Patents by Inventor Tosko A. Misev

Tosko A. Misev has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9434853
    Abstract: Heat-curable powder coating compositions are provided which include i) at least one crystalline polyester resin present in an amount of at least 7.5 wt %; ii) at least one amorphous polyester resin present in an amount of at most 92.5 wt %; and iii) at least one peroxide present in an amount of at least 0.65 parts of peroxide in hundred parts of i)+ii) (pph), wherein the at least one crystalline polyester resin has 2-butenedioic acid ethylenic unsaturations and/or the at least one amorphous polyester resin has 2-butenedioic acid ethylenic unsaturations. The compositions may be cured to an acceptable degree at low temperature, e.g., 130° C. /20 minutes offering powder coatings that may exhibit enhanced flexibility and good adhesion. In addition, the compositions can suitably be used on heat- and/or non heat-sensitive substrates, even if the composition is highly pigmented.
    Type: Grant
    Filed: May 6, 2011
    Date of Patent: September 6, 2016
    Assignee: DSM IP ASSETS B.V.
    Inventors: Tosko Misev, Leendert Jan Molhoek, Johan Franz Gradus Jansen, Matthias Johannes Cornelis Bos, Gerrit Johannes De Lange, Gerbert Dijkstra
  • Publication number: 20130211002
    Abstract: The invention relates to heat-curable powder coating composition comprising: i) at least one crystalline polyester resin present in an amount of at least 7.5 wt %; and ii) at least one amorphous polyester resin present in an amount of at most 92.5 wt %; and iii) at least one peroxide present in an amount of at least 0.
    Type: Application
    Filed: May 6, 2011
    Publication date: August 15, 2013
    Applicant: DSM IP Assets B.V.
    Inventors: Tosko Misev, Leendert Jan Molhoek, Johan Franz Gradus Jansen, Matthias Johannes Cornelis Bos, Gerrit Johannes De Lange, Gerbert Dijkstra
  • Patent number: 7076142
    Abstract: The present invention relates to coated photonic crystal fibers including a photonic crystal fiber and a protective coating surrounding the photonic crystal fiber. The coating is obtained by curing a resin composition, which may include a urethane (meth)acrylate oligomer. The present invention also relates to a coated photonic crystal fiber including a photonic crystal fiber and a protective coating having a refractive index below 1.45.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: July 11, 2006
    Assignee: DSM IP Assets B.V.
    Inventors: Timothy E. Bishop, Tosko Misev
  • Publication number: 20040105643
    Abstract: The present invention relates to coated photonic crystal fibers.
    Type: Application
    Filed: July 18, 2003
    Publication date: June 3, 2004
    Inventors: Timothy E. Bishop, Tosko Misev
  • Publication number: 20030170568
    Abstract: The invention relates to a radiation curable powder photoresist composition comprising the components A a polymer, B a reactive compound having unsaturated groups and C a free radical photoinitiator, wherein the powder photoresist composition is soluble in a developer and wherein the powder photoresist composition has a Tg between 40 and 120° C.
    Type: Application
    Filed: October 30, 2002
    Publication date: September 11, 2003
    Inventors: Tosko A. Misev, Svetlana A. Bratslavsky, Robert Van De Berg Jeths, Paul H. Binda, Steven R. Schmid
  • Publication number: 20020103329
    Abstract: The invention relates to a powder paint binder-composition comprising a polymer that contains endomethylene tetrahydrophthalic acid units and a crosslinker.
    Type: Application
    Filed: November 30, 2001
    Publication date: August 1, 2002
    Applicant: DSM N.V.
    Inventors: Fokeltje A. Koldijk, Eimbert G. Belder, Coenraad M. Gehrels, Tosko A. Misev
  • Patent number: 6342273
    Abstract: The invention relates to a process for coating a substrate with a powder paint composition. The powder paint particles are first charged by friction or induction in the presence of magnetic or nonmagnetic particles, are next transported and are then applied to the substrate or applied to a transfer medium and subsequently transferred to the substrate, by means of an electric field between the substrate respectively the transfer medium and the means of transport whereafter the ponder paint composition is cured or fused to obtain a powder coating.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: January 29, 2002
    Assignees: DSM N.V., Michael Huber Munchen GmbH
    Inventors: Johannes W. H. Handels, Paulus A. M. Steeman, Detlef Schulze-Hagenest, Burkard Huber, Tosko A. Misev, Jorg Buchweitz
  • Patent number: 6337137
    Abstract: The invention relates to a powder paint composition comprising a polymer that contains endomethylene tetrahydrophthalic acid units and a crosslinker. The polymer is obtained by preparing an unsaturated polymer in a first step, which then reacts with cyclopentadiene at a temperature between 160 ° C and 220 ° C in a second step. The polymer preferably contains more than 10 wt.% endomethylene tetrahydrophthalic acid units and is preferably an unsaturated polymer.
    Type: Grant
    Filed: October 14, 1999
    Date of Patent: January 8, 2002
    Assignee: DSM N.V.
