Patents by Inventor Toshihiro Shimakawa

Toshihiro Shimakawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9561511
    Abstract: The present invention is a method for applying a gradient magnetic field to a paramagnetic supporting liquid containing a mixture of first particles and second particles to separate the mixture by particle type. A magnetic susceptibility of the first particles is lower than that of the liquid, and a magnetic susceptibility of the second particles is higher than that of the liquid. A gradient magnetic field is applied to the liquid in a separation tank provided with a magnetic filter and the liquid is stirred. The first particles float in the liquid by a magneto-Archimedes effect. A horizontal magnetic force acts on the first particles by the gradient magnetic field, so that the first particles travel to a region lateral to or outward from the magnetic filter and are gathered in the region. The magnetic filter is excited by the gradient magnetic field to catch the second particles.
    Type: Grant
    Filed: August 24, 2012
    Date of Patent: February 7, 2017
    Assignees: UBE INDUSTRIES, LTD., OSAKA UNIVERSITY
    Inventors: Shigehiro Nishijima, Fumihito Mishima, Koji Kaiso, Toshihiro Shimakawa
  • Patent number: 9370782
    Abstract: The present invention provides a method and an apparatus for separating a mixture that are capable of separating a mixture containing a plurality types of particles, using a countercurrent classification technique, even when there is little difference in density and particle diameter depending on the types of particles. In the present invention, a mixture containing first particles and second particles is separated using a separation tube 13 having the inverted-conical or pyramidal shape or a substantially inverted-conical or pyramidal shape. The first particles and the second particles are made of substances having different magnetic susceptibilities. A fluid is caused to flow upward through the separation tube 13, and the flow of the fluid is used to introduce the mixture into the separation tube 13. The first particles and the second particles are held in the separation tube 13 in a mixed state.
    Type: Grant
    Filed: December 11, 2012
    Date of Patent: June 21, 2016
    Assignees: OSAKA UNIVERSITY, UBE INDUSTRIES, LTD.
    Inventors: Shigehiro Nishijima, Fumihito Mishima, Koji Kaiso, Toshihiro Shimakawa
  • Patent number: 9174221
    Abstract: Provided are a mixture separation method and a separation apparatus in which agglomeration of particles contained in the mixture is suppressed, energy required in distillation treatment of a supporting liquid is small in comparison with conventional methods, and particles that cannot be separated by conventional methods can be separated from a mixture containing the particles. The separation method and separation apparatus of the present invention separate, by type, a plurality of types of particles formed of mutually different materials by applying a magnetic field having a magnetic field gradient to the mixture containing the plurality of types of particles in the supporting liquid. Alternatively, the separation method and separation apparatus of the present invention separate a specific type of particle from such mixture. The supporting liquid is an organic solvent solution obtained by dissolving one or more types of paramagnetic compounds in an organic solvent.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: November 3, 2015
    Assignees: OSAKA UNIVERSITY, UBE INDUSTRIES, LTD.
    Inventors: Shigehiro Nishijima, Fumihito Mishima, Koji Kaiso, Toshihiro Shimakawa
  • Publication number: 20140332449
    Abstract: The present invention provides a method and an apparatus for separating a mixture that are capable of separating a mixture containing a plurality types of particles, using a countercurrent classification technique, even when there is little difference in density and particle diameter depending on the types of particles. In the present invention, a mixture containing first particles and second particles is separated using a separation tube 13 having the inverted-conical or pyramidal shape or a substantially inverted-conical or pyramidal shape. The first particles and the second particles are made of substances having different magnetic susceptibilities. A fluid is caused to flow upward through the separation tube 13, and the flow of the fluid is used to introduce the mixture into the separation tube 13. The first particles and the second particles are held in the separation tube 13 in a mixed state.
    Type: Application
    Filed: December 11, 2012
    Publication date: November 13, 2014
    Applicants: OSAKA UNIVERSITY, UBE INDUSTRIES, LTD.
