Patents by Inventor Toshinori Shiraki

Toshinori Shiraki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20070253772
    Abstract: A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
    Type: Application
    Filed: July 6, 2007
    Publication date: November 1, 2007
    Applicant: ASAHI KASEI CHEMICAL CORPORATION
    Inventors: Nobuaki Kubo, Yasuhiro Kusanose, Shigeo Nakajima, Takaaki Matsuda, Shigeki Takayama, Toshinori Shiraki
  • Patent number: 7279532
    Abstract: A modified hydrogenated copolymer comprising a hydrogenated copolymer and a functional group-containing modifier group bonded to the hydrogenated copolymer, wherein the hydrogenated copolymer is obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the unhydrogenated copolymer having at least one polymer block (H) of the vinyl aromatic monomer units, and wherein the modified hydrogenated copolymer has the following characteristics (1) to (4): (1) a content of the vinyl aromatic monomer units of from more than 60% by weight to less than 90% by weight, based on the weight of the hydrogenated copolymer, (2) a content of the polymer block (H) of from 0.1 to 40% by weight, based on the weight of the unhydrogenated copolymer, (3) a weight average molecular weight of from more than 100,000 to 1,000,000, and (4) a hydrogenation ratio of 70% or more, as measured with respect to the double bonds in the conjugated diene monomer units.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: October 9, 2007
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Masahiro Sasagawa, Shigeki Takayama, Shigeru Sasaki, Takahiro Hisasue, Katsumi Suzuki, Shigeo Nakajima, Toshinori Shiraki
  • Patent number: 7256238
    Abstract: A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: August 14, 2007
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Nobuaki Kubo, Yasuhiro Kusanose, Shigeo Nakajima, Takaaki Matsuda, Shigeki Takayama, Toshinori Shiraki
  • Publication number: 20070179220
    Abstract: An asphalt composition comprising from 0.
    Type: Application
    Filed: March 28, 2007
    Publication date: August 2, 2007
    Inventors: Masahiro Sasagawa, Toshinori Shiraki, Shigeo Nakajima
  • Patent number: 7122594
    Abstract: A modified block copolymer composition comprising (1) 100 parts by weight of a modified block copolymer consisting of vinyl aromatic hydrocarbons and conjugated dienes, containing a functional group having at least one group selected from the group consisting of a hydroxide group, an epoxy group, an amino group, a silanol group and an alkoxysilane group, or a hydrogenation product of the copolymer, and (2) 0.5 to 50 parts by weight at least one of fillers selected from the group consisting of silica-based inorganic fillers, metal oxides and metal hydroxides is disclosed. This modified block copolymer composition is excellent in heat resistance, mechanical strength, transparency, abrasion resistance, and processability.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: October 17, 2006
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Nobuaki Kubo, Yasuhiro Kusanose, Shigeki Takayama, Toshinori Shiraki
  • Publication number: 20060205890
    Abstract: A polymer foam having a specific gravity of from 0.05 to 0.5 and comprising a plurality of cells defined by cell walls which constitute a polymer matrix, wherein the polymer matrix is comprised of 5 to 100 parts by weight of (A) a hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer which contains at least one copolymer block S comprised of vinyl aromatic monomer units and conjugated diene monomer units, and 95 to 0 part by weight of (B) at least one polymer selected from the group consisting of an olefin polymer and a rubbery polymer, and wherein at least one peak of loss tangent (tan?) is observed at ?40° C. to lower than ?10° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer (A).
    Type: Application
    Filed: April 9, 2004
    Publication date: September 14, 2006
    Inventors: Masahiro Sasagawa, Toshinori Shiraki, Chong-Sun Yoo, Jung-Sik Yoon, Kyung-Man Choi, Gi-Yong Um
  • Publication number: 20060128891
    Abstract: A second order modified block copolymer which can be obtained by reacting a first order modified block copolymer with a second order modifier, wherein the first order modified block copolymer comprises a base block copolymer and a functional group-containing first order modifier group bonded to the base block co-polymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second order modifier has a specific functional group which is reactive to the functional group of the first order modifier group of the first order modified block copolymer. A second order modified block copolymer containing polymer composition comprising the second order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
    Type: Application
    Filed: February 2, 2006
    Publication date: June 15, 2006
    Inventors: Nobuaki Kubo, Yasuhiro Kusanose, Shigeo Nakajima, Takaaki Matsuda, Shigeki Takayama, Toshinori Shiraki
  • Publication number: 20050234193
    Abstract: A hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated copolymer containing at least one hydrogenated copolymer block (B) which is obtained by hydrogenating an unhydrogenated random copolymer block comprised of conjugated diene monomer units and vinyl aromatic monomer units, wherein the hydrogenated copolymer has the following characteristics: the hydrogenated copolymer has a content of the vinyl aromatic monomer units of from more than 40% by weight to less than 95% by weight; at least one peak of loss tangent (tan 8) is observed at ?10 to 80° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer; and substantially no crystallization peak ascribed to the copolymer block (B) is observed at ?20 to 80° C. in a differential scanning calorimetry (DSC) chart obtained with respect to the hydrogenated copolymer.
