Abstract: In one example, a nonaqueous electrolyte and a nonaqueous electrolyte cell are configured to prevent deterioration of the cell capability due to an antioxidant under a high temperature environment with the antioxidant in a small content. In one example, the separator is impregnated with an electrolytic solution. In one example, the electrolytic solution contains a solvent, an electrolyte salt and an antioxidant, the solvent contains a halogenated carbonate ester represented, a content of the halogenated carbonate ester is from 0.1 to 50% by mass, and a content of the antioxidant is from 0.01 to 5,000 ppm.

Abstract: A positive electrode includes: a positive electrode collector; and a positive electrode active material layer provided on the positive electrode collector and containing a positive electrode active material and an alkaline earth metal carbonate having a fixed form.

Abstract: A secondary battery capable of improving battery characteristics is provided. The secondary battery includes a cathode 21 containing a cathode active material capable of inserting and extracting an electrode reactant, an anode 22 containing an anode active material capable of inserting and extracting the electrode reactant, and an electrolyte containing a solvent and an electrolyte salt. At least one of the cathode 21, the anode 22, and the electrolyte contains a radical scavenger compound. The radical scavenger compound is a compound in which a group having a radical scavenger function exists as a matrix, to which one or more carboxylic metal bases or one or more sulfonic metal bases are introduced. Chemical stability of the cathode 21, the anode 22, or the electrolyte containing the radical scavenger compound is improved. Thus, at the time of charge and discharge, decomposition reaction of the electrolytic solution is easily inhibited.

Abstract: A nonaqueous electrolyte battery includes: a positive electrode, a negative electrode, and a nonaqueous electrolyte, wherein the positive electrode contains, as a positive electrode active material, a positive electrode material having a surface composition represented by the following formula (I); the nonaqueous electrolyte contains a halogenated carbonate represented by any of the following formulae (1) to (2) and an alkylbenzene represented by the following formula (3); a content of the halogenated carbonate is 0.1% by mass or more and not more than 50% by mass relative to the nonaqueous electrolyte; and a content of the alkylbenzene is 0.

Abstract: A nonaqueous electrolyte includes: a nonaqueous solvent containing 0.1% by volume or more and not more than 50% by volume of at least one member selected from the group consisting of a halogen element-containing chain carbonate represented by the following formula (1) and a halogen element-containing cyclic carbonate represented by the following formula (2); and an electrolyte salt containing a compound represented by the following formula (3) in an amount of 0.001 moles/L or more and not more than 0.

Abstract: A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N?N—Ar?—, where Ar and Ar? are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained.

Abstract: A nonaqueous electrolyte secondary battery includes: a positive electrode; a negative electrode; and a nonaqueous electrolyte, wherein an open circuit voltage in a completely charged state per pair of a positive electrode and a negative electrode is from 4.25 to 6.

Abstract: A battery includes: a positive electrode; a negative electrode; a nonaqueous electrolyte; and a separator, wherein the nonaqueous electrolyte contains at least one sulfonic anhydride selected from the group consisting of compounds represented by the following chemical formulae (1) to (4) and an aromatic compound represented by the following chemical formula (5).

Abstract: A lamellar crystalline organic polymer containing acidic groups and/or ammonium salt thereof, such as ammonium salt of polymuconic acid, is mixed with a substance containing a metal ion such as alkali metal ion, to prepare a metal ion-containing polymer having a structure in which the metal ion is intercalated between the layers of the lamellar crystalline organic polymer having acidic groups. Subsequently, metal ion exchange reaction is conducted if necessary. Thereafter, the metal ion is reduced to produce fine metal particles. Thus, a crystalline organic polymer in which fine metal particles are dispersed in a crystalline organic polymers obtained.

Abstract: A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N?N—Ar?—, where Ar and Ar? are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained.

