Patents by Inventor Toshihiko Tsukatani

Toshihiko Tsukatani has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11891701
    Abstract: A spraying material comprising a rare earth (R), aluminum and oxygen, the spraying material being a powder and comprising a crystalline phase of a rare earth (R) aluminum monoclinic (R4Al2O9) and a crystalline phase of a rare earth oxide (R2O3), with respect to diffraction peaks detected within a diffraction angle 2? range from 10° to 70° by a X-ray diffraction method using the characteristic X-ray of Cu-K?, the spraying material having diffraction peaks attributed to the rare earth oxide (R2O3) and diffraction peaks attributed to the rare earth (R) aluminum monoclinic (R4Al2O9), and an intensity ratio I(R)/I(RAL) of an integral intensity I(R) of the maximum diffraction peak attributed to the rare earth oxide (R2O3) to an integral intensity I(RAL) of the maximum diffraction peak attributed to the rare earth aluminum monoclinic (R4Al2O9) being at least 1.
    Type: Grant
    Filed: April 8, 2020
    Date of Patent: February 6, 2024
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Ryo Iwasaki, Noriaki Hamaya, Toshihiko Tsukatani, Yugo Taniguchi
  • Publication number: 20200325570
    Abstract: A spraying material comprising a rare earth (R), aluminum and oxygen, the spraying material being a powder and comprising a crystalline phase of a rare earth (R) aluminum monoclinic (R4Al2O9) and a crystalline phase of a rare earth oxide (R2O3), with respect to diffraction peaks detected within a diffraction angle 2? range from 10° to 70° by a X-ray diffraction method using the characteristic X-ray of Cu-K?, the spraying material having diffraction peaks attributed to the rare earth oxide (R2O3) and diffraction peaks attributed to the rare earth (R) aluminum monoclinic (R4Al2O9), and an intensity ratio I(R)/I(RAL) of an integral intensity I(R) of the maximum diffraction peak attributed to the rare earth oxide (R2O3) to an integral intensity I(RAL) of the maximum diffraction peak attributed to the rare earth aluminum monoclinic (R4Al2O9) being at least 1.
    Type: Application
    Filed: April 8, 2020
    Publication date: October 15, 2020
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Ryo Iwasaki, Noriaki Hamaya, Toshihiko Tsukatani, Yugo Taniguchi
  • Patent number: 10450505
    Abstract: Provided is a wavelength conversion member in which the following are dispersed in a thermoplastic resin: a LuYAG fluorescent material that is represented by (Y1-?-?Lu?Ce?)3Al5O12 (in which ? is a positive number between 0.3-0.8 inclusive and ? is a positive number between 0.01-0.05 inclusive), that emits yellow-green light as a result of excitation by blue light, and that has a diffraction peak within a range in which the diffraction angle 2? in X-ray diffraction by the K?1 line of Cu is 52.9° to 53.2° inclusive; and a KSF fluorescent material that is represented by K2(Si1-xMnx)F6 (in which x is a positive number between 0.001 and 0.3 inclusive) and that emits red light as a result of excitation by blue light. The content of the KSF fluorescent material in the wavelength conversion member is 1 to 5 times the content of the LuYAG fluorescent material by mass ratio.
    Type: Grant
    Filed: November 27, 2015
    Date of Patent: October 22, 2019
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiro Tsumori, Hajime Nakano, Toshihiko Tsukatani, Kazuhiro Wataya, Takehisa Minowa
  • Patent number: 10288260
    Abstract: A turn signal for a vehicle has a blue LED as a light source, and an outer cover irradiated by the blue light. The outer cover includes a molded body of a polymeric material including phosphors dispersed therein that absorb blue light and emit light. By means of the present invention, it is possible to provide a turn signal for vehicles which has improved visibility and which imparts excellent visibility and sufficient luminous intensity over a wide angle. Further, because the entire outer cover surface-emits light, uniformity of luminous intensity is ensured without subjecting the outer cover to light scattering treatment, enabling as a result preventing glare caused by light scattering treatment, making this turn signal safe without being unpleasant for pedestrians and drivers of nearby vehicles. Furthermore, because no complex optical design is necessary, this turn signal saves space and can be arranged in a vehicle.
