Patents by Inventor Toshio Hironaka

Toshio Hironaka has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5321160
    Abstract: A process for producing an ethylenamine, which comprises reacting ammonia and/or an ethylenamine with an ethanolamine in the presence of hydrogen to obtain an ethylenamine having an increased number of ethylene chains over the ammonia and/or the ethylenamine used as the starting material, wherein a catalyst comprising Ni, X and M elements wherein X is Re, Ir, Pt or Pd, and when X is Re, Ir or Pb, M is at least one rare earth element selected from the group consisting of scandium, yttrium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium, and when X is Pd, M is at least one member selected from the group consisting of rare earth elements is used for the reaction.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: June 14, 1994
    Assignee: Tosoh Corporation
    Inventors: Toshio Hironaka, Noritaka Nagasaki, Yasushi Hara
  • Patent number: 5248827
    Abstract: A process for producing an ethylenamine, which comprises reacting ammonia and/or an ethylenamine with an ethanolamine in the presence of hydrogen to obtain an ethylenamine having an increased number of ethylene chains over the ammonia and/or the ethyelenamine used as the starting material, wherein a catalyst comprising Ni and M elements wherein M is at least one rare earth element selected from the group consisting of scandium, yttrium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium, is used for the reaction.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: September 28, 1993
    Assignee: Tosoh Corporation
    Inventors: Yasushi Hara, Toshio Hironaka, Noritaka Nagasaki, Nobuyuki Kanai, Nobumasa Suzuki, Yukio Ito, Takanori Miyake
  • Patent number: 5001289
    Abstract: Disclosed is a shaped zeolite catalyst used for liquid phase organic reactions. The shaped zeolite catalyst is composed of substantially spherical particles having a particle diameter substantially in the range of from 70 to 300 .mu.m, and which has fine pores having a pore volume of 0.4 to 1 cc per gram of the shaped catalyst and a median pore diameter based on the pore volume of 1,000 to 5,500 .ANG..
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: March 19, 1991
    Assignee: Tosoh Corporation
    Inventors: Masao Nakano, Kazuhiko Sekizawa, Toshio Hironaka, Kiyotaka Oyama, Seiichi Asano
  • Patent number: 4914247
    Abstract: A para-substituted halogenobenzene derivative is prepared by halogenating a benzene derivative in the liquid phase in the presence of a molded zeolite catalyst body comprising, based on the weight of the molded zeolite catalyst body, 10 to 95% by weight of an L-type zeolite as the anhydrous state and 5 to 90% by weight of amorphous silica.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: April 3, 1990
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Kazuhiko Sekizawa, Toshio Hironaka, Masao Nakano, Yukihiro Tsutsumi
  • Patent number: 4861929
    Abstract: A p-substituted halobenzene derivative, which is very valuable in industry, can be obtained by halogenation of benzene and/or a benzene derivative in the liquid phase using, as a catalyst, a faujasite type zeolite in the presence of any one member selected from the group consisting of sulfur-containing compounds, nitrogen-containing organic basic compounds, salts of said nitrogen-containing organic basic compounds, and a mixture of said nitrogen-containing organic basic compounds and salts thereof.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: August 29, 1989
    Assignee: Tosoh Corporation
    Inventors: Takanori Miyake, Kazuhiko Sekizawa, Toshio Hironaka, Yukihiro Tsutsumi
  • Patent number: 4849560
    Abstract: p-Substituted halogenated benzene derivatives are prepared at a high selectivity by halogenating benzene and/or benzene derivatives by using as a catalyst a zeolite modified with a metal salt.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: July 18, 1989
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Kazuhiko Sekizawa, Takanori Miyake, Toshio Hironaka, Yukihiro Tsutsumi
  • Patent number: 4792644
    Abstract: In the liquid phase chlorination of benzene derivatives including benzene per se in the presence of a zeolite possessing the main pores having the opening formed of a 12-membered oxygen ring; para-substituted chlorinated benzene derivatives are preferentially obtained by adding a small quantity of a quaternary ammonium salt or salts to the reaction mixture.
    Type: Grant
    Filed: June 18, 1987
    Date of Patent: December 20, 1988
    Assignee: Tosoh Corporation
    Inventors: Toshio Hironaka, Kazuhiko Sekizawa, Yukihiro Tsutsumi
  • Patent number: 4528410
    Abstract: Olefins are hydrated to the corresponding alcohols in the presence of at least one crystalline alumino-silicate selected from offretite, ferrierite and erionite. The offretite, ferrierite and erionite are preferably characterized by X-ray diffraction patterns shown in Tables 1 and 7; Tables 2, 8 and 9; and Table 3, respectively. At least a part of the exchangeable cations in the offretite, ferrierite and erionite may be exchanged with at least one cation selected from a hydrogen ion, an alkaline earth metal ion and a rare earth metal ion. Furthermore, at least a part of the exchangeable cations in the erionite may be exchanged with an ammonium ion and/or an alkali metal ion.
    Type: Grant
    Filed: October 13, 1983
    Date of Patent: July 9, 1985
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Teruhisa Sakamoto, Satoshi Ishida, Toshio Hironaka, Yukihiro Tsutsumi
  • Patent number: 3943161
    Abstract: Conjugated dienes containing a cyano group having the formula ##EQU1## wherein R.sub.1 and R.sub.2 represent hydrogen atom, an alkyl group or a phenyl group are produced by dehydrating 2-cyano-3-hydroxy-1-olefins in the presence of an alkaline catalyst while continually removing the product being formed from the reaction system.
    Type: Grant
    Filed: November 27, 1974
    Date of Patent: March 9, 1976
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Yuji Nonaka, Keiichi Kihara, Toshio Hironaka, Yasuhiro Oda