Patents by Inventor Toranosuke Saito
Toranosuke Saito has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20020045548Abstract: A heat-sensitive recording sheet comprises an electron donative leuco dye, an acidic developer for developing the dye, and a sensitizer. The acidic developer has a main component of a phenolic compound that contains a sulfonyl group in a molecule. The sensitizer comprises an amide compound, N-(4-tolyl) -phenylacetic amide. An amide compound to be mixed with the N-(4-tolyl)-phenylacetic amide for use in the sensitizer is at least one compound selected from the group consisting of N -cyclohexylphenylacetic amide, N-phenylphenylacetic amide, N-(2-tolyl)phenylacetic amide, N-phenylphenoxyacetic amide, N-(4-tolyl)phenoxyacetic amide, N-phenyl-(4-tolyloxy)acetic amide and N-(4-tolyl)-(4-tolyloxy)acetic amide.Type: ApplicationFiled: May 3, 2001Publication date: April 18, 2002Inventor: Toranosuke Saito
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Patent number: 6107506Abstract: In the coexistence of an a 5.about.20 molar excess of water based upon 2-phenylphenol compound which is reacted with phosphorus trihalide to form a 6-halo-(6H)-dibenzo[c.e][1,2]-oxaphosphorin compound and an organic solvent which is unsoluble in water and is inert in the reaction system, an organic phosphorus compound expressed by the structural formula (1) is hydrolyzed under heating to obtain a biphenyl phosphorus compound expressed by the general formula (2) and then, a cyclising dehydration reaction under heating of the resulting compound is carried out to obtain an organic phosphorus compound expressed by the structural formula (3). This constitution can produce a product of high purity and high quality without using specific chemicals or an equipment made of specific materials.Type: GrantFiled: April 23, 1998Date of Patent: August 22, 2000Inventors: Toranosuke Saito, Takumi Hirayama, Yukinori Kohguchi
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Patent number: 5705452Abstract: A thermal recording medium comprising a as a developer a sulfonyl compound represented by general formula (1) or a polyvalent metal salt thereof. ##STR1## where X represents H or a lower alkyl group, R.sub.1, R.sub.2 and R.sub.3 represent H, halogen atom, a hydroxyl group, a lower alkyl group or a cycloalkyl group, R.sub.4, R.sub.5 and R.sub.6 represent H, halogen atom, a lower alkyl group or a cycloalkyl group, and R.sub.7 represents H or ##STR2## where R.sub.4, R.sub.5 and R.sub.6 are as defined above. The thermal recording medium has a high sensitivity and a lower background blush during storage, and also has excellent stability against heating, moisture and plasticizer.Type: GrantFiled: October 11, 1995Date of Patent: January 6, 1998Assignee: Sanko Haihatsu Kagaku KenkyushoInventors: Toranosuke Saito, Shigeru Oda, Eiji Kawabata
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Patent number: 5393332Abstract: Herein disclosed is a method for preparing a nuclear-substituted salicylic acid or a metal salt thereof represented by the following general formula (1): ##STR1## [wherein R.sub.1 and R.sub.2 each represents a t-butyl group, a t-amyl group, a t-octyl group, an isononyl group or an isododecyl group, provided that at least one of R.sub.1 and R.sub.2 represents an isononyl group or an isododecyl group; M represents a hydrogen atom or a metal atom; and n is the atomic valency of the metal atom M] which comprises the step of subjecting, to a Kolbe-Schmitt reaction, an alkali metal salt of a nuclear-substituted phenol represented by the following general formula (2): ##STR2## [wherein R.sub.1 and R.sub.2 are the same as those defined above] in which 100 to 50% of the alkali metal salt is potassium salt and 0 to 50% thereof is sodium salt, in a substantially water-insoluble solvent as a reaction medium.Type: GrantFiled: December 9, 1993Date of Patent: February 28, 1995Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.Inventors: Toranosuke Saito, Takashi Ishibashi, Eiji Kawabata, Masato Tanaka, Toshio Kimura
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Patent number: 5328884Abstract: The present invention provides a color developer composition characterized in that the composition contains a color developer comprising as its main component a nucleus-substituted salicylic acid salt represented by the formula (1) given below, and at least one amide compound selected from the group consisting of the compounds of represented by the formula (2) and formula (3) given below. ##STR1## wherein R.sub.1 to R.sub.10 are as defined in the specification.Type: GrantFiled: March 8, 1993Date of Patent: July 12, 1994Assignees: Kanzaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku KenkyushoInventors: Masato Tanaka, Tomoharu Shiozaki, Shigeru Oda, Toranosuke Saito