    Inventors: Shigehiro Nishijima, Fumihito Mishima, Koji Kaiso, Toshihiro Shimakawa
  • Publication number: 20140202960
    Abstract: Provided are a mixture separation method and a separation apparatus in which processes are performed efficiently in a short time compared to conventional methods with a low load on the apparatus configuration compared to conventional methods. The present invention is a mixture separation method or a mixture separation apparatus for separating, by applying a gradient magnetic field to a paramagnetic supporting liquid containing a mixture of first particles and second particles, the mixture by particle type. A magnetic susceptibility of the first particles is lower than a magnetic susceptibility of the supporting liquid, and a magnetic susceptibility of the second particles is higher than the magnetic susceptibility of the supporting liquid. A gradient magnetic field is applied to the supporting liquid in the separation tank (7) provided with a magnetic filter means (9) using a magnetic field generating means (11), and the supporting liquid is stirred.
    Type: Application
    Filed: August 24, 2012
    Publication date: July 24, 2014
    Applicants: UBE INDUSTRIES, LTD., OSAKA UNIVERSITY
    Inventors: Shigehiro Nishijima, Fumihito Mishima, Koji Kaiso, Toshihiro Shimakawa
  • Publication number: 20140014559
    Abstract: Provided are a mixture separation method and a separation apparatus in which agglomeration of particles contained in the mixture is suppressed, energy required in distillation treatment of a supporting liquid is small in comparison with conventional methods, and particles that cannot be separated by conventional methods can be separated from a mixture containing the particles. The separation method and separation apparatus of the present invention separate, by type, a plurality of types of particles formed of mutually different materials by applying a magnetic field having a magnetic field gradient to the mixture containing the plurality of types of particles in the supporting liquid. Alternatively, the separation method and separation apparatus of the present invention separate a specific type of particle from such mixture. The supporting liquid is an organic solvent solution obtained by dissolving one or more types of paramagnetic compounds in an organic solvent.
    Type: Application
    Filed: March 28, 2012
    Publication date: January 16, 2014
    Applicants: UBE INDUSTRIES, LTD., OSAKA UNIVERSITY
    Inventors: Shigehiro Nishijima, Fumihito Mishima, Koji Kaiso, Toshihiro Shimakawa
  • Patent number: 5973184
    Abstract: A dialkyl carbonate (e.g., dimethyl carbonate) is prepared at a high yield and a high selectivity by decarbonylation of a dialkyl oxalate (e.g., dimethyl oxalate) in a gaseous phase in the presence of an alkali metal compound (e.g., potassium carbonate).
    Type: Grant
    Filed: November 9, 1998
    Date of Patent: October 26, 1999
    Assignee: Ube Industries, Ltd.
    Inventors: Katsumasa Harada, Ryoji Sugise, Masayuki Nishio, Toshio Kurafuji, Toshihiro Shimakawa
  • Patent number: 5466858
    Abstract: Straight-chain acrylonitrile dimers including 1,4-dicyanobutene, 1,4-dicyanobutadiene and adiponitrile are produced at a high selectivity by dimerizing acrylonitrile in the presence of a ruthenium catalyst, and in the presence of a straight-chain dimer selectivity-enhancing agent comprising at least one member selected from(A) substituted benzoic acids, except for monoalkylbenzoic acids, having at least one substituent and preferably exhibiting a pKa of 1.50 to 6.0 determined in water at an ionic strength of 0 to 0.1 mole/liter at 25.degree. C.;(B) hetero atom-containing acyclic carboxylic acids having at least one substituent having a sulfur or nitrogen atom attached to a carbon atom located in an .alpha.- on .beta.
    Type: Grant
    Filed: August 30, 1994
    Date of Patent: November 14, 1995
    Assignee: Ube Industries, Ltd.
    Inventors: Ryoji Sugise, Kouichi Kashiwagi, Masashi Shirai, Toshihiro Shimakawa
  • Patent number: 5332844
    Abstract: Straight-chain acrylonitrile dimers including 1,4-dicyanobutene, 1,4-dicyanobutadiene and adiponitrile are produced at a high selectivity rate and yield by dimerizing acrylonitrile in the presence of a catalyst comprising at least one ruthenium compound, for example dichloro-tetrakis (dimethylsulfoxide) ruthenium, and in the presence of at least one organic acid, for example, propionic acid, and optionally in the further presence of a basic compound, a reducing compound and/or a sulfoxide compound.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: July 26, 1994
    Assignee: Ube Industries, Ltd.
    Inventors: Ryoji Sugise, Kouichi Kashiwagi, Masashi Shirai, Toshihiro Shimakawa