Abstract: A negative thermal expansion material having a negative thermal expansion coefficient according to the present invention is represented by Zr2?aMaSxP2O12+?, where M is at least one selected from Ti, Ce, Sn, Mn, Hf, Ir, Pb, Pd, and Cr; a is 0?a<2; x is 0.4?x?1; and ? is a value defined as to satisfy a charge neutral condition. The present invention makes it possible to provide a negative thermal expansion material, a composite material and a method for producing a negative thermal expansion material that can realize reduction in cost and density reduction.

Abstract: A method for manufacturing an austenitic stainless steel strip comprises: hot-rolling a material having a component composition containing, in % by mass, more than 20.0% and 30.0% or less of Ni, more than 15.0% and 18.0% or less of Cr, 1.0 to 2.0% of Mo, 3.5% or more and less than 5.0% of Al, more than 1.0% and 2.0% or less of Nb+Ta, 0.3% or less of Ti+V, 1.0% or less of Si, 2.0% or less of Mn, 0.01 to 0.3% of Zr, 0.005 to 0.045% of C, 0.001 to 0.03% of B, and also containing at least one element selected from Y, La, Ce and Hf in an amount such that the content of Y+La+Ce+Hf+Zr can become 0.01 to 0.5% with the remainder comprising Fe and unavoidable impurities; cold-rolling the strip; and heating the strip, then maintaining the strip at that temperature, and rapid-cooling the strip.

Abstract: Provided is a metal gasket including, expressed in mass%, C: 0.10% or less, Si: 1.0% or less, Mn: 2.0% or less, P: 0.04% or less (including 0%), S: 0.01% or less (including 0%), Ni: 25.0-60.0%, Cr: 10.0-20.0%, either Mo or W alone, or both Mo+W/2: 0.05-5.0%, Al: more than 0.8% to 3.0% or less, Ti: 1.5-4.0%, Nb: 0.05-2.5%, V: 1.0% or less (including 0%), B: 0.001-0.015%, Mg: 0.0005-0.01%, S/Mg: 1.0 or less, N: 0.01% or less (including 0%), and O: 0.005% or less (including 0%), with the remainder being Fe and unavoidable impurities. The metal gasket has a metal structure in which a precipitate ?? phase having an average equivalent circle diameter of 25 nm or larger is not present within the austenite base.

Abstract: Provided is a metal gasket including, expressed in mass%, C: 0.10% or less, Si: 1.0% or less, Mn: 2.0% or less, P: 0.04% or less (including 0%), S: 0.01% or less (including 0%), Ni: 25.0-60.0%, Cr: 10.0-20.0%, either Mo or W alone, or both Mo + W/2: 0.05-5.0%, Al: more than 0.8% to 3.0% or less, Ti: 1.5-4.0%, Nb: 0.05-2.5%, V: 1.0% or less (including 0%), B: 0.001-0.015%, Mg: 0.0005-0.01%, S/Mg: 1.0 or less, N: 0.01% or less (including 0%), and O: 0.005% or less (including 0%), with the remainder being Fe and unavoidable impurities. The metal gasket has a metal structure in which a precipitate ?? phase having an average equivalent circle diameter of 25 nm or larger is not present within the austenite base.

Abstract: Provided is a metal gasket including, expressed in mass %, C: 0.10% or less, Si: 1.0% or less, Mn: 2.0% or less, P: 0.04% or less (including 0%), S: 0.01% or less (including 0%), Ni: 25.0-60.0%, Cr: 10.0-20.0%, either Mo or W alone, or both Mo+W/2:0.05-5.0%, Al: more than 0.8% to 3.0% or less, Ti: 1.5-4.0%, Nb: 0.05-2.5%, V: 1.0% or less (including 0%), B: 0.001-0.015%, Mg: 0.0005-0.01%, S/Mg: 1.0 or less, N: 0.01% or less (including 0%), and O: 0.005%) or less (including 0%), with the remainder being Fe and unavoidable impurities. The metal gasket has a metal structure in which a precipitate ?? phase having an average equivalent circle diameter of 25 nm or larger is not present within the austenite base.

