Patents by Inventor Toshifumi Hashiba

Toshifumi Hashiba has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230331939
    Abstract: The present invention provides amphiphilic polymer particles which are formed from a naturally derived starting material and exhibit hydrophobicity, while maintaining an adequate water absorption. An amphiphilic alginic acid particle group which is obtained by subjecting a polyvalent metal salt of alginic acid to a hydrophobization treatment with use of a hydrophobizing agent, wherein: some metal ions in the polyvalent metal salt of alginic acid are hydrophobized through a chemical bond with the hydrophobizing agent; the contact angle at 30 seconds after dropping a water droplet on the particle group is from 300 to 150°; and the water absorption per 100 g of the particles is not less than the oil absorption per 100 g of the particles.
    Type: Application
    Filed: May 7, 2021
    Publication date: October 19, 2023
    Applicant: NISSHINBO HOLDINGS INC.
    Inventors: Toshifumi Hashiba, Kazutoshi Hayakawa, Erina Matsuzaka
  • Publication number: 20230287210
    Abstract: Provided is a biodegradation accelerator for accelerating the biodegradation of resins, etc. in the ocean. This marine-biodegradation accelerator comprises a compound including anions of one or more kinds including an anion having six or more carbon atoms and three or more oxygen atoms and a metal cation having a valence of two or higher, the anions and the cation being bonded by ionic bonding. A group of particles of the compound forms a contact angle of 30° or larger 30 seconds after a waterdrop is dropped thereonto.
    Type: Application
    Filed: May 7, 2021
    Publication date: September 14, 2023
    Applicant: Nisshinbo Holdings Inc.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba, Erina Matsuzaka
  • Publication number: 20220127435
    Abstract: The present invention provides a hydrophobic alginic acid particle group which is obtained by subjecting a polyvalent metal alginate to a hydrophobization treatment, and which is configured such that the water absorption per 100 g of the particles is lower than the oil absorption per 100 g of the particles.
    Type: Application
    Filed: January 30, 2020
    Publication date: April 28, 2022
    Applicant: Nisshinbo Holdings Inc.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba, Erina Matsuzaka
  • Patent number: 11225541
    Abstract: This production method is for disc-shaped polymer particles having an average aspect ratio of 1-1.3. The method comprises conducting, in a solvent, solution polymerization of monomers including a hydrophobic unsaturated monomer which is liquid at 25° C., in the presence of a polymerization initiator, a surfactant, and/or a polymer stabilizer, wherein a solvent mixture containing water, a hydrophilic organic solvent, and a hydrophobic organic solvent is used as the solvent, and, as the polymerization initiator, one or more polymerization initiators soluble in at least one of water, the hydrophilic organic solvent, and the hydrophobic organic solvent are used as a combination that is soluble in all of water, the hydrophilic organic solvent, and the hydrophobic organic solvent, such that the hydrophobic unsaturated monomer, water, the hydrophilic organic solvent, and the hydrophobic organic solvent are mixed at a predetermined ratio.
    Type: Grant
    Filed: April 15, 2019
    Date of Patent: January 18, 2022
    Assignee: NISSHINBO HOLDINGS INC.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba
  • Publication number: 20210246250
    Abstract: This production method is for disc-shaped polymer particles having an average aspect ratio of 1-1.3. The method comprises conducting, in a solvent, solution polymerization of monomers including a hydrophobic unsaturated monomer which is liquid at 25° C., in the presence of a polymerization initiator, a surfactant, and/or a polymer stabilizer, wherein a solvent mixture containing water, a hydrophilic organic solvent, and a hydrophobic organic solvent is used as the solvent, and, as the polymerization initiator, one or more polymerization initiators soluble in at least one of water, the hydrophilic organic solvent, and the hydrophobic organic solvent are used as a combination that is soluble in all of water, the hydrophilic organic solvent, and the hydrophobic organic solvent, such that the hydrophobic unsaturated monomer, water, the hydrophilic organic solvent, and the hydrophobic organic solvent are mixed at a predetermined ratio.
    Type: Application
    Filed: April 15, 2019
    Publication date: August 12, 2021
    Applicant: Nisshinbo Holdings Inc.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba
  • Patent number: 10729623
    Abstract: A method for producing elliptical, needle-shaped, or rod-shaped polymer particles satisfying (1)-(3) below includes a step in which a synthesis solution including water, a mixed solvent of a hydrophilic organic solvent and a hydrophobic organic solvent, a polymeric stabilizer, a polymerization initiator, and an unsaturated monomer is heated, and, at least after the heating has started, the pH of the synthesis solution is adjusted to 5-9 inclusive to perform solution polymerization: (1) the average (LAV) length (L) in a two-dimensional projection diagram obtained by irradiating the particles with light from a direction orthogonal to the longitudinal direction is 0.1-80 ?m; (2) the average (DAV) breadth (D) in the two-dimensional projection diagram obtained by irradiating the particles with light from the direction orthogonal to the longitudinal direction is 0.05-40 ?m; and (3) the average (PAV) aspect ratio (L/D) calculated from the length (L) and the breadth (D) is 1.5-30.