    Type: Grant
    Filed: February 28, 2014
    Date of Patent: May 14, 2019
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiko Tsukatani, Toshihiro Tsumori, Kazuhiro Wataya, Masami Kaneyoshi, Takehisa Minowa
  • Patent number: 9988572
    Abstract: This lighting apparatus is provided with a blue LED chip having a maximum peak at a wavelength of 420-480 nm and a fluorescent material-containing resin layer disposed on the front of the blue LED chip in the light emission direction. The fluorescent material-containing resin layer is obtained by mixing and dispersing a LuAg fluorescent material, which is represented by the formula Lu3Al5O12:Ce3+ and in which the Ce activation rate is 2 mol. % or lower relative to Lu, and a double fluoride fluorescent material represented by the formula A2(B1?xMnx)F6 (in the formula, A is at least one type of element selected from among the group consisting of Li, Na, K and Cs, B is at least one type of element selected from among the group consisting of Si, Ti, Nb, Ge and Sn, and x is an integer that falls within the range 0.001?x?0.1) in a resin.
    Type: Grant
    Filed: November 28, 2014
    Date of Patent: June 5, 2018
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Kazuhiro Wataya, Toshihiro Tsumori, Toshihiko Tsukatani, Takehisa Minowa
  • Patent number: 9978913
    Abstract: An outdoor luminaire comprising a blue LED chip having a maximum peak at a wavelength of 420-480 nm and a phosphor layer disposed forward of the LED chip in its emission direction is provided. The phosphor layer comprises a phosphor of the formula: Lu3Al5O12:Ce3+ which is activated with up to 1 mol % of Ce relative to Lu, the phosphor being dispersed in a resin. In scotopic and mesopic vision conditions, the luminaire produces illumination affording brighter lighting, higher visual perception and brightness over a broader area.
    Type: Grant
    Filed: June 20, 2014
    Date of Patent: May 22, 2018
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiro Tsumori, Toshihiko Tsukatani, Kazuhiro Wataya, Takehisa Minowa
  • Publication number: 20170342320
    Abstract: Provided is a wavelength conversion member in which the following are dispersed in a thermoplastic resin: a LuYAG fluorescent material that is represented by (Y1-?-?Lu?Ce?)3Al5O12 (in which ? is a positive number between 0.3-0.8 inclusive and ? is a positive number between 0.01-0.05 inclusive), that emits yellow-green light as a result of excitation by blue light, and that has a diffraction peak within a range in which the diffraction angle 2? in X-ray diffraction by the K?1 line of Cu is 52.9° to 53.2° inclusive; and a KSF fluorescent material that is represented by K2(Si1-xMnx)F6 (in which x is a positive number between 0.001 and 0.3 inclusive) and that emits red light as a result of excitation by blue light. The content of the KSF fluorescent material in the wavelength conversion member is 1 to 5 times the content of the LuYAG fluorescent material by mass ratio.
    Type: Application
    Filed: November 27, 2015
    Publication date: November 30, 2017
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiro TSUMORI, Hajime NAKANO, Toshihiko TSUKATANI, Kazuhiro WATAYA, Takehisa MINOWA
  • Publication number: 20170336040
    Abstract: This LED light source for a vehicle-mounted headlight is provided with: a blue LED that emits blue light having a dominant wavelength of 430-470 nm; and a fluorescent material that is arranged forward in the light emission direction of the blue light and that performs wavelength conversion of the blue light. The main fluorescent material constituting the fluorescent material is a celium-activated lutetium/aluminum/garnet fluorescent material represented by Lu3Al5O12:Ce. The LED light source for a vehicle-mounted headlight emits pseudo-white light that has a color temperature of 6,000 K or less and that is unlikely to decrease in visibility even during bad weather. The LED light source for a vehicle-mounted headlight has characteristics such as a wide lighting range and excellent visibility in the peripheral area of the visual field (the peripheral visual field) and can thus contribute to accident prevention and road traffic safety.
    Type: Application
    Filed: December 2, 2015
    Publication date: November 23, 2017
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiro TSUMORI, Toshihiko TSUKATANI, Kazuhiro WATAYA, Takehisa MINOWA
  • Patent number: 9617469
    Abstract: Phosphor particles are provided in the form of spherical polycrystalline secondary particles consisting of a multiplicity of primary particles, including a garnet phase having the compositional formula: (A1-xBx)3C5O12 wherein A is Y, Gd, and/or Lu, B is Ce, Nd, and/or Tb, C is Al and/or Ga, and 0.002?x?0.2, the secondary particles having an average particle size of 5-50 ?m.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: April 11, 2017
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiko Tsukatani, Kazuhiro Wataya, Yasushi Takai, Takehisa Minowa
  • Patent number: 9559269
    Abstract: An outdoor luminaire comprising a blue LED chip having a maximum peak at a wavelength of 420-480 nm and a phosphor layer disposed forward of the LED chip in its emission direction is provided. The phosphor layer comprises a phosphor of the formula: Lu3Al5O12:Ce3+ which is activated with up to 1 mol % of Ce relative to Lu, the phosphor being dispersed in a resin. In scotopic and mesopic vision conditions, the luminaire produces illumination affording brighter lighting, higher visual perception and brightness over a broader area.
