Patents by Inventor Tsu-tzu Tsai

Tsu-tzu Tsai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5098987
    Abstract: There are provided crosslinkable, para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and R is an alkyl group having 1 to 4 carbon atoms. In polymers having two pendant R groups, the R groups can be the same or different.
    Type: Grant
    Filed: November 30, 1990
    Date of Patent: March 24, 1992
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 5098988
    Abstract: There are provided para-ordered aromatic heterocyclic copolymers having repeating groups of the following formulas: ##STR1## wherein a, b, c, d, and e are positive integers, each representing an average number of the respective different recurring units present in the repeating group, m and n are 1 or 2, R and R' are alkyl groups having 1 to 4 carbon atoms, and Q is a benzobisazole group of the formula: ##STR2## wherein Y is --O--, --S--, or --NH--. In the copolymers wherein m or n is 2, the R or R' groups can be the same or different. In copolymer I, the ratio a:b can be about 1:1 to 99:1. In copolymer II, the ratio c:(d+e) can be about 1:1 to 99:1, and the ratio d:e can be about 1:99 to 99:1.
    Type: Grant
    Filed: November 30, 1990
    Date of Patent: March 24, 1992
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 5003035
    Abstract: There are provided para-ordered aromatic heterocyclic copolymers having repeating groups of the following formulas: ##STR1## wherein a, b, c, d, and e are positive integers, each representing an average number of the respective different recurring units present in the repeating group, m and n are 1 or 2, R and R' are alkyl groups having 1 to 4 carbon atoms, and Q is a benzobisazole group of the formula: ##STR2## wherein Y is --O--, --S--, or --NH--. In the copolymers wherein m or n is 2, the R or R' groups can be the same or different. In copolymer I, the ratio a:b can be about 1:1 to 99:1. In copolymer II, the ratio c:(d+e) can be about 1:1 to 99:1, and the ratio d:e can be aobut 1:99 to 99:1.
    Type: Grant
    Filed: July 13, 1989
    Date of Patent: March 26, 1991
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 5001217
    Abstract: There are provided crosslinkable, para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and R is an alkyl group having 1 to 4 carbon atoms. In polymers having two pendant R groups, the R groups can be the same or different.
    Type: Grant
    Filed: July 13, 1989
    Date of Patent: March 19, 1991
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4892921
    Abstract: Provided are novel para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and Q is ##STR2## wherein Z is --O-- or --S--. There are also provided methods for preparing the above polymers.
    Type: Grant
    Filed: February 21, 1989
    Date of Patent: January 9, 1990
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4835246
    Abstract: Provided are novel para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and Q is ##STR2## wherein Z is --O-- or --S--. There are also provided methods for preparing the above polymers.
    Type: Grant
    Filed: August 13, 1987
    Date of Patent: May 30, 1989
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4785115
    Abstract: Provided are benzazole-substituted terephthalic acids of the formula ##STR1## wherein n is 1 or 2 and Q is ##STR2## wherein Z is --O-- or --S--. Also provided are methods for preparing the benzazole substituted terephthalic acid compounds.
    Type: Grant
    Filed: August 13, 1987
    Date of Patent: November 15, 1988
    Assignee: The United States of America as represented by the Secretary of the United States
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4762908
    Abstract: A polymer having repeating units of the general formula ##STR1## wherein BB is a benzobisaxazole, benzobisthiazole or benzobisimidazole group and Y is a phenolic, pyridyl or phenoxyphenyl group.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: August 9, 1988
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4723013
    Abstract: Certain 4,8-disubstituted-2,6-naphthalene dicarboxylic acid monomers and a method for their preparation. These monomers are useful for the preparation of polymers, which polymers may be used to prepare high strength fibers.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: February 2, 1988
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4709006
    Abstract: A polymer having repeating units of the general formula ##STR1## wherein BB is a benzobisaxazole, benzobisthiazole or benzobisimidazole group and Y is a phenolic, pyridyl or phenoxyphenyl group.
    Type: Grant
    Filed: April 16, 1986
    Date of Patent: November 24, 1987
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4578432
    Abstract: Thermally stable aromatic heterocyclic block copolymers are prepared by reacting a diamino monomer and terephthalic acid to form a carboxy-terminated rigid rod segment and then polymerizing a carboxy-monoamine monomer therewith to form flexible segments grafted onto the rigid rod segments.
    Type: Grant
    Filed: April 11, 1985
    Date of Patent: March 25, 1986
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4578434
    Abstract: Thermally stable aromatic heterocyclic block copolymers are prepared by reacting a diamino monomer and terephthalic acid to form a carboxy-terminated rigid rod segment and then polymerizing a carboxy-monoamine monomer therewith to form flexible segments grafted onto the rigid rod segments.
    Type: Grant
    Filed: April 11, 1985
    Date of Patent: March 25, 1986
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4578435
    Abstract: Thermally stable aromatic heterocyclic block copolymers are prepared by reacting a diamino monomer and terephthalic acid to form a carboxy-terminated rigid rod segment and then polymerizing a carboxy-monoamine monomer therewith to form flexible segments grafted onto the rigid rod segments.