Abstract: The present invention provides a Ni-based alloy that is hot-workable and exhibits an excellent high-temperature strength, and provides a heat-resistant plate material using the same. This Ni-based alloy is composed of, by mass, C: 0.002 to 0.10%, Si: less than 1.0%, Mn: up to 1.0%, P: up to 0.04% (including 0%), S: up to 0.01% (including 0%), Cr: 15.0 to 25.0%, Co: 0.1 to 18.0%, Mo: not less than 2.0% and less than 4.0%, Al: 3.0 to 5.0%, Ti: not less than 0.01% and less than 0.5%, Zr: 0.01 to 0.1%, B: 0.001 to 0.015%, Fe: up to 3.0%, Mg or Mg+0.6×Ca: 0.0005 to 0.01%, N: up to 0.01% (including 0%), O: up to 0.005% (including 0%), and the balance of Ni with inevitable impurities, S/Mg or S/(Mg+0.6×Ca) being up to 1.0, and a G value represented by the following formula (1) being 30 to 45. G=7+0.11Cr+8.23Al+4.66Ti?0.

Abstract: There is provided a steel for solid oxide fuel cells which contains more than 0 and not more than 0.05 mass % of C, 0.05 mass % or less of N, 0.01 mass % or less of O, 0.2 mass % or less of Al, 0.15 mass % or less of Si, 0.1 to 1.0 mass % of Mn, 20.0 to 25.0 mass % of Cr, more than 0 mass % and not more than 1.0 mass % of Ni, 0.02 to 0.12 mass % of La, 0.1 to 0.5 mass % of Zr, 0.15 to 0.5 mass % of La+Zr, and Fe and impurities as a remainder. The following relational formula is satisfied, and an Fe and Zr-containing intermetallic compound viewed in a ferrite matrix is 1.1 % or less in terms of a visual field area ratio 5(7C+6N)/(7?4(7C+6N))?Zr?41(7C+6N)/(7+66(7C+6N)).

Abstract: The present invention provides a Ni-based alloy that is hot-workable and exhibits an excellent high-temperature strength, and provides a heat-resistant plate material using the same. This Ni-based alloy is composed of, by mass, C: 0.002 to 0.10%, Si: less than 1.0%, Mn: up to 1.0%, P: up to 0.04% (including 0%), S: up to 0.01% (including 0%), Cr: 15.0 to 25.0%, Co: 0.1 to 18.0%, Mo: not less than 2.0% and less than 4.0%, Al: 3.0 to 5.0%, Ti: not less than 0.01% and less than 0.5%, Zr: 0.01 to 0.1%, B: 0.001 to 0.015%, Fe: up to 3.0%, Mg or Mg+0.6×Ca: 0.0005 to 0.01%, N: up to 0.01% (including 0%), O: up to 0.005% (including 0%), and the balance of Ni with inevitable impurities, S/Mg or S/(Mg+0.6×Ca) being up to 1.0, and a G value represented by the following formula (1) being 30 to 45. G=7+0.11Cr+8.23Al+4.66Ti-0.

Abstract: A low thermal expansion superalloy is composed of, in mass %, 0.1% or less of C, 0.1-1.0% of Si, 1.0% or less of Mn, 25-32% of Ni, more than 18% but less than 24% of Co, more than 0.25% but 1.0% or less of Al, 0.5-1.5% of Ti, more than 2.1% but less than 3.0% of Nb, 0.001-0.01% of B and 0.0005-0.01% of Mg, with the balance of Fe and unavoidable impurities, while satisfying Mg/S?1, 52.9?1.235Ni+Co<55.8%, (Al+Ti+Nb) is 3.5-5.5%, and the F value is 8% or less. In the superalloy, a granular intermetallic compound containing Si, Nb, and Ni alone or in a total amount of 36 mass % or more is precipitated at a grain boundary of an austenite matrix, and an intermetallic compound including a larger concentration of Ni, Al, Ti, and Nb and having 50 nm or smaller of an average diameter is precipitated in the austenite matrix.