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Patent number: 5250108Abstract: The present invention provides a color developer composition characterized in that the composition contains a color developer comprising as its main component a nucleus-substituted salicylic acid salt represented by the formula (1) given below, and at least one amide compound selected from the group consisting of the compounds of represented by the formula (2) and formula (3) given below. ##STR1## wherein R.sub.1 to R.sub.10 are as defined in the specification.Type: GrantFiled: April 1, 1991Date of Patent: October 5, 1993Assignees: Kanzaki Paper Manufacturing Co. Ltd., Sanko Kaihatsu Kagaku KenkyushoInventors: Masato Tanaka, Tomoharu Shiozaki, Shigeru Oda, Toranosuke Saito
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Patent number: 5248828Abstract: A method for preparing a sulfone represented by the following formula: ##STR1## wherein R' represents a lower alkyl group, an aryl group or an aryl group whose nucleus has at least one substituent selected from the group consisting of a halogen atom, nitro group, a lower alkyl group, phenyl group and a phenyl group substituted with a halogen atom, or an alkali metal salt thereof. A sulfonic acid ester of 4-hydroxybiphenyl is condensed at a temperature of 0.degree. to 200.degree. C. in a presence of a Lewis acid or a super-strong acid with a sulfonyl chloride represented by the formula R'SO.sub.2 Cl, wherein R' is the same as that defined above.Type: GrantFiled: June 10, 1992Date of Patent: September 28, 1993Assignee: Sanko Kaihatsu Kagaku KenkyushoInventors: Toranosuke Saito, Shigeru Oda, Hiroki Tsunomachi, Daishiro Kishimoto
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Patent number: 5236988Abstract: An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition contains an engineering plastic material and an aliphatic polyester.Type: GrantFiled: September 25, 1990Date of Patent: August 17, 1993Assignees: Sekisui Chemical Co., Ltd., Kabushiki Kaisha Sanko Kaihatsu Kagaku KenkyushoInventors: Kazuo Doyama, Makoto Yamaguchi, Makoto Ohsuga, Akihiro Niki, Toranosuke Saito, Hiroki Tsunomachi, Daishiro Kishimoto
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Patent number: 5235084Abstract: A method for preparing a sulfone represented by the following formula: ##STR1## wherein R and R' each represent a lower alkyl group, an aryl group or an aryl group whose nucleus has at least one substituent selected from the group consisting of a halogen atom, nitro group, a lower alkyl group, phenyl group and a phenyl group substituted with a halogen atom, comprises the step of condensing a sulfonic acid ester of 4-hydroxybiphenyl represented by the following formula: ##STR2## with a sulfonyl chloride of R'SO.sub.2 Cl at a temperature of 0.degree. to 200.degree. C. in the presence of a Lewis acid or a superstrong acid.Type: GrantFiled: April 7, 1992Date of Patent: August 10, 1993Assignee: Sanko Kaihatsu Kagaku KenkyushoInventors: Toranosuke Saito, Shigeru Oda, Hiroki Tsunomachi, Daishiro Kishimoto
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Patent number: 5235024Abstract: A polyester is provided that comprises as main monomer components thereof a dicarboxylic acid and a diol, including a p-quaterphenyl derivative of specific formula. The use of appropriate kinds of dicarboxylic acid for the polyester makes it possible to obtain a thermoplastic elastomer or an engineering platic material (i.e., liquid-crystal polymer).Type: GrantFiled: November 24, 1992Date of Patent: August 10, 1993Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku KenkyushoInventors: Akihiro Niki, Makoto Ohsuga, Toshio Uesaka, Toranosuke Saito, Hiroki Tsunomachi, Kazuo Doyama, Makoto Yamaguchi, Daishiro Kishimoto
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Patent number: 5204190Abstract: Herein disclosed are a method for preparing an aqueous developer dispersion which comprises the steps of dissolving, in an organic solvent, a developer which comprises a nuclear-substituted salicylic acid salt represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group having not more than 15 carbon atoms, a cycloalkyl group, a phenyl group, a nuclear-substituted phenyl group, an aralkyl group or a nculear-substituted aralkyl group, or two adjacent groups selected from R.sub.1 to R.sub.Type: GrantFiled: June 29, 1992Date of Patent: April 20, 1993Assignees: Sanko Kaihatsu Kagaku Kenyusho, Kanzaki Paper Manufacturing Co., Ltd.Inventors: Toranosuke Saito, Shigeru Oda, Tomoharu Shiozaki, Masato Tanaka