    Type: Grant
    Filed: April 11, 1985
    Date of Patent: March 25, 1986
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4559404
    Abstract: Mono -and di-acetylenic-substituted 2-phenylbenzothiazoles are prepared by reacting the corresponding mono- or di-halogen-substituted 2-phenylbenzothiazole with an alkyne, such as 2-methyl-3-butyne-2-ol in the presence of a suitable catalyst.
    Type: Grant
    Filed: December 28, 1983
    Date of Patent: December 17, 1985
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4544713
    Abstract: Thermally stable aromatic heterocyclic block copolymers are prepared by reacting a diamino monomer and terephthalic acid to form a carboxy-terminated rigid rod segment and then polymerizing a carboxy-monoamine monomer therewith to form flexible segments grafted onto the rigid rod segments.
    Type: Grant
    Filed: May 16, 1984
    Date of Patent: October 1, 1985
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4518759
    Abstract: This invention is directed to the preparation of certain arylene bis-silanols in highly purified form and to the preparation of five new arylene bis-silanols in particular, along with a procedure for polymerizing these and other arylene-type bis-silanols using phosgene as a polymerization promotor or catalyst, to obtain highly purified, high molecular weight arylenesiloxanylene polymers having the characteristic structure: ##STR1## where Y is an arylene or substituted arylene moiety: R and R' are the same or different alkyl group(s), substituted alkyl group(s) or a phenyl group, X ranges from about 1 to 3 and n ranges from about 300 to 1500, said polymers having molecular weights (number average) of 100,000 and higher.Preferred polymers are those arylenesiloxanylenecarbonate polymers which, when laminated to polycarbonate sheets or glass maintain their transparency, stability and adherence to said substrates at temperatures of up to and including 400.degree. F.
    Type: Grant
    Filed: January 27, 1982
    Date of Patent: May 21, 1985
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Harold Rosenberg, Tsu-tzu Tsai
  • Patent number: 4442293
    Abstract: Mono- and di-acetylenic-substituted 2-phenylbenzothiazoles are prepared by reacting the corresponding mono- or di-halogen-substituted 2-phenylbenzothiazole with an alkyne, such as 2-methyl-3-butyne-2-ol in the presence of a suitable catalyst.
    Type: Grant
    Filed: March 9, 1982
    Date of Patent: April 10, 1984
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4436886
    Abstract: Mono- and di-acetylenic-substituted 2-phenylbenzothiazoles are thermally self-polymerized to form thermally stable polymers. The polymers are useful as laminating resins for fibrous composites, particularly for high temperature applications.
    Type: Grant
    Filed: February 2, 1983
    Date of Patent: March 13, 1984
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Tsu-Tzu Tsai, Fred E. Arnold
  • Patent number: 4382144
    Abstract: This invention is directed to the preparation of certain arylene bis-silanols in highly purified form and to the preparation of five new arylene bis-silanols in particular, along with a procedure for polymerizing these and other arylene-type bis-silanols using phosgene as a polymerization promotor or catalyst, to obtain highly purified, high molecular weight arylene-siloxanylene polymers having the characteristic structure: ##STR1## where Y is an arylene or substituted arylene moiety; R and R' are the same or different alkyl group(s), substituted alkyl group(s) or a phenyl group, x ranges from about 1 to 3 and n ranges from about 300 to 1500, said polymers having molecular weights (number average) of 100,000 and higher.Preferred polymers are those arylenesiloxanylenecarbonate polymers which, when laminated to polycarbonate sheets or glass maintain their transparency, stability and adherence to said substrates at temperatures of up to and including 400.degree. F.
    Type: Grant
    Filed: January 27, 1982
    Date of Patent: May 3, 1983
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Harold Rosenberg, Tsu-tzu Tsai
  • Patent number: 4366323
    Abstract: This invention is directed to the preparation of certain arylene bis-silanols in highly purified form and to the preparation of five new arylene bis-silanols in particular, along with a procedure for polymerizing these and other arylene-type bis-silanols using phosgene as a polymerization promotor or catalyst, to obtain highly purified, high molecular weight arylene-siloxanylene polymers having the characteristic structure: ##STR1## where Y is an arylene or substituted arylene moiety; R and R' are the same or different alkyl group(s), substituted alkyl group(s) or a phenyl group, x ranges from about 1 to 3 and n ranges from about 300 to 1500; said polymers having molecular weights (number average) of 100,000 and higher.Preferred polymers are those arylenesiloxanylenecarbonate polymers which, when laminated to polycarbonate sheets or glass maintain their transparency, stability and adherence to said substrates at temperatures of up to and including 400.degree. F.
    Type: Grant
    Filed: January 27, 1982
    Date of Patent: December 28, 1982
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Harold Rosenberg, Tsu-tzu Tsai