Abstract: A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.

Abstract: In a process for producing C1-C10 aldehydes by oxidative dehydrogenation of C1-C10 alcohols over a shaped catalyst body obtainable by three-dimensional shaping and/or arranging in space of silver-containing fibers and/or threads, the average diameter or the average diagonal length of an essentially rectangular or square cross section of these silver-containing fibers and/or threads is in the range from 30 ?m to 200 ?m.

Abstract: A method of production of a catalyst that has 0.05-0.25 wt. % of precious metal, preferably for the oxidative dehydrogenation of olefinically unsaturated alcohols, comprising the following steps a) producing a D.C. plasma, b) introducing the metal and support material into the plasma, c) evaporating the metal and support material or “shattering” the solid bodies of metal and support material in the plasma, and reaction of the particles, d) cooling, so that very small particles of composite material are obtained, e) applying the composite material on the catalyst support proper, the correspondingly produced catalyst and use thereof.

Abstract: Catalyst for preparing ethylene oxide, at least comprising silver applied to a support, the support having a BET constant C in the range from 0 to 800, determined in accordance with DIN ISO 9277.

Abstract: Process for preparing a catalyst for preparing ethylene oxide, which comprises silver and zinc applied to a support, where the process comprises at least (i) providing a support, (ii) applying zinc to the support according to (i) in an amount of from 10 ppm to 1500 ppm, in each case calculated as element and based on the total weight of the support according to (i), by bringing the support into contact with at least one mixture G1 comprising at least one zinc compound, (iii) drying and/or calcining the support obtained according to (ii), (iv) applying silver to the dried and/or calcined support by bringing the support into contact with at least one mixture G2 comprising at least one silver compound.

Abstract: The present invention relates to a shaped catalyst body for preparing ethylene oxide, which comprises at least silver and rhenium applied to an alumina support, and also to a process for producing it, wherein the alumina support has the geometry of a hollow cylinder and the shaped catalyst body has a rhenium content CR and CR/ppm by weight, based on the wall thickness of the hollow cylinder dW in mm, and calculated as element, in the range 120?CR/dW?200.

Abstract: The invention relates to a process for producing a catalyst for the oxidation of ethylene to ethylene oxide, which comprises a) providing a support which comprises alumina and has been impregnated with silver or with a silver-comprising compound and has a temperature T0; and b) heating the impregnated support from the temperature T0 to a temperature T1 at a heating rate of at least 30 K/min, and also the catalyst itself which can be obtained by this process.

Abstract: A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.

Abstract: Supported noble metal-comprising catalysts which can be obtained by a) application of colloidal noble metal in the form of a colloidal solution, optionally in admixture with additives acting as promoters, to a support material, b1) drying of the resulting product at from 150 to 350° C., or b2) drying of the resulting product at from 150 to 350° C. and subsequent calcination at from 350 to 550° C. for epoxidation or oxidative dehydrogenation, a process for producing it, its use and also the use of colloidal noble metal for producing supported catalysts.

Abstract: The present invention relates to a process for preparing ethylene oxide by reaction of ethylene with oxygen in the presence of at least one silver-comprising catalyst, wherein the reaction takes place in a reactor which has a catalyst packed bed having at least two zones (i) and (ii) and the silver content of the catalyst in zone (i) is lower than the silver content of the catalyst in zone (ii). The catalyst packed bed preferably has a further zone (a) with which the reaction mixture comes into contact before the zones (i) and (ii). According to the invention, the silver content of the catalyst in the zone (a) is higher than the silver content of the catalyst in zone (i).

Abstract: The present invention relates to a process for producing hydrocarbons from methane, which comprises, in a first stage (i), reacting methane to form ethylene and, in a later stage (ii), reacting the product mixture obtained in stage (i) which comprises ethylene and methane to give higher-value hydrocarbons. In addition, the present invention relates to a plant for producing hydrocarbons from methane in which, in a single plant strand, a plurality of plant units are arranged successively in series comprising: a first reactor A for carrying out a conversion from methane to ethylene a second reactor B for carrying out a conversion from ethylene to higher-value hydrocarbons.

Abstract: Proposed is a process for preparing isocyanates by dissociating the corresponding carbamates, which comprises dissociating the carbamates in the presence of a heterogeneous Lewis-acidic catalyst.

Abstract: This invention relates to a process, comprising reacting ethylene and oxygen or a source of oxygen in the presence of a catalyst in a reactor to form a product comprising ethylene oxide, wherein the catalyst contains silver or silver compound and a support and the catalyst is in the form of particulate solids having a mean particle diameter from 1 to 1000 ?m and wherein the molar ratio of oxygen to ethylene is from 1:4 to 10:1.

Abstract: The use of a supported noble metal catalyst obtainable by applying a sparingly soluble noble metal compound to a support from solution or suspension, and subsequently treating thermally, for preparing olefinically unsaturated carbonyl compounds.

Abstract: A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.

Abstract: A process for preparing olefinically unsaturated carbonyl compounds by oxidative dehydrogenation in an oxygenous atmosphere over a supported catalyst which comprises gold and optionally further noble metals at temperatures in the range from 50 to 240° C.