Patents by Inventor Tsu-tzu Tsai
Tsu-tzu Tsai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5098987Abstract: There are provided crosslinkable, para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and R is an alkyl group having 1 to 4 carbon atoms. In polymers having two pendant R groups, the R groups can be the same or different.Type: GrantFiled: November 30, 1990Date of Patent: March 24, 1992Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 5098988Abstract: There are provided para-ordered aromatic heterocyclic copolymers having repeating groups of the following formulas: ##STR1## wherein a, b, c, d, and e are positive integers, each representing an average number of the respective different recurring units present in the repeating group, m and n are 1 or 2, R and R' are alkyl groups having 1 to 4 carbon atoms, and Q is a benzobisazole group of the formula: ##STR2## wherein Y is --O--, --S--, or --NH--. In the copolymers wherein m or n is 2, the R or R' groups can be the same or different. In copolymer I, the ratio a:b can be about 1:1 to 99:1. In copolymer II, the ratio c:(d+e) can be about 1:1 to 99:1, and the ratio d:e can be about 1:99 to 99:1.Type: GrantFiled: November 30, 1990Date of Patent: March 24, 1992Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 5003035Abstract: There are provided para-ordered aromatic heterocyclic copolymers having repeating groups of the following formulas: ##STR1## wherein a, b, c, d, and e are positive integers, each representing an average number of the respective different recurring units present in the repeating group, m and n are 1 or 2, R and R' are alkyl groups having 1 to 4 carbon atoms, and Q is a benzobisazole group of the formula: ##STR2## wherein Y is --O--, --S--, or --NH--. In the copolymers wherein m or n is 2, the R or R' groups can be the same or different. In copolymer I, the ratio a:b can be about 1:1 to 99:1. In copolymer II, the ratio c:(d+e) can be about 1:1 to 99:1, and the ratio d:e can be aobut 1:99 to 99:1.Type: GrantFiled: July 13, 1989Date of Patent: March 26, 1991Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 5001217Abstract: There are provided crosslinkable, para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and R is an alkyl group having 1 to 4 carbon atoms. In polymers having two pendant R groups, the R groups can be the same or different.Type: GrantFiled: July 13, 1989Date of Patent: March 19, 1991Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4892921Abstract: Provided are novel para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and Q is ##STR2## wherein Z is --O-- or --S--. There are also provided methods for preparing the above polymers.Type: GrantFiled: February 21, 1989Date of Patent: January 9, 1990Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4835246Abstract: Provided are novel para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and Q is ##STR2## wherein Z is --O-- or --S--. There are also provided methods for preparing the above polymers.Type: GrantFiled: August 13, 1987Date of Patent: May 30, 1989Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4785115Abstract: Provided are benzazole-substituted terephthalic acids of the formula ##STR1## wherein n is 1 or 2 and Q is ##STR2## wherein Z is --O-- or --S--. Also provided are methods for preparing the benzazole substituted terephthalic acid compounds.Type: GrantFiled: August 13, 1987Date of Patent: November 15, 1988Assignee: The United States of America as represented by the Secretary of the United StatesInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4762908Abstract: A polymer having repeating units of the general formula ##STR1## wherein BB is a benzobisaxazole, benzobisthiazole or benzobisimidazole group and Y is a phenolic, pyridyl or phenoxyphenyl group.Type: GrantFiled: April 7, 1987Date of Patent: August 9, 1988Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4723013Abstract: Certain 4,8-disubstituted-2,6-naphthalene dicarboxylic acid monomers and a method for their preparation. These monomers are useful for the preparation of polymers, which polymers may be used to prepare high strength fibers.Type: GrantFiled: April 7, 1987Date of Patent: February 2, 1988Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4709006Abstract: A polymer having repeating units of the general formula ##STR1## wherein BB is a benzobisaxazole, benzobisthiazole or benzobisimidazole group and Y is a phenolic, pyridyl or phenoxyphenyl group.Type: GrantFiled: April 16, 1986Date of Patent: November 24, 1987Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4578432Abstract: Thermally stable aromatic heterocyclic block copolymers are prepared by reacting a diamino monomer and terephthalic acid to form a carboxy-terminated rigid rod segment and then polymerizing a carboxy-monoamine monomer therewith to form flexible segments grafted onto the rigid rod segments.Type: GrantFiled: April 11, 1985Date of Patent: March 25, 1986Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4578434Abstract: Thermally stable aromatic heterocyclic block copolymers are prepared by reacting a diamino monomer and terephthalic acid to form a carboxy-terminated rigid rod segment and then polymerizing a carboxy-monoamine monomer therewith to form flexible segments grafted onto the rigid rod segments.Type: GrantFiled: April 11, 1985Date of Patent: March 25, 1986Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4578435Abstract: Thermally stable aromatic heterocyclic block copolymers are prepared