Patents by Inventor Toshikazu Umemura

Toshikazu Umemura has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5717055
    Abstract: A method of producing polycarbonate resin pellets containing very less residual organic solvent and low molecular weight volatile matters and having a high transparency by melt-kneading a polycarbonate resin powder in an extruder equipped with a screw having a material seal mechanism, and vents, and devolatilizing the residual organic solvent and/or the low molecular weight volatile matters at the vent portion and then extruding the molten resin.The polycarbonate resin pellets are suitable for optical grade articles and automobile lenses.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: February 10, 1998
    Assignee: Mitsubishi Gas Chemical Company, LTD.
    Inventors: Tatsuhide Hosomi, Toshikazu Umemura, Toshiaki Takata, Yuji Mori
  • Patent number: 5438108
    Abstract: A grafted aromatic polycarbonate resin is produced by melt-kneading a graft precursor comprising a mixture of 35 to 95% by weight of aromatic polycarbonate resin particles and 65 to 5% by weight of vinylic copolymer containing active oxygen, the vinylic copolymer being present in the aromatic polycarbonate resin particles, thereby subjecting to grafting reaction of the aromatic polycarbonate resin and the vinylic copolymer, where the grafting reaction can be sufficiently carried out and thus the grafted polycarbonate resin is useful for molding materials for optical disks, optical lenses, etc. a polymer blend-compatible agent, adhesives, paints, etc.
    Type: Grant
    Filed: January 25, 1994
    Date of Patent: August 1, 1995
    Assignees: Mitsubishi Gas Chemical Company, Inc., NOF Corporation
    Inventors: Toshikazu Umemura, Takayuki Watanabe, Tatsuo Iwai, Motoyuki Sugiura
  • Patent number: 5427998
    Abstract: A polycarbonate resin solution for forming a thermal-sublimating dye-receiving layer film, comprising a random copolycarbonate resin dissolved in an organic solvent, the resin having a structural unit represented by following formula (1) and a structural formula represented by following formula (2) or (3), the molar ratio of the structural unit represented by formula (1) to the structural unit represented by formula (2) or (3) being from 35/65 to 65/35, and having a number average molecular weight of from 5,000 to 50,000. ##STR1## wherein R.sup.1 to R.sup.12 each represents a hydrogen atom, a halogen atom, or an alkyl group having from 1 to 4 carbon atoms and in formula (1), A represents a straight chain, branched, or cyclic alkylidene group having from 1 to 10 carbon atoms, an aryl-substituted alkylidene group, an arylene group, or a sulfonyl group.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: June 27, 1995
    Assignee: Mitsubishi Gas Chemical Co., Ltd.
    Inventors: Toshikazu Umemura, Satoshi Kanayama
  • Patent number: 5426159
    Abstract: Disclosed is a process for producing a grafted polycarbonate resin for optical use, which comprises adding to an aqueous suspension of an aromatic polycarbonate resin having radical-polymerizable unsaturated terminal group on a molecule wherein the aromatic polycarbonate resin has an average particle diameter of 0.1 to 5 mm and an apparent density of 0.2 to 0.9 g/cm.sup.3, a vinyl monomer and a radical-polymerization initiator, heating the aqueous suspension at a lower temperature by 5.degree. C. to 20.degree. C. than the decomposition temperature for a half-life period of 10 hours of the radical-polymerization initiator, thereby impregnating the polycarbonate resin with the vinyl monomer and the radical-polymerization initiator, then elevating the temperature to the range of from a lower temperature by 50.degree. C. to a higher temperature by 30.degree. C.
    Type: Grant
    Filed: July 15, 1993
    Date of Patent: June 20, 1995
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Toshikazu Umemura
  • Patent number: 5244605
    Abstract: In a process for producing a halogenated polycarbonate molded article from a powder or pellets of a halogenated polycarbonate resin or composition thereof by means of injection molding using an injection molding machine, the improvement wherein the injection molding machine comprises a cylinder whose inner circumferential wall being made of a corrosion-resistant and abrasion-resistant alloy comprising alloy component (1), (2), or (3) given below, and a screw part made of a steel having a metal coating formed by hard chromium plating or hard nickel plating or made of SUS420, SUS440, Hastelloy C, or a steel comprising alloy component (4) given below:______________________________________ Alloy component (1): C: 0.5-2 wt % Si: 1-5 wt % B: 0.5-5 wt % Ni: 10-25 wt % Cr: 20-35 wt % W: 10-25 wt % Cu: 0.5 -5 wt % Remainder: Co and unavoidable impurities, Alloy component (2): Si: 0.2-4 wt % Mn: 0.
