Abstract: The present invention is to provide an inorganic sintered material that excels in photocatalytic activity as compared with that exhibited in the use of a photocatalyst of titanium oxide only. It is provided an inorganic sintered material comprising a photocatalyst, wherein the photocatalyst comprising a base having photocatalytic activity; and a silicon oxide film covering the base, wherein the film is substantially pore-free, and wherein the photocatalyst has a alkali metal content of not less than 1 ppm but not more than 1,000 ppm.

Abstract: The present invention provides a method for manufacturing a titanium dioxide photocatalyst composite material, and relates to a method for manufacturing a titanium dioxide composite ceramic material on which photoactive (photooxidative) apatite or another calcium phosphate monocrystal is partially deposited, wherein the method is characterized in promoting the following reactions by immersing titanium dioxide in an aqueous solution containing an excess of phosphorus ions and calcium ions in comparison with an artificial body fluid in order to fabricate a titanium dioxide photocatalyst composite material on which a compound composed of one or more apatite or other calcium phosphate Ca9(PO4)6 monocrystals is partially deposited: (1) forming and aggregating calcium phosphate clusters and producing octacalcium phosphate; (2) converting the octacalcium phosphate into an apatite or other calcium phosphate Ca9(PO4)6 monocrystal; and (3) growing the monocrystal.

Abstract: The present invention provides a hydraulic composite material endowed with multiple functions such as a photocatalytic function, and a method for production thereof, and relates to hydraulic a composite material having a substance-adsorbing function, humidity-adjusting function, and/or photocatalytic function, the material being characterized in that calcium silicate cement or a calcium phosphate cement is deposited as a hydraulic material on a suitable substrate in the presence of water so as to be hardened and to thereby cause the cement to solidify, be fixed, and self-adhere to the application surface; and also relates to a method for producing a hydraulic composite material characterized in that a suspension or solution containing the above hydraulic material is mixed with a photocatalyst.

Abstract: The present invention provides a method for preparing a high-density thin silica film with excellent translucency on a substrate having an arbitrary profile and surface characteristics, a method for controlling the surface roughness of the thin silica film, a method for preparing a silica-titania composite film, a composite film with photocatalytic action obtained by these methods, and a composite structure.

Abstract: The present invention provides a method for manufacturing a titanium dioxide photocatalyst composite material, and relates to a method for manufacturing a titanium dioxide composite ceramic material on which photoactive (photooxidative) apatite or another calcium phosphate monocrystal is partially deposited, wherein the method is characterized in promoting the following reactions by immersing titanium dioxide in an aqueous solution containing an excess of phosphorus ions and calcium ions in comparison with an artificial body fluid in order to fabricate a titanium dioxide photocatalyst composite material on which a compound composed of one or more apatite or other calcium phosphate Ca9(PO4)6 monocrystals is partially deposited: (1) forming and aggregating calcium phosphate clusters and producing octacalcium phosphate; (2) converting the octacalcium phosphate into an apatite or other calcium phosphate Ca9(PO4)6 monocrystal; and (3) growing the monocrystal.

Abstract: A dental resin material mixed with a composition containing, as a maincomponent, titanium dioxide whose surface has been partly coated with apatite. In the dental resin material, it is preferable that anatase-, rutile-, brookit-type titanium dioxide or a mixture of these components is used as the titanium dioxide. The apatite for partial coating of titanium dioxide is produced by immersing powdery titanium dioxide in a pseudo body fluid and stirring the immersed titanium dioxide approximately at the same temperature as a human body temperature, i.e., 36° C. In this instance, it is important that the apatite is deposited in the form of platy crystals of less than 2 mm in thickness to cover 0.001-10% of the surface of titanium dioxide.

Abstract: A dental resin material mixed with a composition containing, as a maincomponent, titanium dioxide whose surface has been partly coated with apatite. In the dental resin material, it is preferable that anatase-, rutile-, brookit-type titanium dioxide or a mixture of these components is used as the titanium dioxide. The apatite for partial coating of titanium dioxide is produced by immersing powdery titanium dioxide in a pseudo body fluid and stirring the immersed titanium dioxide approximately at the same temperature as a human body temperature, i.e., 36° C. In this instance, it is important that the apatite is deposited in the form of platy crystals of less than 2 mm in thickness to cover 0.001-10% of the surface of titanium dioxide.

Abstract: The present invention provides a new active oxygen generating material and a manufacturing method thereof. The present invention relates to an active oxygen generating agent containing polyaniline compounded or mixed with calcium phosphate that is made by forming a porous calcium phosphate coating on at least part of the surface of polyaniline particles; to a method for manufacturing an active oxygen generating agent component wherein calcium phosphate is precipitated onto the surface of polyaniline by immersing the polyaniline in a pseudo-fluid comprising calcium ions and phosphate ions; to a method for generating active oxygen by bringing a liquid that contains dissolved oxygen in contact with the above-mentioned active oxygen generating agent; and a composition for an environmental clarification.

Abstract: The present invention provides a cleansing, bleaching, and sterilizing agent and a cleansing method for the oral cavity, dental prosthetics, and so forth, and a method for manufacturing said agent, a dental prosthetic cleansing system, a bleaching agent for discolored teeth and a method for manufacturing said agent, a bleaching system, a composition for environmental purification containing a photoactive compound composed of phosphorus and calcium, and a paint using the same.

Abstract: A system for bleaching discolored teeth is provided, and this system has a function irradiating light emitted from a light-emitting section to the surface of teeth applied with a chemical agent including titanium dioxide and hydrogen peroxide, a irradiation energy of wavelength 380 to 420 nm of the light emitted from the light-emitting section is at least 37 mW/cm2 and the ratio of irradiation energy of wavelength 380 to 420 nm with respect to the irradiation energy of wavelength 200 to 800 nm thereof is at least 36% at this light-emitting section, and whereby it is possible to obtain high bleaching effect of the teeth, to reduce the heat applied to the teeth to a low level (no more than 40° C.) and to reduce emission of ultraviolet light that has an adverse effect on the human body to a low level.