by reacting a diamino monomer and terephthalic acid to form a carboxy-terminated rigid rod segment and then polymerizing a carboxy-monoamine monomer therewith to form flexible segments grafted onto the rigid rod segments.Type: GrantFiled: April 11, 1985Date of Patent: March 25, 1986Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4559404Abstract: Mono -and di-acetylenic-substituted 2-phenylbenzothiazoles are prepared by reacting the corresponding mono- or di-halogen-substituted 2-phenylbenzothiazole with an alkyne, such as 2-methyl-3-butyne-2-ol in the presence of a suitable catalyst.Type: GrantFiled: December 28, 1983Date of Patent: December 17, 1985Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4544713Abstract: Thermally stable aromatic heterocyclic block copolymers are prepared by reacting a diamino monomer and terephthalic acid to form a carboxy-terminated rigid rod segment and then polymerizing a carboxy-monoamine monomer therewith to form flexible segments grafted onto the rigid rod segments.Type: GrantFiled: May 16, 1984Date of Patent: October 1, 1985Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4518759Abstract: This invention is directed to the preparation of certain arylene bis-silanols in highly purified form and to the preparation of five new arylene bis-silanols in particular, along with a procedure for polymerizing these and other arylene-type bis-silanols using phosgene as a polymerization promotor or catalyst, to obtain highly purified, high molecular weight arylenesiloxanylene polymers having the characteristic structure: ##STR1## where Y is an arylene or substituted arylene moiety: R and R' are the same or different alkyl group(s), substituted alkyl group(s) or a phenyl group, X ranges from about 1 to 3 and n ranges from about 300 to 1500, said polymers having molecular weights (number average) of 100,000 and higher.Preferred polymers are those arylenesiloxanylenecarbonate polymers which, when laminated to polycarbonate sheets or glass maintain their transparency, stability and adherence to said substrates at temperatures of up to and including 400.degree. F.Type: GrantFiled: January 27, 1982Date of Patent: May 21, 1985Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Harold Rosenberg, Tsu-tzu Tsai
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Patent number: 4442293Abstract: Mono- and di-acetylenic-substituted 2-phenylbenzothiazoles are prepared by reacting the corresponding mono- or di-halogen-substituted 2-phenylbenzothiazole with an alkyne, such as 2-methyl-3-butyne-2-ol in the presence of a suitable catalyst.Type: GrantFiled: March 9, 1982Date of Patent: April 10, 1984Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4436886Abstract: Mono- and di-acetylenic-substituted 2-phenylbenzothiazoles are thermally self-polymerized to form thermally stable polymers. The polymers are useful as laminating resins for fibrous composites, particularly for high temperature applications.Type: GrantFiled: February 2, 1983Date of Patent: March 13, 1984Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tsu-Tzu Tsai, Fred E. Arnold
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Patent number: 4382144Abstract: This invention is directed to the preparation of certain arylene bis-silanols in highly purified form and to the preparation of five new arylene bis-silanols in particular, along with a procedure for polymerizing these and other arylene-type bis-silanols using phosgene as a polymerization promotor or catalyst, to obtain highly purified, high molecular weight arylene-siloxanylene polymers having the characteristic structure: ##STR1## where Y is an arylene or substituted arylene moiety; R and R' are the same or different alkyl group(s), substituted alkyl group(s) or a phenyl group, x ranges from about 1 to 3 and n ranges from about 300 to 1500, said polymers having molecular weights (number average) of 100,000 and higher.Preferred polymers are those arylenesiloxanylenecarbonate polymers which, when laminated to polycarbonate sheets or glass maintain their transparency, stability and adherence to said substrates at temperatures of up to and including 400.degree. F.Type: GrantFiled: January 27, 1982Date of Patent: May 3, 1983Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Harold Rosenberg, Tsu-tzu Tsai
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Patent number: 4366323Abstract: This invention is directed to the preparation of certain arylene bis-silanols in highly purified form and to the preparation of five new arylene bis-silanols in particular, along with a procedure for polymerizing these and other arylene-type bis-silanols using phosgene as a polymerization promotor or catalyst, to obtain highly purified, high molecular weight arylene-siloxanylene polymers having the characteristic structure: ##STR1## where Y is an arylene or substituted arylene moiety; R and R' are the same or different alkyl group(s), substituted alkyl group(s) or a phenyl group, x ranges from about 1 to 3 and n ranges from about 300 to 1500; said polymers having molecular weights (number average) of 100,000 and higher.Preferred polymers are those arylenesiloxanylenecarbonate polymers which, when laminated to polycarbonate sheets or glass maintain their transparency, stability and adherence to said substrates at temperatures of up to and including 400.degree. F.Type: GrantFiled: January 27, 1982Date of Patent: December 28, 1982Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Harold Rosenberg, Tsu-tzu Tsai