Abstract: A hydrogen permeable module includes a hydrogen permeable membrane that permeates hydrogen, an outer peripheral part of the hydrogen permeable membrane being restricted, an inside of the outer peripheral part of the hydrogen permeable membrane being not restricted. The hydrogen permeable module permeates the hydrogen by constantly keeping a pressure of a primary side to a pressure that is equal to or more than a pressure of a secondary side. The inside of the outer peripheral part of the hydrogen permeable membrane is not restricted so as to be capable of expanding to the secondary side.

Abstract: A hydrogen permeable module includes a hydrogen permeable membrane that permeates hydrogen, an outer peripheral part of the hydrogen permeable membrane being restricted, an inside of the outer peripheral part of the hydrogen permeable membrane being not restricted. The hydrogen permeable module permeates the hydrogen by constantly keeping a pressure of a primary side to a pressure that is equal to or more than a pressure of a secondary side. The inside of the outer peripheral part of the hydrogen permeable membrane is not restricted so as to be capable of expanding to the secondary side.

Abstract: The invention intends to provide a hydrogen storage alloy that can absorb and release hydrogen effectively at room temperature and shows excellent hydrogen storage amount and effective hydrogen transfer amount and furthermore shows excellent endurance. A pulverized hydrogen storage alloy powder is heated at 600° C. or more and 1200° C. or less for 10 min to 30 hr to apply strain relief annealing. A particle diameter of the hydrogen storage alloy powder is desirably 10 ?m or less and the hydrogen storage alloy is desirably mainly composed of a BCC phase. Since the initial strain ahead of the hydrogenation is removed, a solid solution region of hydrogen is largely reduced and an initial hydrogen storage amount and an effective hydrogen transfer amount are increased.

Abstract: An Nb—Ti—Co alloy having both good hydrogen permeability and good hydrogen embrittlement resistance comprises one of Fe, Cu or Mn as a fourth element, incorporating from 1 to 14 mol %. The content of Mn, if any, is preferably from 1 to 9 mol %. The desired hydrogen permeability can be attained by the (Nb, Ti) phase and the desired hydrogen embrittlement resistance can be attained by the CoTi phase, making is possible to obtain excellent hydrogen permeability and excellent hydrogen embrittlement resistance. None of Fe, Cu or Mn can impair these properties. Fe, Cu or Mn can replace some of the Co elements. Fe, Cu or Mn enhances the workability of the alloy.

Abstract: A (Nb, Ti) phase in an Nb—Ti—Co alloy is composed of a granular structure. The Nb—Ti—Co alloy is preferably subjected to heat treatment at 800° C. or more so that the eutectic structure in the casted state can be changed to a granular structure. The Nb—Ti—Co alloy used there is preferably NbxTi(100-x-y)Coy, (x?70, 20?y?50 (mol %)). By properly predetermining the heating temperature and time, the resulting alloy exhibits improved hydrogen permeability in combination with a good hydrogen embrittlement resistance characteristic in the CoTi phase, making it possible to provide a practical hydrogen permeable membrane having an advantageously high performance.

Abstract: In a multiphase hydrogen permeation alloy comprising a phase in charge of hydrogen permeation and a phase in charge of hydrogen embrittlement resistance, a structure in which the phase in charge of hydrogen permeability is continuously interconnected and in which more preferably the growth direction of the aforementioned phase in charge of hydrogen permeation lies aligned in the thickness direction of the permeation membrane. As the hydrogen permeation alloy, an Nb—Ti—Co alloy is exemplified, wherein the phase in charge of hydrogen permeability is made of an (Nb, Ti) phase and the aforementioned phase in charge of hydrogen embrittlement resistance is made of a CoTi phase. By virtue of the fact that the growth direction of the phase in charge of hydrogen permeation lies aligned in the thickness direction of the permeation membrane, the hydrogen permeation pass length becomes short to give further improved hydrogen permeation property.