Abstract: A martensitic stainless steel for a fuel injection member contains, in mass %, at least 0.35% and less than 0.50% of C, more than 0.20% and at most 0.40% of Si, 0.2-0.4% of Mn, 0.25% or less of Ni, 15.0-17.0% of Cr, more than 2.0% and at most 3.0% of Mo, 0.1-0.3% of W, 0.001-0.003% of B, and at least 0.15% and less than 0.20% of N, with the remainder comprising Fe and inevitable impurities, which include 0-0.025% of P, 0-0.005% of S, 0-0.2% of Cu, 0-0.05% of Al, 0-0.02% of Ti, 0-0.02% of Nb, 0-0.15% of V, 0-0.003% of O, and 0-0.001% of H.

Abstract: A low thermal expansion superalloy is composed of, in mass %, 0.1% or less of C, 0.1-1.0% of Si, 1.0% or less of Mn, 25-32% of Ni, more than 18% but less than 24% of Co, more than 0.25% but 1.0% or less of Al, 0.5-1.5% of Ti, more than 2.1% but less than 3.0% of Nb, 0.001-0.01% of B and 0.0005-0.01% of Mg, with the balance of Fe and unavoidable impurities, while satisfying Mg/S?1, 52.9?1.235Ni+Co<55.8%, (Al+Ti+Nb) is 3.5-5.5%, and the F value is 8% or less. In the superalloy, a granular intermetallic compound containing Si, Nb, and Ni alone or in a total amount of 36 mass % or more is precipitated at a grain boundary of an austenite matrix, and an intermetallic compound including a larger concentration of Ni, Al, Ti, and Nb and having 50 nm or smaller of an average diameter is precipitated in the austenite matrix.

Abstract: Provided is a metal gasket including, expressed in mass %, C: 0.10% or less, Si: 1.0% or less, Mn: 2.0% or less, P: 0.04% or less (including 0%), S: 0.01% or less (including 0%), Ni: 25.0-60.0%, Cr: 10.0-20.0%, either Mo or W alone, or both Mo+W/2:0.05-5.0%, Al: more than 0.8% to 3.0% or less, Ti: 1.5-4.0%, Nb: 0.05-2.5%, V: 1.0% or less (including 0%), B: 0.001-0.015%, Mg: 0.0005-0.01%, S/Mg: 1.0 or less, N: 0.01% or less (including 0%), and O: 0.005%) or less (including 0%), with the remainder being Fe and unavoidable impurities. The metal gasket has a metal structure in which a precipitate ?? phase having an average equivalent circle diameter of 25 nm or larger is not present within the austenite base.

Abstract: A high-strength Ni-base alloy having favorable corrosion resistance, high strength, and high ductility, around room temperature is provided. A high-strength Ni-base alloy includes: in % by mass, less than 0.01% of C, not more than 0.5% of Si, not more than 0.5% of Mn, 15 to 25% of Cr. 1.0 to 5.0% of Mo or Mo+0.5W, 0.2 to 0.8% of Al, 1.0 to 2.0% of Ti, 3.00 to 3.80% of Nb, not more than 30% of Fe, and 0.0007 to 0.010% of Mg; Ni; and impurities. A value represented by Mg/S is not less than 0.7, and an A value is not less than 0.015 and less than 0.027, the A value being represented by A value=Al/(Al+1.77(Ti?1.36C)+3.44(Nb?5.1C)).

Abstract: An electrode material for at least one of a center electrode (5) and a ground electrode (27) provided with a chip (31, 32) for use in a spark plug (1). The electrode material contains Ni as a principal component, and has a Si content of from 0.50% to 1.0% by mass, an Al content of from 0.2% to 2.0% by mass, a Cr content of from 12% to 34% by mass, a rare-earth element or the like content of from 0.03% to 0.2% by mass, a Fe content of more than 0% but not more than 20% by mass, a C content of not more than 0.10% by mass, and a Mn content of not more than 1.0% by mass. The total content of Si and Al is not less than 0.80% by mass, and less than one tenth of the Cr content.

Abstract: There is provided a steel for solid oxide fuel cells which contains Zr and has a composition balance which allows a thin plate to stably obtain excellent oxidation resistance. The steel for solid oxide fuel cells contains more than 0 and not more than 0.05 mass % of C, 0.05 mass % or less of N, 0.01 mass % or less of O, 0.2 mass % or less of Al, 0.15 mass % or less of Si, 0.1 to 1.0 mass % of Mn, 20.0 to 25.0 mass % of Cr, more than 0 mass % and not more than 1.0 mass % of Ni, 0.02 to 0.12 mass % of La, 0.1 to 0.5 mass % of Zr, 0.15 to 0.5 mass % of La+Zr, and Fe and impurities as a remainder. The following relational formula is satisfied, and an Fe and Zr-containing intermetallic compound viewed in a ferrite matrix is 1.1 mass % or less in terms of a visual field area ratio.