    Inventors: Fokeltje A. Koldijk, Eimbert G. Belder, Coenraad M. Gehrels, Tosko A. Misev
  • Patent number: 5763099
    Abstract: The invention relates to a binder composition for powder coatings. The binder composition is substantially based on a mixture of an unsaturated polyester and an oligomer having a plurality of allyl groups and further having at least either ether and ester groups or urethane and optionally ether groups.The oligmer is preferably an allyl ether ester being more preferably the ester of trimethylolpropane diallyl ether or pentaerythritol triallyl ether and a polycarboxylic acid (anhydride).
    Type: Grant
    Filed: May 7, 1996
    Date of Patent: June 9, 1998
    Assignee: DSM N.V.
    Inventors: Tosko A. Misev, Eimbert G. Belder, Fokeltje A. Koldijk
  • Patent number: 5728779
    Abstract: A binder composition for thermosetting powder paints comprising (i) a polymer that is capable of reacting with epoxy groups and (ii) a crosslinker that contains epoxy groups, wherein the crosslinker comprises at least one C.sub.5 to C.sub.26 linear or branched aliphatic chain with the proviso that epoxy groups are carried on at least one aliphatic chain. In order to function as a crosslinker the amount of oxirane-oxygen originating from the crosslinker in the binder composition is higher than 0.1 meq/gram. The crosslinker is, for example, an epoxydized oil, a modified epoxydized oil or an epoxydized alkyd resin. A powder paint comprising the binder composition can contain a suitable catalyst and, optionally, an additional curing agent.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: March 17, 1998
    Assignee: DSM N.V.
    Inventors: Adrianus J. van de Werff, Leendert J. Molhoek, Marten Houweling, Robert van den Berg Jeths, Dirk A. W. Stanssens, Robert van der Linde, Tosko A. Misev
  • Patent number: 5326832
    Abstract: The invention relates to a powder paint, comprising a polyepoxy compound, a polyester resin and customary additives, the polyester resin having an acid number ranging from 15 through 70 and a hydroxyl number of 10 or below and being substantially based on units of dicarboxylic acids, glycols and monomers of functionality three or higher, wherein the dicarboxylic acids are comprised of at least 15 mole % of isophthalic acid and at least 5 mole % of 1,4-cyclohexane dicarboxylic acid and wherein the glycols are comprised of at least 50 mole % of branched aliphatic glycols with 5-11 carbon atoms, which may optionally comprise an ester group, and at most 50 mole % of aliphatic glycol with 2-6 carbon atoms, and wherein the monomers have a functionality three or higher in an amount of at most 8 mole % of dicarboxylic acids plus glycols.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: July 5, 1994
    Assignee: DSM N.V.
    Inventors: Eimbert G. Belder, Fokeltje A. Koldijk, Frits Visser, Tosko A. Misev, Albertus R. Hofkamp, Marten Houweling
  • Patent number: 5321100
    Abstract: The invention relates to a powder paint, comprising a polyepoxy compound, a polyester resin and customary additives, the polyester resin having an acid number ranging from 15 through 70 and a hydroxyl number of 10 or below and being substantially based on units of dicarboxylic acids, glycols and monomers of functionality three or higher, wherein the dicarboxylic acids are comprised of at least 15 mole % of isophthalic acid and at least 5 mole % of 1,4-cyclohexane dicarboxylic acid and wherein the glycols are comprised of at least 50 mole % of branched aliphatic glycols with 5-11 carbon atoms, which may optionally comprise an ester group, and at most 50 mole % of aliphatic glycol with 2-6 carbon atoms, and wherein the monomers have a functionality three or higher in an amount of at most 8 mole % of dicarboxylic acids plus glycols.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: June 14, 1994
    Assignee: DSM N.V.
    Inventors: Eimbert G. Belder, Fokeltje A. Koldijk, Frits Visser, Tosko A. Misev, Albertus R. Hofkamp, Marten Houweling
  • Patent number: 5168110
    Abstract: The present invention relates to a powder coating based on a carboxyl-functional polyester and an epoxy-functional cross-linking agent. The cross-linking agent is the reaction product of an isocyanate-containing compound and a hydroxyglycidyl ester. The present invention also relates to the reaction product of a hydroxylglycidyl ester and an isocyanate-containing compound based on an active hydrogen-containing compound and a polyisocyanate. The present invention also relates to hydroxyglycidyl esters with a molecular weight between 132 and 500 and reaction products thereof.
    Type: Grant
    Filed: February 15, 1991
    Date of Patent: December 1, 1992
    Assignee: DSM N.V. of Het Overloon
    Inventors: Wilhelmus H. H. A. Van Den Elshout, Herman J. Wories, Tosko A. Misev
  • Patent number: 5124387
    Abstract: The invention relates to a triboelectrically processable powder coating based on a polyester-containing binding agent and a nitrogen-containing additive. The nitrogen-containing additive is a sterically hindered tertiary amine or aminoalcohol.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: June 23, 1992
    Assignee: DSM N.V.
    Inventors: Paul H. G. Binda, Tosko A. Misev
  • Patent number: 5086087
    Abstract: The invention relates to a composition containing UV curable unsaturated monomers and/or oligomers, a photoinitiator and colloidal silica with an organosilane compound, a polyalkoxysilane being used as organosilane compound and the composition containing an acid catalyst.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: February 4, 1992
    Assignee: Stamicarbon B.V.
    Inventor: Tosko A. Misev