    Type: Grant
    Filed: June 12, 1991
    Date of Patent: September 14, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Toshikazu Umemura, Toshiaki Asoh
  • Patent number: 5116547
    Abstract: A method of coloring a polycarbonate extruded or molded product for optical members, which is colored by a liquid coloring process for obtaining a colored polycarbonate extruded or molded product for optical members by extrusion or injection molding. The process involves mixing a polycarbonate resin for optical members and a liquid coloring agent dispersion obtained by dispersing a coloring agent in a dispersing agent. The dispersing agent includes a specific saturated fatty acid ester or silicon oil. After mixing the polycarbonate resin and liquid coloring agent dispersion, the resulting mixture is melted and thereafter extruded or molded to form a product for optical members.
    Type: Grant
    Filed: July 20, 1990
    Date of Patent: May 26, 1992
    Assignees: Mitsubishi Gas Chemical Co., Victor Company of Japan, Ltd.
    Inventors: Shuji Tsukahara, Toshikazu Umemura, Kazuyoshi Ichise
  • Patent number: 5095049
    Abstract: A process for producing a low-particle-content transparent thermoplastic resin solution, which comprises centrifuging a solution of a transparent thermoplastic resin containing free water to separate it into a resin solution phase, an aqueous phase and an intermediate layer, and separating the resin solution phase from the aqueous phase and the intermediate layer. By this process, the number of particles having a size of at least 0.5 .mu.m in the resin solution can be decreased to 10,000 or less, preferably substantially zero, per gram of the transparent thermoplastic resin.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: March 10, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Kenji Maeda, Toshikazu Umemura, Yuki Ohtani, Takeaki Megumi
  • Patent number: 5073313
    Abstract: A process for producing a polycarbonate molded article having a low dust level from a polycarbonate resin in the form of a powder or pellets by injection molding using an injection molding machine. The injection molding machine includes a cylinder whose inner circumferential wall is made of a corrosion- and abrasion-resistant alloy from alloy components (1), (2), or (3) given below and a screw part made of a steel having a metal coating formed of hard chromium plating or hard nickel plating or formed of titanium carbide or tungsten carbide, or is made of SUS420, SUS440, Hastelloy C, or a steel of alloy component (4) given below:Alloy components (1):C: 0.5-1.5 wt%Si: 1.0-2.0 wt%B: 0.5-2.5 wt%Ni: 10.0-20.0 wt%Cr: 20.0-30.0 wt%W: 10.0-20.0 wt%Cu: 0.5-2.0 wt%Remainder: Co and unavoidable impurities,Alloy components (2):Ni: 0.0-2.0 wt%Cr: 5.0-15.0 wt%Fe: 0.0-1.0 wt%Mn: 0.1-2.0 wt%Si: 0.2-4.0 wt%B: 2.0-4.0 wt%Remainder: Co and unavoidable impurities,Alloy components (3):Cr: 5.0-10.0 wt%Co: 5.0-40.0 wt%Fe: 0.0-10.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: December 17, 1991
    Assignee: Mitsubishi Gas Chemical Co., Ltd.
    Inventors: Toshikazu Umemura, Makoto Matsumura, Toshiaki Izumida, Kazuyuki Akahori
  • Patent number: 4918160
    Abstract: A method for producing a purified polycarbonate resin is disclosed, comprising contacting a solid polycarbonate resin with a fluid comprising at least 70% by weight of carbon dioxide and having a temperature of 30.degree. to 120.degree. C. and a pressure of at least 10 kg/cm.sup.2. The method can effectively remove almost all the impurities contained in the polycarbonate resin within a very short period of time, thereby providing highly purified polycarbonate resin materials which are suitably used in the fields of information, electronic and medical industries.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: April 17, 1990
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Shigeo Kondoh, Toshikazu Umemura
  • Patent number: 4845193
    Abstract: A process for producing a low-particle polycarbonate resin molding material suitable for use as molding material for optical materials is disclosed, which comprises directly supplying a polycarbonate resin wet powder having a water content of from 0.5 to 10.0% by weight and an organic solvent content of from 0.01 to 5.0% by weight, said wet powder, when dried, having a weight average particle diameter of from 5 to 60 mesh, to a vented extruder and extruding the wet powder while venting to obtain pellets containing not more than 20 ppm of a residual halogenated hydrocarbon. The molding material has a greatly decreased solvent content while being freed from a particle content increase.
