Abstract: A fluorinated compound represented by D1-Rf1—O—CH2—(CmF2mO)n-A (wherein D1 is CF3— or CF3—O—, Rf1 is a C1-20 fluoroalkylene group containing at least one hydrogen atom, a C2-20 fluoroalkylene group containing at least one hydrogen atom and having an etheric oxygen atom between carbon-carbon atoms, etc., m is an integer of from 1 to 6, n is an integer of from 1 to 200, and A is a monovalent organic group having at least one (meth)acryloyl group), which is capable of imparting excellent antifouling properties (oily ink repellency, fingerprint stain removability) and lubricity to e.g. a hard coat layer; a hard coat layer-forming composition which contains such a fluorinated compound; and an article having a hard coat layer formed from such a composition.

Abstract: A fluorinated compound represented by D1-Rf1—O—CH2—(CmF2mO)n-A (wherein D1 is CF3— or CF3—O—, Rf1 is a C1-20 fluoroalkylene group containing at least one hydrogen atom, a C2-20 fluoroalkylene group containing at least one hydrogen atom and having an etheric oxygen atom between carbon-carbon atoms, etc., m is an integer of from 1 to 6, n is an integer of from 1 to 200, and A is a monovalent organic group having at least one (meth)acryloyl group), which is capable of imparting excellent antifouling properties (oily ink repellency, fingerprint stain removability) and lubricity to e.g. a hard coat layer; a hard coat layer-forming composition which contains such a fluorinated compound; and an article having a hard coat layer formed from such a composition.

Abstract: To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability.

Abstract: A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

Abstract: To provide an amorphous fluorinated polymer which is soluble in a fluorinated solvent having a boiling point of at most 70° C., and a fluorinated polymer composition containing it. An amorphous fluorinated polymer characterized by having a fluorine content of at least 50 mass % and an intrinsic viscosity of at least 0.03 g/dL and less than 0.05 dL/g as measured in perfluoro(2-butyltetrahydrofuran) at 30° C.

Abstract: To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency and post-air-drying water repellency to the surface of an article and which presents a low environmental impact, and a method for its production. A water/oil repellent composition which comprises a copolymer having structural units based on the following monomer (a), structural units based on the following monomer (b) and structural units based on the following monomer (c), and a medium, wherein the molar ratio of the structural units based on the monomer (a) to the structural units based on the monomer (b) (i.e. (a)/(b)) is at least 1: monomer (a): vinyl chloride; monomer (b): a vinyl ether having no polyfluoroalkyl group and having a crosslinkable functional group; and monomer (c): a monomer having a polyfluoroalkyl group.

Abstract: To provide a copolymer which is capable of providing an article surface with a dynamic water repellency and which has extremely excellent washing durability of water repellency and oil repellency, while placing little burden on the environment; a method for its production; and a water/oil repellent composition. A copolymer comprising structural units of the monomer (a) and structural units of the monomer (b), wherein the total of the content of structural units based on the monomer (a) and the content of structural units based on the monomer (b) is at least 85 mass % of all structural units (100 mass %), and the molar ratio ((a)/(b)) of the content of structural units based on the monomer (a) to the content of structural units based on the monomer (b) is from 0.12 to 3; and a water/oil repellent composition containing such a copolymer.

Abstract: To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability.

Abstract: To provide an amorphous fluorinated polymer which is soluble in a fluorinated solvent having a boiling point of at most 70° C., and a fluorinated polymer composition containing it. An amorphous fluorinated polymer characterized by having a fluorine content of at least 50 mass % and an intrinsic viscosity of at least 0.03 g/dL and less than 0.05 g/dL as measured in perfluoro(2-butyltetrahydrofuran) at 30° C.

Abstract: A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

Abstract: To provide a coating composition useful to form an antireflection film having a refractive index lower than 1.4, excellent in water solubility and long-term stability in the form of a water solution. A coating composition containing a fluoropolymer having ionic functional groups (such as a fluoropolymer having polymer units of —CF2CF[O(CF2)3COOH]—), an acid and an aqueous medium.