    Type: Grant
    Filed: May 2, 2016
    Date of Patent: August 4, 2020
    Assignee: NISSHINBO HOLDINGS, INC.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba, Erina Matsuzaka, Goki Yamada
  • Patent number: 10584193
    Abstract: These flat elliptical polymer particles have a front view, a planar view, and a side view in a projection diagram based on third-angle projection which are all elliptical. The flat elliptical polymer particles satisfy (1)-(4): (1) the average length (LAV) of flat portions satisfies 0.13?(LAV)?500 ?m; (2) the average breadth (DAV) of the flat portions satisfies 0.1?(DAV)?250 ?m; (3) the average (P1AV) aspect ratio (L/D) calculated from the length (L) and the breadth (D) satisfies 1.3<P1AV?50; and (4) the average (P2AV) aspect ratio (D/T) calculated from the breadth (D) and the thickness (T) of the side surface satisfies 1.2<P2AV?100.
    Type: Grant
    Filed: May 2, 2016
    Date of Patent: March 10, 2020
    Assignee: NISSHINBO HOLDINGS INC.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba, Erina Matsuzaka
  • Publication number: 20200054535
    Abstract: Provided is a skin cosmetic that includes: (A) 0.1-40 mass % of polymer particles that include prolate-spheroidal polymer particles A that haw no flat surfaces that (1), in a two-dimensional projection obtained by shining light from a direction that is orthogonal to a longitudinal-axis direction, have an average (L1AV) major axis (L1) of 3-60 ?m, that (2), in the two-dimensional projection obtained by shining light from the direction that is orthogonal to the longitudinal-axis direction, have an average (D1AV) minor axis (D1) of 0.5-30 ?m, and that (3) have an average (P1AV) aspect ratio (L1/D1), as calculated from the major axes (L1) and the minor axes (D1), of 1.5-30; and 60-99.9 mass % of other components that include (B) inorganic particles and (C) an oily component.
    Type: Application
    Filed: February 21, 2018
    Publication date: February 20, 2020
    Applicant: Nisshinbo Holdings Inc.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba
  • Publication number: 20190254938
    Abstract: Provided are skin cosmetics including 0.1-50% by mass of polymer particles including flat, oval, spherical polymer particles A in which: all of the front view, the plan view, and the side view of a projection drawing based on the third angle method are ovals; (1) the average (LAV) of the long diameter (L) of the flat portion is 0.13?LAV?500 ?m; (2) the average (DAV) of the short diameter (D) of the flat portion is 0.1?DAV?250 ?m; and (3) the average (P1AV) of the aspect ratio (L/D) calculated from the long diameter (L) and the short diameter (D) is 1.3<P1AV?50.
    Type: Application
    Filed: November 1, 2017
    Publication date: August 22, 2019
    Applicant: Nisshinbo Holdings Inc.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba, Mitsugu Takahashi, Goki Yamada, Hiroko Hiraoka
  • Publication number: 20180134823
    Abstract: These flat elliptical polymer particles have a front view, a planar view, and a side view in a projection diagram based on third-angle projection which are all elliptical. The flat elliptical polymer particles satisfy (1)-(4): (1) the average length (LAV) of flat portions satisfies 0.13?(LAV)?500 ?m; (2) the average breadth (DAV) of the flat portions satisfies 0.1?(DAV)?250 ?m; (3) the average (P1AV) aspect ratio (L/D) calculated from the length (L) and the breadth (D) satisfies 1.3<P1AV?50; and (4) the average (P2AV) aspect ratio (D/T) calculated from the breadth (D) and the thickness (T) of the side surface satisfies 1.2<P2AV?100.
    Type: Application
    Filed: May 2, 2016
    Publication date: May 17, 2018
    Applicant: Nisshinbo Holdings Inc.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba, Erina Matsuzaka
  • Publication number: 20180118867
    Abstract: Provided are elliptical, needle-shaped, or rod-shaped crosslinked polymer particles in which 5-100 mol % of all repeating units are repeating units derived from an unsaturated monomer having a functional group selected from an epoxy group, a carboxyl group, an amide group, a hydroxy group an amino group, and a thiol group, wherein (1) the average (LAV) length (L) in a two-dimensional projection diagram obtained by irradiating the particles with light from a direction orthogonal to the longitudinal direction is 0.1-80 ?m, (2) the average (DAV) breadth (D) in the two-dimensional projection diagram obtained by irradiating, the particles with light from the direction orthogonal to the longitudinal direction is 0.05-40 ?m, and (3) the average (PAV) aspect ratio (L/D) calculated from the length (L) and the breadth (D) is 1.5-30.
