Abstract: Using a modified CVD infusion process and femtosecond laser irradiation, the methods of the present invention demonstrate the ability to create core-shell nanoparticles of metal and metal oxide nanoparticles embedded within the bulk of an optically transparent substrate. With the use of optical masks and multiple precursor chemicals, the inventive methods make it possible to create nanoparticles or core-shell nanoparticles with drastically different compositions in close proximity to each other. Since the mechanism for precursor decomposition is limited to the surface of the nanoparticles within the substrate, it is possible to control the chemistry, size, and shape of nanoparticles within an optically transparent substrate on a nanoscale.

Abstract: Using a modified CVD infusion process and femtosecond laser irradiation, the methods of the present invention demonstrate the ability to create core-shell nanoparticles of metal and metal oxide nanoparticles embedded within the bulk of an optically transparent substrate. Changes in the optical properties and changes in the structure, size, and shape of the nanoparticles were observed as a result of the methods. It was also observed that core-shell nanoparticles made using the inventive methods preferentially nucleated in the near surface region of the substrate, indicating a precursor-diffusion-dependent process for the nucleation growth of core-shell nanoparticles. With the use of optical masks and multiple precursor chemicals, the inventive methods make it possible to create nanoparticles or core-shell nanoparticles with drastically different compositions in close proximity to each other.