Abstract: A positive electrode includes: a salt represented by the following formula (1) on the surface of an active material contained in a positive electrode active material layer provided on a positive electrode collector, or at least on the surface of the positive electrode active material layer wherein R represents a hydrocarbon group which may have an unsaturated bond, a group obtained by halogenating or hydroxylating this hydrocarbon group, or a hydrogen group; R1 and R2 each independently represents an unsaturated bond, a hydrocarbon group which may have N or O, R1 and R2 may be bonded to each other to form a ring, in which the ring may further contain N or O, or a hydrogen group; Aa? represents an acid anion capable of being bonded to at least any one of R, R1, R2 and the ring; Mx? represents a metal ion capable of forming a salt together with Aa?; and a, b, x and y each represents an integer of 1 or more.

Abstract: A lamellar crystalline organic polymer containing acidic groups and/or ammonium salt thereof, such as ammonium salt of polymuconic acid, is mixed with a substance containing a metal ion such as alkali metal ion, to prepare a metal ion-containing polymer having a structure in which the metal ion is intercalated between the layers of the lamellar crystalline organic polymer having acidic groups. Subsequently, metal ion exchange reaction is conducted if necessary. Thereafter, the metal ion is reduced to produce fine metal particles. Thus, a crystalline organic polymer in which fine metal particles are dispersed in a crystalline organic polymeris obtained.

Abstract: A positive electrode active material includes: a particle containing a positive electrode material capable of intercalating and deintercalating an electrode reactant; and a film provided in at least a part of the particle and having a peak of C2H5S+, C3H7S+ or C4H9S+ obtained by cation analysis by time of flight secondary ion mass spectrometry.

Abstract: An electrode includes: an electrode collector and an electrode active material layer, wherein a film containing a salt represented by the following formula (I) is provided on the electrode active material layer: R1AnMx ??(I) wherein R1 represents an n-valent organic group containing a sulfur atom; n represents an integer of from 1 to 4; A represents an anion; M represents a metal ion; and x represents an integer of 1 or more.

Abstract: A lamellar crystalline organic polymer containing acidic groups and/or ammonium salt thereof, such as ammonium salt of polymuconic acid, is mixed with a substance containing a metal ion such as alkali metal ion, to prepare a metal ion-containing polymer having a structure in which the metal ion is intercalated between the layers of the lamellar crystalline organic polymer having acidic groups. Subsequently, metal ion exchange reaction is conducted if necessary. Thereafter, the metal ion is reduced to produce fine metal particles. Thus, a crystalline organic polymer in which fine metal particles are dispersed in a crystalline organic polymer is obtained.

Abstract: An electrolyte capable of improving battery characteristics even at high temperatures, a battery including the electrolyte, and a method for manufacturing an electrolyte are provided. The electrolyte contains at least one type of compound represented by the following formula: where R1, R2, R3, and R4 independently represent a hydrogen group, a fluorine group, a methyl group, an ethyl group, or a group in which a fluorine group has substituted for a part of the methyl group or the ethyl group; at least one of R1, R2, R3, and R4 is a group containing fluorine (F); and X, Y, and Z independently represents sulfur (S) or oxygen (O) except the case in which all of X, Y, and Z are oxygen (O), that is, X=Y=Z=O.

Abstract: A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N?N—Ar?—, where Ar and Ar? are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained.

Abstract: A separator having a fine porous structure and including a polyolefin thermoplastic resin and a block copolymer as constituent materials is provided. The block copolymer including a monomer unit derived from a polyolefin resin and a monomer unit derived from a polymer component, The polyolefin resin has a melting point lower than that of the polyolefin thermoplastic resin, the polymer component being incompatible with polyolefin.

Abstract: A secondary battery capable of improving the cycle characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode current collector, an anode active material layer that is provided on the anode current collector, and contains an anode active material containing at least one of a simple substance of silicon, an alloy of silicon, a compound of silicon, a simple substance of tin, an alloy of tin, and a compound of tin, and a coat that is provided on the anode active material layer, and contains an ionic polymer containing lithium.

Abstract: A battery capable of improving cycle characteristics is provided. An anode includes: an anode current collector; an anode active material arranged on the anode current collector; and a coating arranged on the anode active material layer, in which the coating includes at least one of a metal salt represented by Chemical Formula 1 and a metal salt of oxocarbonic acid.