Abstract: A high-strength Ni-base alloy having favorable corrosion resistance, high strength, and high ductility, around room temperature is provided. A high-strength Ni-base alloy includes: in % by mass, less than 0.01% of C, not more than 0.5% of Si, not more than 0.5% of Mn, 15 to 25% of Cr. 1.0 to 5.0% of Mo or Mo+0.5W, 0.2 to 0.8% of Al, 1.0 to 2.0% of Ti, 3.00 to 3.80% of Nb, not more than 30% of Fe, and 0.0007 to 0.010% of Mg; Ni; and impurities. A value represented by Mg/S is not less than 0.7, and an A value is not less than 0.015 and less than 0.027, the A value being represented by A value=Al/(Al+1.77(Ti?1.36C)+3.44(Nb?5.1C)).

Abstract: An electrode material for at least one of a center electrode (5) and a ground electrode (27) provided with a chip (31, 32) for use in a spark plug (1). The electrode material contains Ni as a principal component, and has a Si content of from 0.50% to 1.0% by mass, an Al content of from 0.2% to 2.0% by mass, a Cr content of from 12% to 34% by mass, a rare-earth element or the like content of from 0.03% to 0.2% by mass, a Fe content of more than 0% but not more than 20% by mass, a C content of not more than 0.10% by mass, and a Mn content of not more than 1.0% by mass. The total content of Si and Al is not less than 0.80% by mass, and less than one tenth of the Cr content.

Abstract: Disclosed is steel for a solid oxide fuel cell, which has excellent oxidation resistance, reduces Cr evaporation, has good electrical conductivity and has a thermal expansion coefficient similar to that of a ceramic component such as an electrolyte or an electrode. Specifically disclosed is steel for solid oxide fuel cells, which has excellent oxidation resistance and contains, in mass %, 0.1% or less of C, 0.2% or less of Al, 0.2% or less of Si, 0.4% or less of Mn, 16.0-28.0% of Cr, 1.5% or less of Ni, 1.0% or less of REM and/or Zr in total, 1.0-3.0% of W, and more than 0.2% but 4.0% or less of Cu, with the balance made up of Fe and unavoidable impurities.

Abstract: An electrode material to be used for producing an earth electrode of a spark plug has a chemical composition of 0.3 to 3.0 mass % of Si, 0.01 to 0.3 mass % of one or more elements selected from the group consisting of Y and rare earth elements, not more than 0.5 mass % of Ti, not more than 1.2 mass % of Fe, and one or both of not more than 0.20 mass % of Ca and not more than 0.08 mass % of Mg. The electrode material further contains C, Mn, Cr, Al, N, S, a remainder Ni, and incidental impurities. In a total content of C, Mn, Cr, Al, N and S, C is not more than 0.1 mass %, Mn is less than 0.5 mass %, Cr is less than 0.5 mass %, Al is not more than 0.3 mass %, N is not more than 0.05 mass %, and S is not more than 0.03 mass %.

Abstract: Provided is an Ni-base alloy excellent in strength, ductility and other properties through the resolution of micro-segregation. Also provided is a process for manufacturing an Ni-base alloy containing by mass C:0.15% or less, Si:1% or less, Mn:1% or less, Cr:10 to 24%, Mo+(1/2)W (where Mo may be contained either alone or as an essential component):5 to 17%, Al:0.5 to 1.8%, Ti:1 to 2.5%, Mg:0.02% or less, and either B:0.02% or less and/or Zr:0.2% or less at an Al/(Al+0.56Ti) ratio of 0.45 to 0.70 with the balance consisting of Ni and impurities, which comprises subjecting, at least one time, an Ni-base alloy material which is prepared by vacuum melting and has the above composition to homogenization heat treatment at 1160 to 1220° C. for 1 to 100 hours. The Mo segregation ratio of the alloy is controlled to 1 to 1.17 by the homogenization heat treatment.