    Type: Grant
    Filed: June 20, 2014
    Date of Patent: January 31, 2017
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiro Tsumori, Toshihiko Tsukatani, Kazuhiro Wataya, Takehisa Minowa
  • Publication number: 20170009131
    Abstract: This lighting apparatus is provided with a blue LED s chip having a maximum peak at a wavelength of 420-480 nm and a fluorescent material-containing resin layer disposed on the front of the blue LED chip in the light emission direction. The fluorescent material-containing resin layer is obtained by mixing and dispersing a LuAg fluorescent material, which is represented by the formula Lu3Al5O12:Ce3+ and in which the Ce activation rate is 2 mol. % or lower relative to Lu, and a double fluoride fluorescent material represented by the formula A2(B1?xMnx)F6 (in the formula, A is at least one type of element selected from among the group consisting of Li, Na, K and Cs, B is at least one type of element selected from among the group consisting of Si, Ti, Nb, Ge and Sn, and x is an integer that falls within the range 0.001?x?0.1) in a resin.
    Type: Application
    Filed: November 28, 2014
    Publication date: January 12, 2017
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Kazuhiro WATAYA, Toshihiro TSUMORI, Toshihiko TSUKATANI, Takehisa MINOWA
  • Patent number: 9472731
    Abstract: A phosphor-containing resin molded body and a wavelength conversion member, in each of which one or more kinds of spherical phosphors represented by (AxByCz)3C5O12 (wherein A represents one or more rare earth elements selected from among Y, Gd and Lu; B represents one or more rare earth elements selected from among Ce, Nd and Tb; C represents Al and/or Ga; and x, y and z respectively represent positive numbers satisfying 0.002?y?0.2, 0<z?2/3 and x+y+z=1) and having an average circularity of 0.3 or less are dispersed in an amount of 0.1-20% by mass; a light emitting device which is provided with the wavelength conversion member; and a resin pellet for phosphor-containing resin molded bodies.
    Type: Grant
    Filed: December 25, 2013
    Date of Patent: October 18, 2016
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiko Tsukatani, Toshihiro Tsumori, Kazuhiro Wataya, Hajime Nakano, Takehisa Minowa
  • Publication number: 20160218251
    Abstract: A phosphor-containing resin molded body and a wavelength conversion member, in each of which one or more kinds of spherical phosphors represented by (AxByCz)3C5O12 (wherein A represents one or more rare earth elements selected from among Y, Gd and Lu; B represents one or more rare earth elements selected from among Ce, Nd and Tb; C represents Al and/or Ga; and x, y and z respectively represent positive numbers satisfying 0.002?y?0.2, 0<z?2/3 and x+y+z=1) and having an average circularity of 0.3 or less are dispersed in an amount of 0.1-20% by mass; a light emitting device which is provided with the wavelength conversion member; and a resin pellet for phosphor-containing resin molded bodies.
    Type: Application
    Filed: December 25, 2013
    Publication date: July 28, 2016
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshihiko Tsukatani, Toshihiro Tsumori, Kazuhiro Wataya, Hajime Nakano, Takehisa Minowa
  • Publication number: 20160010826
    Abstract: A turn signal for a vehicle has a blue LED as a light source, and an outer cover irradiated by the blue light. The outer cover includes a molded body of a polymeric material including phosphors dispersed therein that absorb blue light and emit light. By means of the present invention, it is possible to provide a turn signal for vehicles which has improved visibility and which imparts excellent visibility and sufficient luminous intensity over a wide angle. Further, because the entire outer cover surface-emits light, uniformity of luminous intensity is ensured without subjecting the outer cover to light scattering treatment, enabling as a result preventing glare caused by light scattering treatment, making this turn signal safe without being unpleasant for pedestrians and drivers of nearby vehicles. Furthermore, because no complex optical design is necessary, this turn signal saves space and can be arranged in a vehicle.