    Type: Application
    Filed: May 2, 2016
    Publication date: May 3, 2018
    Applicant: Nisshinbo Holdings Inc.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba, Erina Matsuzaka
  • Publication number: 20180104160
    Abstract: A method for producing elliptical, needle-shaped, or rod-shaped polymer particles satisfying (1)-(3) below includes a step in which a synthesis solution including water, a mixed solvent of a hydrophilic organic solvent and a hydrophobic organic solvent, a polymeric stabilizer, a polymerization initiator, and an unsaturated monomer is heated, and, at least after the heating has started, the pH of the synthesis solution is adjusted to 5-9 inclusive to perform solution polymerization: (1) the average (LAV) length (L) in a two-dimensional projection diagram obtained by irradiating the particles with light from a direction orthogonal to the longitudinal direction is 0.1-80 ?m; (2) the average (DAV) breadth (D) in the two-dimensional projection diagram obtained by irradiating the particles with light from the direction orthogonal to the longitudinal direction is 0.05-40 ?m; and (3) the average (PAV) aspect ratio (L/D) calculated from the length (L) and the breadth (D) is 1.5-30.
    Type: Application
    Filed: May 2, 2016
    Publication date: April 19, 2018
    Applicant: NISSHINBO HOLDINGS, INC.
    Inventors: Kazutoshi Hayakawa, Toshifumi Hashiba, Erina Matsuzaka, Goki Yamada
  • Publication number: 20160262988
    Abstract: Provided is an ultraviolet scattering agent characterized by comprising at least one type of elliptical or needle-like polymer particle A, wherein (1) the average (LAV) of the long axis (L) in a two-dimensional projection diagram obtained by radiating light from a direction perpendicular to the long-axis direction is 0.1 to 80 ?m, (2) the average (DAV) of the short axis (D) in a two-dimensional projection diagram obtained by radiating light from a direction perpendicular to the long-axis direction is 0.05 to 40 ?m, and (3) the average (PAV) of the aspect ratio (L/D) calculated from the long axis (L) and the short axis (D) is 2 to 30.
    Type: Application
    Filed: November 11, 2014
    Publication date: September 15, 2016
    Applicant: NISSHINBO HOLDINGS, INC.
    Inventors: Kazutoshi HAYAKAWA, Erina MATSUZAKA, Goki YAMADA, Toshifumi HASHIBA
  • Patent number: 9093196
    Abstract: Conductive particles each includes a polymer base particle and a conductive layer coating the polymer base particle. Let the compressive elastic deformation characteristic KX of one conductive particle when the displacement of particle diameter of the conductive particles is X % be defined by the following formula: KX=(3/?2)·(SX?3/2)·(R?1/2)·FX. FX is the load (N) necessary for X % displacement of the conductive particles. SX is the compressive deformation amount (mm) upon X % displacement of the conductive particles. R is the particle radius (mm) of the conductive particles. The compressive elastic deformation characteristic K50 when the displacement of particle diameter of the conductive particles is 50% is 100 to 50000 N/mm2 at 20° C., and the recovery factor of particle diameter of the conductive particles when the displacement of particle diameter of the conductive particles is 50% is not less than 30% at 20° C.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: July 28, 2015
    Assignee: NISSHINBO HOLDINGS, INC.
    Inventors: Toshifumi Hashiba, Kazutoshi Hayakawa, Satomi Kudo, Kohei Moriyama, Tsuyoshi Fujii
  • Publication number: 20100222477
    Abstract: A filler for substrates which comprises an inorganic substance and a carbodiimide-group-containing organic layer chemically bonded to the surface of the inorganic substance. Examples of the carbodiimide-group-containing organic layer include a layer comprising a carbodiimide-group-containing compound represented by either of the following formulae. Due to the constitution, the filler for substrates can be highly dispersed in a resin for substrates even when added in a high proportion and can give a substrate inhibited from deteriorating in electrical properties, mechanical properties, etc. (X1)m—Z-[A-(R1—N?C?N)n—R1—NCO]1 ??(1) (X1)m—Z-[A-(R1—N?C?N)n—R1-A-Z—(X2)3]1 ??(2) [R1 represents a residue of an isocyanate compound; X? and X2 each independently represents hydrogen, halogeno, etc.
    Type: Application
    Filed: June 21, 2006
    Publication date: September 2, 2010
    Applicant: NISSHINBO INDUSTRIES, INC.