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Patent number: 5191057Abstract: A polyester is provided that comprises as main monomer components thereof a dicarboxylic acid and a diol, including a p-quaterphenyl derivative of specific formula. The use of appropriate kinds of dicarboxylic acid for the polyester makes it possible to obtain a thermoplastic elastomer or an engineering plastic material (i.e., liquid-crystal polymer).Type: GrantFiled: December 11, 1991Date of Patent: March 2, 1993Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku KenkyushoInventors: Akihiro Niki, Makoto Ohsuga, Toshio Uesaka, Toranosuke Saito, Hiroki Tsunomachi, Kazuo Doyama, Makoto Yamaguchi, Daishiro Kishimoto
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Patent number: 5164001Abstract: Herein disclosed are a method for preparing an aqueous developer dispersion which comprises the steps of dissolving, in an organic solvent, a developer which comprises a nuclear-substituted salicylic acid salt represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group having not more than 15 carbon atoms, a cycloalkyl group, a phenyl group, a nuclear-substituted phenyl group, an aralkyl group or a nuclear-substituted aralkyl group, or two adjacent groups selected from R.sub.1 to R.sub.Type: GrantFiled: November 21, 1990Date of Patent: November 17, 1992Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.Inventors: Toranosuke Saito, Shigeru Oda, Tomoharu Shiozaki, Masato Tanaka
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Patent number: 5143890Abstract: The present invention provides a heat sensitive recording material, including a substrate and a heat sensitive recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor reactive with the dye to form a color when contacted therewith, the recording material also including 1-(4-methoxyphenoxy)-2-(2-methylphenoxy)ethane in the heat sensitive recording layer.Type: GrantFiled: November 21, 1990Date of Patent: September 1, 1992Assignees: Kanzaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kenkyusho CorporationInventors: Tetsuo Tsuchida, Yukihiro Abe, Tomoyuki Okimoto, Toranosuke Saito
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Patent number: 5118443Abstract: A developer comprising at least one polyvalent metal salt of a nuclear substituted salicylic acid of the following general formula is provided. ##STR1## In the formula, R.sub.1 represents an alkyl group having from 1 to 12 carbon atoms, R.sub.2 represents a hydrogen atom or an alkyl group having from 1 to 12 carbon atoms, R.sub.3 represents a hydrogen atom or a methyl group provided that at least one of R.sub.1 and R.sub.2 is a secondary butyl group, a secondary hexyl group, an isohexyl group, a secondary octyl group, an isononyl group, a secondary decyl group, a secondary dodecyl group or an isododecyl group and the total number of the carbon atoms in R.sub.1, R.sub.2 and R.sub.3 is from 9 to 18, M is a polyvalent metal atom, and m is a valence of M. An aqueous dispersion containing the developer and a method for preparing the developer are also described.Type: GrantFiled: January 22, 1991Date of Patent: June 2, 1992Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.Inventors: Toranosuke Saito, Takashi Ishibashi, Tomoharu Shiozaki, Tetsuo Shiraishi
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Patent number: 5107006Abstract: The clathrate compound according to the present invention which comprises, as host crystals, crystals of a polyvalent metal salt of a specific nuclear-substituted salicylic acid or a hydrate thereof and, as a gest molecule, an organic compound having 1 to 12 carbon atoms is well soluble in organic solvents or organic compounds having relatively low polarity and has good stability to light rays and NO.sub.x gases and, therefore, the clathrate compound has excellent properties favorable for use as antibiotics, stabilizers for polymeric compounds and developers for recording materials.Type: GrantFiled: December 5, 1990Date of Patent: April 21, 1992Assignee: Sanko Kaihatsu Kagaku KenkyushoInventor: Toranosuke Saito