    Type: Grant
    Filed: July 21, 1988
    Date of Patent: July 4, 1989
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Toshikazu Umemura, Kenji Maeda, Yutaka Kojima, Toshiaki Izumida, Kou Tanabe
  • Patent number: 4681927
    Abstract: A process for producing an oxymethylene copolymer by copolymerizing trioxane with at least one cyclic comonomer selected from the group consisting of cyclic ethers and cyclic formals, said process comprising(1) polymerizing trioxane alone or with a cyclic comonomer in the presence of a polymerization catalyst until the conversion of trioxane reaches 10 to 95%, and(2) thereafter adding a cyclic comonomer and a polymerization catalyst to the reaction system and continuing the polymerization.
    Type: Grant
    Filed: May 27, 1986
    Date of Patent: July 21, 1987
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Toshikazu Umemura, Isamu Masumoto, Yukihiro Iha
  • Patent number: 4526921
    Abstract: An acetal resin composition comprising an acetal resin and a low molecular weight polycarbonate compound having an intrinsic viscosity of 0.2 dl/g or less in methylene chloride at 25.degree. C. and, optionally, an organic or inorganic filler is disclosed. Said composition has improved surface gloss and weather resistance.
    Type: Grant
    Filed: March 5, 1984
    Date of Patent: July 2, 1985
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Masanori Sakurai, Junichi Miyawaki, Toshikazu Umemura, Akiyoshi Shibata
  • Patent number: 4506053
    Abstract: An acetal resin composition comprising(A) an acetal resin,(B) at least one member selected from the group consisting of (1) a polyfunctional cyanic acid ester or its prepolymer, (2) a mixture of a polyfunctional cyanic acid ester or its prepolymer with a polyfunctional maleimide or its prepolymer and (3) a pre-copolymer of a polyfunctional cyanic acid ester and a polyfunctional maleimide,(C) an amine-substituted triazine and/or a cyanoguanidine compound, and(D) an inorganic filler other than glass, and/or an organic filler.
    Type: Grant
    Filed: December 7, 1983
    Date of Patent: March 19, 1985
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Masanori Sakurai, Junichi Miyawaki, Toshikazu Umemura, Toshikatsu Kawata, Shinzi Kiboshi, Akiyoshi Shibata
  • Patent number: 4366305
    Abstract: In a process for producing a stabilized oxymethylene copolymer by heat-melting, at a temperature ranging between the melting point of the copolymer and a temperature 100.degree. C.
    Type: Grant
    Filed: November 17, 1981
    Date of Patent: December 28, 1982
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akira Amemiya, Tadashi Kunii, Tomotaka Furusawa, Mutsuhiko Takeda, Katsumasa Tanaka, Toshikazu Umemura, Yoshihiro Ono, Isamu Masumoto, Noriyasu Nakao, Masanori Furukawa
  • Patent number: 4343929
    Abstract: A process for producing a polyacetal homopolymer or copolymer which comprises continuously feeding a liquid starting mixture containing molten trioxane and a catalyst and optionally a comonomer through a feed opening of a reactor, said reactor being a continuously stirring-type mixer having two stirring shafts having a plurality of plate-like paddles fixed thereto the cross-section of each of said paddles taken perpendicularly of the axial direction of the stirring shaft having a shape of a convex lens, an ellipse or a quasipolygon inscribing a phantom circle at each vertex, one of said paddles facing another paddle fixed to the other stirring shaft and said one paddle being positioned such that it rotates while the edges thereof keep a slight clearance from the inner surface of the barrel and the other paddle; polymerizing the starting mixture while moving it toward the discharge opening by the rotation of the paddles, the improvement wherein the profiles of the paddles are changed, or the arrangement of the
    Type: Grant
    Filed: October 23, 1980
    Date of Patent: August 10, 1982
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Akitoshi Sugio, Kazuyoshi Taka, Akira Amemiya, Tomotaka Furusawa, Mutsuhiko Takeda, Katsumasa Tanaka, Toshikazu Umemura, Yoshihiro Ono
  • Patent number: 4339569
    Abstract: In a process for producing an oxymethylene homopolymer or copolymer having improved stability which comprises polymerizing trioxane or a mixture of trioxane and a cyclic ether and/or a cyclic acetal in bulk in the presence of a catalyst which is at least one compound selected from the group consisting of boron trifluoride, boron trifluoride hydrate and coordination compounds of boron trifluoride with organic compounds containing an oxygen or sulfur atom, the improvement which comprises performing the bulk polymerization without destroying the bulk polymerization system, or which comprises adding a tertiary phosphine compound to the polymerization system to deactivate the catalyst, before the polymerization system formed by the bulk polymerization is destroyed.