Abstract: A tooth bleaching agent comprising (a) titanium dioxide initiating photocatalytic action by irradiation with light, (b) a chemical compound generating hydrogen peroxide in aqueous solution, (c) an inorganic thickening agent or an organic thickening agent, (d) phosphoric acid and (d) condensed phosphate is proposed. A tooth bleaching method characterized by bleaching tooth by applying the breaching agent onto the surface of a tooth followed by irradiating the applied surface with light is also proposed.

Abstract: A system for bleaching discolored teeth is provided, and this system has a function irradiating light emitted from a light-emitting section to the surface of teeth applied with a chemical agent including titanium dioxide and hydrogen peroxide, a irradiation energy of wavelength 380 to 420 nm of the light emitted from the light-emitting section is at least 37 mW/cm2 and the ratio of irradiation energy of wavelength 380 to 420 nm with respect to the irradiation energy of wavelength 200 to 800 nm thereof is at least 36% at this light-emitting section, and whereby it is possible to obtain high bleaching effect of the teeth, to reduce the heat applied to the teeth to a low level (no more than 40° C.) and to reduce emission of ultraviolet light that has an adverse effect on the human body to a low level.

Abstract: A dental resin material mixed with a composition containing, as a maincomponent, titanium dioxide whose surface has been partly coated with apatite. In the dental resin material, it is preferable that anatase-, rutile-, brookit-type titanium dioxide or a mixture of these components is used as the titanium dioxide. The apatite for partial coating of titanium dioxide is produced by immersing powdery titanium dioxide in a pseudo body fluid and stirring the immersed titanium dioxide approximately at the same temperature as a human body temperature, i.e., 36° C. In this instance, it is important that the apatite is deposited in the form of platy crystals of less than 2 mm in thickness to cover 0.001-10% of the surface of titanium dioxide.

Abstract: A living tissue replacement of crystallized glass having bioaffinity and mechanical strength is briefly obtained simply by pressure molding or machining without using a special equipment. A glass material having a softening point below its crystallization temperature and exhibiting viscous flow at temperatures below its melting point is heated at a temperature above its Tg and pressed at the temperature to mold to a desired shape, thereby manufacturing a living tissue replacement such as a dental crown. Molding can be done under a pressure of up to 20 MPa.

Abstract: A photocatalytic powder for environmental clarification, comprising finely divided titanium dioxide particles having a coating of porous calcium phosphate formed on at least part of the surface of each titanium dioxide particle, wherein an anionic surface active agent is present at least on the interface between said coating of porous calcium phosphate and the titanium dioxide particle. This photocatalytic powder is produced by dispersing finely divided titanium dioxide particles in an aqueous slurry containing an anionic surface active agent, and then forming a coating of porous calcium phosphate on at least part of the surface of each titanium dioxide particle. This photocatalytic powder is used, for example, by supporting it in an organic polymer shaped article.

Abstract: The present invention relates to a sheet type oral implant, and the present invention is an oral implant to be used by being secured on an alveolar bone, this oral implant is characterized by having a sheet portion whose shape on the bone side matches in an inverted convex-concave arrangement the surface shape of the alveolar bone; fixing hooks provided to the edges of the sheet portion and designed for securing the oral implant on the alveolar bone and preventing the implant from falling off; and a post portion for mounting an artificial tooth.

Abstract: The present invention relates to a method for bleaching a discolored tooth, comprising the steps of applying a solution/paste of titanium dioxide powder and hydrogen peroxide solution onto the surface of discolored teeth, and bleaching the tooth based on the photocatalytic action that is produced by irradiating this area with light; and to a bleaching agent for applying onto the surface of discolored tooth to bleach the discolored tooth based on the photocatalytic action that is produced by irradiating this area with light, the bleaching agent comprising as active ingredients a combination of hydrogen peroxide solution and titanium dioxide producing photocatalytic action when irradiated with light.

Abstract: An environment-purifying material is obtained by immersing a carrier with a titanium oxide film coated on its surface or a substrate comprising titanium oxide particles, in a pseudo-body fluid containing an excessive amount of calcium phosphate, and then coating the surface of the substrate with a porous calcium phosphate film that easily adsorbs toxic substances and that is inactive as a photocatalyst.

Abstract: A photocatalytic powder for environmental clarification, comprising finely divided titanium dioxide particles having a coating of porous calcium phosphate formed on at least part of the surface of each titanium dioxide particle, wherein an anionic surface active agent is present at least on the interface between said coating of porous calcium phosphate and the titanium dioxide particle. This photocatalytic powder is produced by dispersing finely divided titanium dioxide particles in an aqueous slurry containing an anionic surface active agent, and then forming a coating of porous calcium phosphate on at least part of the surface of each titanium dioxide particle. This photocatalytic powder is used, for example, by supporting it in an organic polymer shaped article.

Abstract: A coating composition which is excellent in water resistance, weatherability and durability and can maintain its appearance for a prolonged period of time can be provided. A coating composition comprising a coating component and a photocatalyst containing calcium phosphate and titanium oxide is disclosed. As the photocatalyst, use is made of titanium oxide particles partially covered thereon with calcium phosphate, or porous body coated thereon with a film of titanium oxide, the film of titanium oxide being further covered partially thereon with calcium phosphate. The crystal form of titanium oxide is preferably anatase. The organic coating includes vinyl-type synthetic resin emulsions, and the inorganic coating is e.g. a solution containing a metal alkoxide for forming a film by a sol-gel method.