    Inventors: Nami Tsukamoto, Toshifumi Hashiba, Mayumi Mizushiri
  • Publication number: 20100160512
    Abstract: A flame retardant which comprises an inorganic hydroxide and a carbodiimide-group-containing organic layer chemically bonded to the surface of the inorganic hydroxide. Examples of the carbodiimide-group-containing organic layer include a layer comprising a carbodiimide-group-containing compound represented by either of the following formulae. Due to the constitution, the flame retardant can be highly dispersed in a resin even when added in a high proportion and can give a molding inhibited from deteriorating in electrical properties, mechanical properties, etc. (X1)m-Z-[A-(R1—N?C?N)n—R1—NCO]1??(1) (X1)m-Z-[A-(R1—N?C?N)n—R1-A-Z-(X2)3])3??(2) [R1 represents a residue of an isocyanate compound; X1 and X2 each independently represents hydrogen, halogeno, etc.
    Type: Application
    Filed: June 21, 2006
    Publication date: June 24, 2010
    Applicant: NISSHINBO INDUSTRIES, INC.
    Inventors: Nami Tsukamoto, Toshifumi Hashiba, Mayumi Mizushiri
  • Patent number: 7387832
    Abstract: Flaky particles which are produced through easy conversion from mother particles by using an organic compound other than monomers having double bonds as the hardening and crosslinking agent and to which at least one mechanical or functional characteristic selected from among reactivity, close adhesion, and tackiness is imparted by the presence of part of the unreacted reactive groups of the organic compound inside and on the particles; and a process for the production of the flaky particles. More specifically, flaky particles composed of mother particles (A) having functional groups and an organic compound (B) which has groups reactive with the functional groups of the particles (A) and is soluble in a solvent, characterized in that at least part of the functional groups of the mother particles (A) and at least part of the reactive groups of the organic compound (B) react with each other to form crosslinks.
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: June 17, 2008
    Assignee: Nisshinbo Industries, Inc.
    Inventors: Toshifumi Hashiba, Kazutoshi Hayakawa, Takaya Sato, Hiroshi Yoshida
  • Publication number: 20080124552
    Abstract: A particle with a rough surface for plating or vapor deposition which has been formed from a base (A) having first functional groups on the surface thereof and particles (B) having on the surface thereof second functional groups reactive with the first functional groups and having an average particle diameter which is smaller than the diameter of the base (A) and not smaller than 0.1 ?m, by uniting the base (A) with the particles (B) through chemical bonds between the first functional groups and the second functional groups, wherein the base (A) has at least two projecting parts on the surface thereof. In this particle, the base has been tenaciously bonded to the protruding particles. Because of this, even when the protruding particles used have a size not smaller than the given size, the particle with a rough surface can secure a surface area while maintaining a thickness of a conductive coating film. As a result, the particle can have high conductivity.
    Type: Application
    Filed: May 24, 2005
    Publication date: May 29, 2008
    Applicant: Nisshinbo Industries, Inc.
    Inventors: Toshifumi Hashiba, Nami Tsukamoto, Kazutoshi Hayakawa, Satomi Kudo
  • Publication number: 20080078977
    Abstract: Conductive particles each includes a polymer base particle and a conductive layer coating the polymer base particle. Let the compressive elastic deformation characteristic KX of one conductive particle when the displacement of particle diameter of the conductive particles is X % be defined by the following formula: KX=(3/?2)·(SX?3/2)·(R?1/2)·FX. FX is the load (N) necessary for X % displacement of the conductive particles. SX is the compressive deformation amount (mm) upon X % displacement of the conductive particles. R is the particle radius (mm) of the conductive particles. The compressive elastic deformation characteristic K50 when the displacement of particle diameter of the conductive particles is 50% is 100 to 50000 N/mm2 at 20° C., and the recovery factor of particle diameter of the conductive particles when the displacement of particle diameter of the conductive particles is 50% is not less than 30% at 20° C.
    Type: Application
    Filed: September 28, 2007
    Publication date: April 3, 2008
    Applicant: NISSHINBO INDUSTRIES, INC.
    Inventors: Toshifumi HASHIBA, Kazutoshi HAYAKAWA, Satomi KUDO, Kohei MORIYAMA, Tsuyoshi FUJII
  • Publication number: 20080020207
    Abstract: A particle having a rough surface and obtained from a particle (A) having grafted on the surface thereof a polymer having first functional groups and particles (B) having grafted on the surface thereof a polymer having second functional groups reactive with the first functional groups, by uniting the particle (A) with the particles (B) through chemical bonds between the first functional groups and the second functional groups. In this particle with a rough surface, the core particle has been tenaciously bonded to the protruding particles. Because of this, even when the protruding particles have an increased particle diameter, the protruding particles can be prevented from readily shedding from the core particle.
    Type: Application
    Filed: May 24, 2005
    Publication date: January 24, 2008
    Applicant: Nisshinbo Industries, Inc.
    Inventors: Toshifumi Hashiba, Nami Tsukamoto, Kazutoshi Hayakawa, Satomi Kudo