solid electrolyte material undergoes a phase transition from a first phase to a second phase, and the second phase has an ionic conductivity less than the ionic conductivity of the first phase.

Abstract: A method of preparing a sulfide solid electrolyte, the method including: first contacting a starting materials including Li2S, P2S5, and LiI in a first solvent to provide a precursor; and second contacting the precursor with a second solvent to prepare the sulfide solid electrolyte, wherein the first solvent includes a C1-C3 alkyl group or a cyclic ether compound which is unsubstituted or substituted with a C1-C3 alkoxy group, and the second solvent includes a C1-C10 hydrocarbon substituted with a C1 to C6 alkoxy group.

Abstract: A solid electrolyte material represented by Formula 1: L1+2x(M1)1?x(M2)(M3)4??Formula 1 wherein 0.25<x<1, L is at least one element selected from a Group 1 element, M1 is at least one element selected from a Group 2 element, a Group 3 element, a Group 12 element, and a Group 13 element, M2 is at least one element selected from a Group 5 element, a Group 14 element, and a Group 15 element, and M3 is at least one element selected from a Group 16 element, and wherein the solid electrolyte material has an I-4 crystal structure.

Abstract: A solid electrolyte for an all-solid secondary battery, wherein the solid electrolyte has a composition represented by Formula (1): Li7-xPS6-xBrx??(1) wherein 1.2<x<1.75, the solid electrolyte has an argyrodite crystal structure, and the solid electrolyte has at least one peak at a position of a 29.65±0.50° 2? when analyzed by X-ray diffraction using CuK? radiation.

Abstract: A positive electrode active material includes a core and a coating disposed on at least a portion of a surface of the core. The core includes a lithium metal oxide, a lithium metal phosphate, or a combination thereof. The coating includes a compound according to the formula LimM1nXp, wherein M1, X, m, n and p are as defined herein. Also, an electrochemical cell including the positive electrode active material, and methods for the manufacture of the positive electrode active material and the electrochemical cell.

Abstract: A composite cathode active material including: a core particle; a first coating layer; and a second coating layer; wherein the core particle includes a cathode active material, the first and second coating layers cover a surface of the core particle, the first coating layer includes a first lithium-containing compound, wherein the first lithium-containing compound includes zirconium, niobium, titanium, aluminum, or a combination thereof, the second coating layer includes a second lithium-containing compound, wherein the second lithium-containing compound includes germanium, niobium, gallium, or a combination thereof, and the first lithium-containing compound is different from the second lithium-containing compound.

Abstract: A sodium-conductive solid-state electrolyte material includes a compound of the composition Na10MP2S12, wherein M is selected from Ge, Si, and Sn. The material may have a conductivity of at least 1.0×10?5 S/cm at a temperature of about 300K and may have a tetragonal microstructure, e.g., a skewed P1 crystallographic structure. Also provided are an electrochemical cell that includes the sodium-conductive solid-state electrolyte material and a method for producing the sodium-conductive solid electrolyte material via controlled thermal processing parameters.

Abstract: A method of manufacturing a lithium ion conductive glass ceramic, includes a step of forming granules using a material including an SiO2 source, a ZrO2 source, a P2O5 source and an Na2O source; a step of obtaining a powder including a glass ceramic by passing the granules under a heated gas phase atmosphere to melt the granules and solidifying the melted granules; a step of obtaining a target object including a glass ceramic by performing a heat treatment on the powder to precipitate crystals; and a step of obtaining a lithium ion conductive glass ceramic by performing an ion-exchange process on the target object in molten salt including lithium ions.

Abstract: A method of manufacturing a lithium ion conductive solid electrolyte includes (a) a step of preparing an object to be processed including a crystalline material, that includes alkali metal other than lithium and whose ionic conductivity at room temperature is greater than or equal to 1×10?13 S/cm; and (b) a step of performing an ion-exchange process on the object to be processed in molten salt including lithium ions.

Abstract: A solid electrolyte for an all-solid secondary battery, the solid electrolyte including: Li, S, P, an M1 element, and an M2 element, wherein the M1 element is at least one element selected from Na, K, Rb, Sc, Fr, and the M2 element is at least one element selected from F, Cl, Br, I, molar amounts of lithium and the M1 element satisfy 0<M1/(Li+M1)?0.07, and the solid electrolyte has peaks at positions of 15.42°±0.50° 2?, 17.87° degrees±0.50° degrees 2?, 25.48° degrees±0.50° degrees 2?, 30.01° degrees±0.50° 2?, and 31.38°±0.50° 2? when analyzed by X-ray diffraction using CuK? radiation.

Abstract: The present invention relates to an alkali-free glass having a strain point of 725° C. or higher, an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 40×107/° C., a temperature T2 at which a glass viscosity is 102 dPa·s of 1,710° C. or lower, and a temperature T4 at which a glass viscosity is 104 dPa·s of 1,320° C. or lower, the alkali-free glass including, in terms of mol % on the basis of oxides, SiO2: 66 to 70, Al2O3: 12 to 15, B2O3: 0 to 1.5, MgO: more than 9.5 and 13 or less, CaO: 4 to 9, SrO: 0.5 to 4.5, BaO: 0 to 1, and ZrO2: 0 to 2, in which MgO+CaO+SrO+BaO is from 17 to 21, MgO/(MgO+CaO+SrO+BaO) is 0.4 or more, MgO/(MgO+CaO) is 0.4 or more, MgO/(MgO+SrO) is 0.6 or more, and the alkali-free glass does not substantially contain an alkali metal oxide.