Abstract: To produce a hydrogen storage alloy by melting a hydrogen storage alloy having a body-centered cubic crystal structure without using a refractory crucible and solidifying a molten alloy by a unidirectional solidification process. The unidirectional solidification is carried out by a cold crucible induction melting method at a moving speed of a solid-liquid interface in the range of 10 to 200 mm/hr by using a water-cooled metal crucible in a vacuum or an inert gas atmosphere.

Abstract: In a multiphase hydrogen permeation alloy comprising a phase in charge of hydrogen permeation and a phase in charge of hydrogen embrittlement resistance, a structure in which the phase in charge of hydrogen permeability is continuously interconnected and in which more preferably the growth direction of the aforementioned phase in charge of hydrogen permeation lies aligned in the thickness direction of the permeation membrane. As the hydrogen permeation alloy, an Nb—Ti—Co alloy is exemplified, wherein the phase in charge of hydrogen permeability is made of an (Nb, Ti) phase and the aforementioned phase in charge of hydrogen embrittlement resistance is made of a CoTi phase. By virtue of the fact that the growth direction of the phase in charge of hydrogen permeation lies aligned in the thickness direction of the permeation membrane, the hydrogen permeation pass length becomes short to give further improved hydrogen permeation property.

Abstract: A (Nb, Ti) phase in an Nb—Ti—Co alloy is composed of a granular structure. The Nb—Ti—Co alloy is preferably subjected to heat treatment at 800° C. or more so that the eutectic structure in the casted state can be changed to a granular structure. The Nb—Ti—Co alloy used there is preferably NbxTi(100-x-y)Coy, (x?70, 20?y?50 (mol %)). By properly predetermining the heating temperature and time, the resulting alloy exhibits improved hydrogen permeability in combination with a good hydrogen embrittlement resistance characteristic in the CoTi phase, making it possible to provide a practical hydrogen permeable membrane having an advantageously high performance.

Abstract: An Nb—Ti—Co alloy having both good hydrogen permeability and good hydrogen embrittlement resistance comprises one of Fe, Cu or Mn as a fourth element, incorporating from 1 to 14 mol %. The content of Mn, if any, is preferably from 1 to 9 mol %. The desired hydrogen permeability can be attained by the (Nb, Ti) phase and the desired hydrogen embrittlement resistance can be attained by the CoTi phase, making is possible to obtain excellent hydrogen permeability and excellent hydrogen embrittlement resistance. None of Fe, Cu or Mn can impair these properties. Fe, Cu or Mn can replace some of the Co elements. Fe, Cu or Mn enhances the workability of the alloy.

Abstract: A hydrogen storage alloy of TiaMnbVcZrd (one of two kinds or more of Fe, Co, Cu, Zn, Ca, Al, Mo and Ni)x (herein, a is 10 to 40 atomic %, b is 40 to 60 atomic %, c is 5 to 30 atomic %, d is 15 atomic % or less, and x is 0 to 10 atomic %) is obtained by the rapid solidification (solidification at the cooling rate of desirably 103° C./sec or higher).

Abstract: A high-capacity hydrogen storage alloy has a crystal structure containing a body-centered cubic structure as a single or main phase and made of a composition represented by the general formula TiaCrbMocFed, in which a is in a range of from 25 to 45% by atomic weight, b is in a range of from 30 to 65% by atomic weight, c is in a range of from 5 to 40% by atomic weight, and d is in a range of from 0 to 15% by atomic weight. In production of the alloy, a heat treatment is performed at a temperature in a range of from 1,200 to 1,500° C. for 1 minute to 24 hours and then cooling is performed at a speed equal to or higher than the cooling speed obtained by water cooling.

Abstract: A hydrogen storage alloy of TiaMnbVcZrd (one of two kinds or more of Fe, Co, Cu, Zn, Ca, Al, Mo and Ni)x (herein, a is 10 to 40 atomic %, b is 40 to 60 atomic %, c is 5 to 30 atomic %, d is 15 atomic % or less, and x is 0 to 10 atomic %) is obtained by the rapid solidification (solidification at the cooling rate of desirably 103° C./sec or higher).