    Type: Grant
    Filed: May 19, 1980
    Date of Patent: July 13, 1982
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Akitoshi Sugio, Akira Amemiya, Tadashi Kunii, Tomotaka Furusawa, Mutsuhiko Takeda, Katsumasa Tanaka, Toshikazu Umemura
  • Patent number: 4301273
    Abstract: In a process for producing a stabilized oxymethylene copolymer which comprises heat-melting an oxymethylene copolymer having unstable, unblocked terminals obtained by the copolymerization of trioxane with a cyclic acetal and/or a cyclic ether to heat decompose it in the presence of available heat stabilizers; the improvement which comprises heating said oxymethylene copolymer having unblocked terminals in a mixer at a temperature between the melting point of said oxymethylene copolymer and a point 100.degree. C. higher than said melting point under a pressure of 0.
    Type: Grant
    Filed: May 27, 1980
    Date of Patent: November 17, 1981
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Akira Amemiya, Tadashi Kunii, Tomotaka Furusawa, Mutsuhiko Takeda, Katsumasa Tanaka, Toshikazu Umemura
  • Patent number: 4189565
    Abstract: A process for polymerizing trioxane made from an aqueous solution of methanol-containing formaldehyde by a conventional method or copolymerizing the trioxane with another monomer, characterized bycooling the trioxane to crystallize it,allowing the trioxane in a crystalline state to stand in an open system in an atmosphere of air or an inert gas to remove polyoxymethylene dimethoxide from the trioxane,melting the trioxane, andpolymerizing the trioxane or copolymerizing the trioxane and the another monomer.
    Type: Grant
    Filed: December 20, 1978
    Date of Patent: February 19, 1980
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Akira Amemiya, Tetsuya Abe, Tomotaka Furusawa, Takeo Suzumori, Mutsuhiko Takeda, Masaharu Kimura, Yoshiharu Ohtsuki, Katsumasa Tanaka, Toshikazu Umemura, Kiyokazu Kawaguchi, Michio Ohba
  • Patent number: 4115369
    Abstract: A process for continuously producing an oxymethylene polymer by continuously polymerizing a starting monomer containing at least 50 mole% of trioxane in bulk in the presence of a catalyst, which comprises feeding the starting monomer into a first-stage polymerization reactor having a self-cleaning action to perform a first-stage polymerization reaction until the conversion reaches 40 to 70%, withdrawing the reaction mixture as a powder from the outlet of the first-stage polymerization reactor, feeding the reaction mixture into a second-stage polymerization reactor having a stirring action to perform a second-stage polymerization reaction until the conversion reaches 95 to 100%, and then withdrawing the polymerization product as a powder from the outlet of the second-stage polymerization reactor.
    Type: Grant
    Filed: November 29, 1977
    Date of Patent: September 19, 1978
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Tomotaka Furusawa, Katsumasa Tanaka, Toshikazu Umemura, Hiroyuki Urabe
  • Patent number: 4087411
    Abstract: A process for preparing oxymethylene polymers which comprises polymerizing trioxane or both trioxane and a specific cyclic ether in the presence of a catalytic amount of a boron fluoride-type catalyst, stopping the polymerization, and then subjecting the resulting polymer to a terminal stabilizing treatment, wherein the polymerization is stopped by adding a specific trivalent organic phosphorus compound and then the terminal stabilizing treatment is performed without removing the catalyst from the polymer.
    Type: Grant
    Filed: September 13, 1976
    Date of Patent: May 2, 1978
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Yoshiharu Ohtsuki, Toshikazu Umemura, Makoto Mizutani