Abstract: A solid electrolyte material represented by Formula 1: L1+2x(M1)1-x(M2)(M3)4??Formula 1 wherein 0.25<x<1, L is at least one element selected from a Group 1 element, M1 is at least one element selected from a Group 2 element, a Group 3 element, a Group 12 element, and a Group 13 element, M2 is at least one element selected from a Group 5 element, a Group 14 element, and a Group 15 element, and M3 is at least one element selected from a Group 16 element, and wherein the solid electrolyte material has an I-4 crystal structure.

Abstract: The present invention relates to a non-alkali glass having a strain point of from 710° C. to lower than 725° C., an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPa·s of 1320° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 66 to 70, Al2O3 12 to 14, B2O3 exceeding 0 to 1.5, MgO exceeding 9.5 to 13 (or 5 to 9.5), CaO 4 to 9 (or 4 to 11), SrO 0.5 to 4.5, BaO 0 to 0.5 and ZrO 0 to 2.

Abstract: A sodium-conductive solid-state electrolyte material includes a compound of the composition Na10MP2S12, wherein M is selected from Ge, Si, and Sn. The material may have a conductivity of at least 1.0×10?5 S/cm at a temperature of about 300K and may have a tetragonal microstructure, e.g., a skewed P1 crystallographic structure. Also provided are an electrochemical cell that includes the sodium-conductive solid-state electrolyte material and a method for producing the sodium-conductive solid electrolyte material via controlled thermal processing parameters.

Abstract: The present invention relates to a non-alkali glass having a strain point of from 710° C. to lower than 725° C., an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPd·s of 1320° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 66 to 70, Al2O3 12 to 14, B2O3 exceeding 0 to 1.5, MgO exceeding 9.5 to 13 (or 5 to 9.5), CaO 4 to 9 (or 4 to 11), SrO 0.5 to 4.5, BaO 0 to 0.5 and ZrO 0 to 2.

Abstract: The present invention relates to a non-alkali glass having a strain point of from 710° C. to lower than 725° C., an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPa·s of 1320° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 66 to 70, Al2O3 12 to 14, B2O3 exceeding 0 to 1.5, MgO exceeding 9.5 to 13 (or 5 to 9.5), CaO 4 to 9 (or 4 to 11), SrO 0.5 to 4.5, BaO 0 to 0.5 and ZrO 0 to 2.

Abstract: The present invention relates to an alkali-free glass having a strain point of 725° C. or higher, an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 40×107/° C., a temperature T2 at which a glass viscosity is 102 dPa·s of 1,710° C. or lower, and a temperature T4 at which a glass viscosity is 104 dPa·s of 1,320° C. or lower, the alkali-free glass including, in terms of mol % on the basis of oxides, SiO2: 66 to 70, Al2O3: 12 to 15, B2O3: 0 to 1.5, MgO: more than 9.5 and 13 or less, CaO: 4 to 9, SrO: 0.5 to 4.5, BaO: 0 to 1, and ZrO2: 0 to 2, in which MgO+CaO+SrO+BaO is from 17 to 21, MgO/(MgO+CaO+SrO+BaO) is 0.4 or more, MgO/(MgO+CaO) is 0.4 or more, MgO/(MgO+SrO) is 0.6 or more, and the alkali-free glass does not substantially contain an alkali metal oxide.

Abstract: The present invention relates to an alkali-free glass having a strain point of 725° C. or higher, an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 40×10?7/° C., a temperature T2 at which a glass viscosity is 102 dPa·s of 1,710° C. or lower, and a temperature T4 at which a glass viscosity is 104 dPa·s of 1,320° C. or lower, the alkali-free glass including, in terms of mol % on the basis of oxides, SiO2: 66 to 70, Al2O3: 12 to 15, B2O3: 0 to 1.5, MgO: more than 9.5 and 13 or less, CaO: 4 to 9, SrO: 0.5 to 4.5, BaO: 0 to 1, and ZrO2: 0 to 2, in which MgO+CaO+SrO+BaO is from 17 to 21, MgO/(MgO+CaO+SrO+BaO) is 0.4 or more, MgO/(MgO+CaO) is 0.4 or more, MgO/(MgO+SrO) is 0.6 or more, and the alkali-free glass does not substantially contain an alkali metal oxide.

Abstract: The present invention relates to an alkali-free glass having a strain point of 735° C. or higher, an average thermal expansion coefficient at from 50 to 350° C. of from 30×10?7 to 40×10?7/° C., a temperature T2 at which a glass viscosity is 102 dPa·s of 1,710° C. or lower, a temperature T4 at which a glass viscosity is 104 dPa·s of 1,340° C. or lower, and a devitrification temperature of 1,330° C. or lower, the alkali-free glass including, in terms of mol % on the basis of oxides: SiO2 66 to 69, Al2O3 12 to 15, B2O3 0 to 1.5, MgO 6 to 9.5, CaO 7 to 9, SrO 0.5 to 3, BaO 0 to 1, and ZrO2 0 to 2, in which MgO+CaO+SrO+BaO is from 16 to 18.2, MgO/(MgO+CaO+SrO+BaO) is 0.35 or more, MgO/(MgO+CaO) is 0.40 or more and less than 0.52, and MgO/(MgO+SrO) is 0.45 or more.

Abstract: A method of manufacturing a lithium ion conductive glass ceramic, includes a step of forming granules using a material including an SiO2 source, a ZrO2 source, a P2O5 source and an Na2O source; a step of obtaining a powder including a glass ceramic by passing the granules under a heated gas phase atmosphere to melt the granules and solidifying the melted granules; a step of obtaining a target object including a glass ceramic by performing a heat treatment on the powder to precipitate crystals; and a step of obtaining a lithium ion conductive glass ceramic by performing an ion-exchange process on the target object in molten salt including lithium ions.