    Type: Application
    Filed: June 26, 2004
    Publication date: October 20, 2005
    Inventors: Masahiro Sasagawa, Toshinori Shiraki, Shigeki Takayama, Shigeru Sasaki, Katsumi Suzuki, Takahiro Hisasue, Kazuo Moritou
  • Publication number: 20050222331
    Abstract: The present invention provides a block copolymer or a hydrogenated product thereof excellent in low-temperature shrinkability, natural shrinkability, rigidity and the like, excellent in a balance of physical properties such as blocking resistance, resistance to fusion bonding in hot water, impact resistance and the like, and having a few fish eyes (FE's) caused by gels. Further, the invention provides a heat shrinkable film and a heat shrinkable multilayer film suitable for drink container packaging, cap seals and the like, using such a block copolymer or the hydrogenated product thereof.
    Type: Application
    Filed: April 23, 2003
    Publication date: October 6, 2005
    Inventors: Susumu Hoshi, Masahiro Mori, Yukio Yamaura, Toshinori Shiraki
  • Publication number: 20050171251
    Abstract: An asphalt composition comprising 0.5 to 50 parts by weight of a block copolymer component (I), 100 parts by weight of an asphalt (II) and 0.01 to 10 parts by weight of at least one vulcanizing agent (III) selected from the group consisting of sulfur and a sulfur-containing compound, wherein the block copolymer component (I) comprises at least one modified block copolymer comprising an unhydrogenated or hydrogenated base block copolymer comprising at least one vinyl aromatic polymer block (A) and at least one conjugated diene polymer block (B), and a functional group-containing modifier group bonded to the base block copolymer.
    Type: Application
    Filed: April 24, 2003
    Publication date: August 4, 2005
    Inventors: Shigeo Nakajima, Toshinori Shiraki
  • Publication number: 20050119414
    Abstract: A modified hydrogenated copolymer comprising a hydrogenated copolymer and a functional group-containing modifier group bonded to the hydrogenated copolymer, wherein the hydrogenated copolymer is obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the unhydrogenated copolymer having at least one polymer block (H) of the vinyl aromatic monomer units, and wherein the modified hydrogenated copolymer has the following characteristics (1) to (4): (1) a content of the vinyl aromatic monomer units of from more than 60% by weight to less than 90% by weight, based on the weight of the hydrogenated copolymer, (2) a content of the polymer block (H) of from 0.1 to 40% by weight, based on the weight of the unhydrogenated copolymer, (3) a weight average molecular weight of from more than 100,000 to 1,000,000, and (4) a hydrogenation ratio of 70% or more, as measured with respect to the double bonds in the conjugated diene monomer units.
    Type: Application
    Filed: February 27, 2003
    Publication date: June 2, 2005
    Inventors: Masahiro Sasagawa, Shigeki Takayama, Shigeru Sasaki, Takahiro Hisasue, Katsumi Suzuki, Shigeo Nakajima, Toshinori Shiraki
  • Publication number: 20050107521
    Abstract: An asphalt composition comprising from 0.
    Type: Application
    Filed: October 20, 2004
    Publication date: May 19, 2005
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Masahiro Sasagawa, Toshinori Shiraki, Shigeo Nakajima
  • Patent number: 6875827
    Abstract: The present invention relates to a hydrogenated polymer which is a hydrogenation product of a conjugated diene polymer having an average vinyl bond content of 20% by weight or more and less than 50% by weight and a weight average molecular weight of 60,000 to 600,000 to a degree such that 85% or more of the residual double bonds in the conjugated diene units are hydrogenated, and which has a molecular weight and a number of terminal methyl group carbons as measured by GPC/FTIR analysis satisfying relationship (1): Va?Vb?0.03Vc??(1) wherein Va, Vb and Vc represent the number of terminal methyl group carbon atoms per 1000 carbon atoms contained in a polymer whose molecular weight is twice the peak top molecular weight, half the peak top molecular weight, and the peak top molecular weight, respectively.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: April 5, 2005
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Masahiro Sasagawa, Shinichi Nakajima, Shigeki Takayama, Takasi Sato, Toshinori Shiraki
  • Patent number: 6815509
    Abstract: A process for hydrogenating a polymer, which process comprises contacting a polymer containing an olefinic unsaturated group with hydrogen in the presence of a hydrogenation catalyst to hydrogenate the olefinic unsaturated group of the polymer, and recycling at least one part of the hydrogenated polymer for hydrogenation. According to the process of the present invention, there can be provided a polymer having a desirable degree of hydrogenation steadily for a long period.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: November 9, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Koichi Miyamoto, Yasumasa Yamakoshi, Toshinori Shiraki
  • Publication number: 20040176514
    Abstract: A modified block copolymer composition comprising (1) 100 parts by weight of a modified block copolymer consisting of vinyl aromatic hydrocarbons and conjugated dienes, containing a functional group having at least one group selected from the group consisting of a hydroxide group, an epoxy group, an amino group, a silanol group and an alkoxysilane group, or a hydrogenation product of the copolymer, and (2) 0.5 to 50 parts by weight at least one of fillers selected from the group consisting of silica-based inorganic fillers, metal oxides and metal hydroxides is disclosed. This modified block copolymer composition is excellent in heat resistance, mechanical strength, transparency, abrasion resistance, and processability.