    Type: Application
    Filed: February 28, 2014
    Publication date: January 14, 2016
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshihiko Tsukatani, Toshihiro Tsumori, Kazuhiro Wataya, Masami Kaneyoshi, Takehisa Minowa
  • Publication number: 20150338034
    Abstract: A wavelength conversion member including a light emitting member being a molding of a mixture containing a transparent or translucent polymer material and a phosphor, and a reflection layer laminated on part of a surface of the light emitting member. In the wavelength conversion member which converts light from a light source by the phosphor and radiates the converted light in a desired direction, light emitted from the phosphor in the wavelength conversion member which is emitted in other directions than desired radiating direction can be efficiently utilized without loss.
    Type: Application
    Filed: May 21, 2015
    Publication date: November 26, 2015
    Applicant: Shin-Etsu Chemical. Co., Ltd.
    Inventors: Kazuhiro Wataya, Toshihiro Tsumori, Toshihiko Tsukatani
  • Patent number: 9062251
    Abstract: Phosphor particles of generally spherical shape have an average particle diameter of 5-50 ?m and an average roundness of up to 0.3. The phosphor includes a garnet phase having formula: (A1-xBx)3C5O12 wherein A is Y, Gd, or Lu, B is Ce, Nd, or Tb, C is Al or Ga, and 0.002?x?0.2.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: June 23, 2015
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiko Tsukatani, Kazuhiro Wataya
  • Publication number: 20150085467
    Abstract: A red lamp is provided comprising a blue LED array and a red emissive member. The red emissive member is made of a resin having dispersed therein a phosphor capable of absorbing blue light and emitting red light, the phosphor being selected from among silicate, SiAlON, silicon nitride, sulfide, and garnet structure phosphors. The red lamp offers high efficiency, high light intensity, and improved visibility both in front and lateral directions and is thus suited for use in vehicle lighting fixtures such as red rear position lamps and red stop lamps.
    Type: Application
    Filed: September 25, 2014
    Publication date: March 26, 2015
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiro Tsumori, Kazuhiro Wataya, Toshihiko Tsukatani, Takehisa Minowa
  • Publication number: 20140376229
    Abstract: An outdoor luminaire comprising a blue LED chip having a maximum peak at a wavelength of 420-480 nm and a phosphor layer disposed forward of the LED chip in its emission direction is provided. The phosphor layer comprises a phosphor of the formula: Lu3Al5O12:Ce3+ which is activated with up to 1 mol % of Ce relative to Lu, the phosphor being dispersed in a resin. In scotopic and mesopic vision conditions, the luminaire produces illumination affording brighter lighting, higher visual perception and brightness over a broader area.
    Type: Application
    Filed: June 20, 2014
    Publication date: December 25, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiro Tsumori, Toshihiko Tsukatani, Kazuhiro Wataya, Takehisa Minowa
  • Publication number: 20140369022
    Abstract: A light-emitting device is provided comprising an excitation light source capable of emitting laser light and a phosphor adapted to convert the wavelength of the laser light and to generate light of converted wavelength. The phosphor is polycrystalline secondary particles each consisting of a plurality of primary particles and containing therein pores with a diameter of 0.2-25 ?m. The device produces light of quality in that the speckle noise that gives a glare or strange sense to eyesight when the light is illuminated to a rough surface is reduced.
    Type: Application
    Filed: June 11, 2014
    Publication date: December 18, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Kazuhiro Wataya, Toshihiko Tsukatani, Shintaro Tanaka
  • Patent number: 8865022
    Abstract: Phosphor particles are provided in the form of spherical polycrystalline secondary particles consisting of a multiplicity of primary particles, including a garnet phase having the composition: (AxByCz)3C5O12 wherein A is Y, Gd, and/or Lu, B is Ce, Nd, and/or Tb, C is Al and/or Ga, and x, y and z are in the range: 0.002<y?0.2, 0<z?2/3, and x+y+z=1. The phosphor particles are prepared by granulating powder oxides containing one or more of the elements A, B, and C, melting the granules in a plasma and solidifying outside the plasma, and heat treating the resulting particles in a non-oxidizing atmosphere at a temperature of higher than 800° C. to 1,700° C.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: October 21, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshihiko Tsukatani, Kazuhiro Wataya, Yasushi Takai, Takehisa Minowa