Abstract: A composition for a photoresist protective film comprising a fluoropolymer having at least one functional group selected from the group consisting of —COOH, —SO3H, —OP(?O)(OH)2, —NR2 and —N+R3Cl? (wherein R represents a C1-4 alkyl group) and having a weight average molecular weight Mw of from 1,000 to 100,000 and a solvent.

Abstract: To provide a coating composition useful to form an antireflection film having a refractive index lower than 1.4, excellent in water solubility and long-term stability in the form of a water solution. A coating composition containing a fluoropolymer having ionic functional groups (such as a fluoropolymer having polymer units of —CF2CF[O(CF2)3COOH]—), an acid and an aqueous medium.

Abstract: A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

Abstract: A water and oil repellent composition comprising a compound of the following formula (1) and a thermoplastic polymer, as essential components: where the symbols in the formula (1) have the following meanings: Rf: a C1-20 polyfluoroalkyl group, X: (CH2)m, wherein m is an integer of from 1 to 10, A, A1, A2: each independently, O, S or N(Z3), wherein Z3 is a hydrogen atom or an alkyl group, Z1: an octadecyl group, Z2: an alkyl group, or an alkyl group having at least one hydrogen atom substituted, W: a trivalent organic group, and a, b: each independently, 1 or 2, provided that a+b is 2 or 3.

Abstract: A water dispersion type water and oil repellent composition capable of imparting highly long-lasting water and oil repellency to fibers of various materials. It comprises a polymer which essentially contains polymerized units of a (meth)acrylate having a polyfluoroalkyl group and polymerized units of a polymerizable monomer which essentially contains a polymerizable unsaturated group and a hydroxyl group and in which the polymerizable unsaturated group and the hydroxyl group are connected to each other through 7 or more covalent bonds, a surfactant which contains a nonionic surfactant in an amount of from 60 to 100 wt %, an aqueous medium, and a cross-linkable compound.

Abstract: A water repellent composition is provided containing the polymers (A) and (B), wherein polymers (A) and (B) are not present in the same particles, wherein polymer (A) is an addition polymer having at least 60 mass % of polymerized units of a (meth)acrylate (a) having a polyfluoroalkyl group, and 0-40 mass % of a methacrylate (b) having a long chain alkyl group and not a polyfluoroalkyl group, and, if necessary, polymerized units of a polymerizable monomer (x) other than monomers (a) and (b), polymer (B) is an addition polymer having 0-60 mass % of monomer (a), and at least 30 mass % of polymerized units of a polymerizable monomer (c), other than monomers (a) and (b), and, if necessary, polymerized units of a monomer (y) other than monomers (a) and (c), along with an article treated therewith and the method of treating an article with the water repellent composition.

Abstract: A water and oil repellent composition comprising a compound of the following formula (1) and a thermoplastic polymer, as essential components: 1

Abstract: A water repellent composition is provided containing the polymers (A) and (B), wherein polymers (A) and (B) are not present in the same particles, wherein polymer (A) is an addition polymer having at least 60 mass % of polymerized units of a (meth)acrylate (a) having a polyfluoroalkyl group, and 0-40 mass % of a methacrylate (b) having a long chain alkyl group and not a polyfluoroalkyl group, and, if necessary, polymerized units of a polymerizable monomer (x) other than monomers (a) and (b), polymer (B) is an addition polymer having 0-60 mass % of monomer (a), and at least 30 mass % of polymerized units of a polymerizable monomer (c), other than monomers (a) and (b), and, if necessary, polymerized units of a monomer (y) other than monomers (a) and (c), along with an article treated therewith and the method of treating an article with the water repellent composition.

Abstract: The invention relates to a water dispersion type water and oil repellent composition which satisfies both repeated washing durability of water and oil repellency and durability of hydrostatic pressure resistance. A water dispersion type water and oil repellent composition comprising (A) a fluorine-containing copolymer having hydroxy groups, (B) a fluorine-containing copolymer having epoxy groups, (C) a compound having a blocked isocyanate group and having no carbon-carbon unsaturated bond and (D) an amino resin, as effective components.