    Type: Application
    Filed: December 10, 2003
    Publication date: September 9, 2004
    Inventors: Nobuaki Kubo, Yasuhiro Kusanose, Shigeki Takayama, Toshinori Shiraki
  • Publication number: 20040157994
    Abstract: A second-order modified block copolymer which can be obtained by reacting a first-order modified block copolymer with a second-order modifier, wherein the first-order modified block copolymer comprises a base block copolymer and a functional group-containing first-order modifier group bonded to the base block copolymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second-order modifier has a specific functional group which is reactive to the functional group of the first-order modifier group of the first-order modified block copolymer. A second-order modified block copolymer-containing polymer composition comprising the second-order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.
    Type: Application
    Filed: December 4, 2003
    Publication date: August 12, 2004
    Inventors: Nobuaki Kubo, Yasuhiro Kusanose, Shigeo Nakajima, Takaaki Matsuda, Shigeki Takayama, Toshinori Shiraki
  • Publication number: 20030162908
    Abstract: The present invention relates to a hydrogenated polymer which is a hydrogenation product of a conjugated diene polymer having an average vinyl bond content of 20% by weight or more and less than 50% by weight and a weight average molecular weight of 60,000 to 600,000 to a degree such that 85% or more of the residual double bonds in the conjugated diene units are hydrogenated, and which has a molecular weight and a number of terminal methyl group carbons as measured by GPC/FTIR analysis satisfying relationship (1):
    Type: Application
    Filed: December 11, 2002
    Publication date: August 28, 2003
    Inventors: Masahiro Sasagawa, Shinichi Nakajima, Shigeki Takayama, Takasi Sato, Toshinori Shiraki
  • Publication number: 20020107423
    Abstract: A process for hydrogenating a polymer, which process comprises contacting a polymer containing an olefinic unsaturated group with hydrogen in the presence of a hydrogenation catalyst to hydrogenate the olefinic unsaturated group of the polymer, and recycling at least one part of the hydrogenated polymer for hydrogenation. According to the process of the present invention, there can be provided a polymer having a desirable degree of hydrogenation steadily for a long period.
    Type: Application
    Filed: February 19, 2002
    Publication date: August 8, 2002
    Inventors: Koichi Miyamoto, Yasumasa Yamakoshi, Toshinori Shiraki
  • Patent number: 5332784
    Abstract: A terminal-modified block copolymer having the rest of an amino group or imido group-containing terminal-treating agent bonded to the polymer terminal which is obtained by treating the active terminal of a block copolymer comprising conjugated dienes and vinylaromatic hydrocarbon compounds which is obtained by using as the polymerization initiator at least one member selected from alkali metals or organoalkali metals and has a vinylaromatic hydrocarbon content of 5 to 95% by weight and a number average molecular weight of 5,000 to 1,000,000 with at least one terminal-treating agent selected from imide compounds, cyanamide compounds, aziridinyl compounds, amide compounds, or tertiary amino group-containing compounds other than said compounds; and an adhesive composition excellent in tackiness, adhesiveness, and creep resistance characteristic which comprises said block copolymer and a tackifier resin, 9 water-absorbing composition comprising said block copolymer and a highly water-absorbing resin, a thermoplas
    Type: Grant
    Filed: May 13, 1992
    Date of Patent: July 26, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Toshinori Shiraki, Yasuo Hattori
  • Patent number: 5278246
    Abstract: A modified block copolymer composition comprising a thermoplastic polymer and a modified block copolymer consisting essentially of a base block copolymer of a monovinyl substituted aromatic hydrocarbon polymer block and an olefin compound polymer block having an ethylenic unsaturation degree not exceeding 20%, the base block copolymer having a molecular unit containing a carboxylic acid group and/or a group derived therefrom grafted thereto. The modified block copolymer composition of the present invention is a resinous composition excellent in impact resistance, adhesion, paint adhesion, weatherability, resistance to thermal deterioration, transparency and gloss or a rubbery or leather-like composition excellent in heat resistance, adrasion resistance, compression set resistance, adhesion, transparency, oil resistance, weatherability and resistance to heat aging.
    Type: Grant
    Filed: February 20, 1992
    Date of Patent: January 11, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Toshinori Shiraki, Fusakazu Hayano, Hideo Morita