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Patent number: 5049685Abstract: A nuclear substituted salicylic acid represented by the following general formula (I): ##STR1## (in the formula (I), R.sub.1 represents a methyl group, an isopropyl group, a tert-butyl group, a tert-amyl group, a tert-hexyl group, a tert-octyl group, an .alpha., .alpha.-dialkylbenzyl group or a nuclear substituted .alpha., .alpha.-dialkylbenzyl group; and R.sub.2 represents a tert-butyl group, a tert-amyl group, a tert-hexyl group, a tert-octyl group, an .alpha., .alpha.-dialkylbenzyl group or a nuclear substituted .alpha., .alpha.-dialkylbenzyl group) and a salt thereof are herein disclosed. The novel nuclear substituted salicylic acids and salts thereof according to the present invention have good solubility in water, organic solvents or organic polymeric compounds and, therefore, these compounds are very favorable as bactericidal and germicidal agents, stabilizers for polymeric compounds or color developing agents for recording materials.Type: GrantFiled: November 9, 1989Date of Patent: September 17, 1991Assignee: Sanko Kaihatsu Kagaku KenkyushoInventor: Toranosuke Saito
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Patent number: 5041604Abstract: A process for producing a high quality di(aryloxy)alkane with a high yield by the use of readily commercially available materials, without using any particular solvent or agent and by means of a simple operation and a general apparatus is provided, which process comprises subjecting a halogenated alkane of the formula (II)X--A--Y (II)wherein X and Y each represent a halogen atom and A represents a lower alkylene group, and a phenol of the formula (III) ##STR1## wherein R.sub.1 to R.sub.5 each are same or different, represent hydrogen, halogen, lower alkyl, lower alkoxy, carboxylic acid salt, acyl or nitro group, and may form a ring in conjunction of two adjacent groups,to condensation reaction in the presence of an alkali in an aqueous medium to form a di(aryloxy)alkane of the formula (I) ##STR2## and is characterized (i) by carrying out the condensation reaction in a molar ratio of the compound of the formula (II): the phenol of the formula (III): the alkali in terms of monovalent base of 1:1.5 to 3.0:1.Type: GrantFiled: June 20, 1990Date of Patent: August 20, 1991Assignee: Sanko Kaihatsu Kagaku KenkyushoInventors: Toranosuke Saito, Masakatu Kitani, Takashi Ishibashi
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Patent number: 5019548Abstract: A heat sensitive recording material comprising a substrate and a recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor reactive with the dye to form a color when contacted therewith, the recording material being characterized in that, as the color acceptor is used at least one compound selected from the group consisting of 4-hydroxy-4'-isopropyloxydiphenylsulfone, 4,4'-(1,3-dimethylbutylidene) bisphenol, 4,4'-(1-phenylethylidene)bisphenol, 4,4'-(p-phenylenediisopropylidene)bisphenol and 4,4'-(m-phenylenediisopropylidene) bisphenol, and to the recording layer is added at least one of a heat-fusible substance represented by the formula [I] ##STR1## wherein X is hydrogen atom, halogen atom, C.sub.1.about.4 alkyl or C.sub.1.about.4 alkoxy.Type: GrantFiled: August 24, 1989Date of Patent: May 28, 1991Assignees: Kanzaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kenkyusho CorporationInventors: Toshitake Suzuki, Fumio Seyama, Shuki Okauchi, Toranosuke Saito, Masakatu Kitani, Takashi Ishibashi
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Patent number: RE36321Abstract: In a heat-sensitive recording material incorporating a colorless or pale-colored basic dye and a color acceptor which is reactive with the basic dye to form a color when contacted therewith, the recording material characterized in that at least one compound represented by the formula ?I! is contained in a heat-sensitive recording layer ##STR1## wherein X is --O-- or --COO--, R.sub.1 to R.sub.4 are each hydrogen atom, alkyl having 1 to 8 carbon atoms, aryl having 6 to 10 carbon atoms, aralkyl having 7 to 9 carbon atoms, chlorine atom, acetyl, propionyl, methoxy, methylthio, methoxycarbonyl, cyano, nitro or cyclohexenyl, substituents R.sub.1 and/or R.sub.2 or substituents R.sub.3 and R.sub.4 may link together to form aromatic ring(s), n is an integer of 1 to 10.Type: GrantFiled: June 20, 1988Date of Patent: September 28, 1999Assignees: Kansaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kekyusho CorporationInventors: Toshitake Suzuki, Naoto Arai, Shoji Aoyagi, Toranosuke Saito, Masakatu Kitani, Takashi Ishibashi