Patents by Inventor Tsuguo Koyanagi

Tsuguo Koyanagi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6864415
    Abstract: A photoelectric cell that includes a first insulating base, having on its surface a first electrode layer, which has on its surface a metal oxide semiconductor film, which includes anatase titanium oxide particles, on which a photosensitizer is absorbed and a second insulating base having on its surface a second electrode layer and an electrolyte sealed between the metal oxide semiconductor film and the second electrode layer. The first electrode layer and the second electrode layer are arranged opposite from each other. At least one of the first and second insulating bases with an electrode layer is transparent.
    Type: Grant
    Filed: February 6, 2003
    Date of Patent: March 8, 2005
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Tsuguo Koyanagi, Michio Komatsu, Hirokazu Tanaka, Katsuhiro Shirono
  • Publication number: 20050031924
    Abstract: The electrolyte membrane according to the present invention comprises inorganic oxide particles having proton conductivity, and an organic resin or an inorganic matrix component. The inorganic oxide particles having proton conductivity preferably comprise hydrated antimony oxide particles represented by the following formula (1) and have an average particle diameter of 5 to 50 nm, and the content of the hydrated antimony oxide particles is preferably in the range of 5 to 80% by weight in terms of an oxide (Sb2O5); Sb2O5.nH2O??(1) wherein n is 0.1 to 5. By the use of the electrolyte membrane of the present invention, a fuel cell exhibiting high cell performance even in a prolonged operation and/or an operation at high temperature can be obtained.
    Type: Application
    Filed: November 8, 2002
    Publication date: February 10, 2005
    Inventors: Katsuhiro Shirono, Tsuguo Koyanagi, Michio Komatsu
  • Patent number: 6849797
    Abstract: A photovoltaic cell includes a first substrate having on its surface a first electrode layer having on its surface a semiconductor film on which a photosensitizer is adsorbed, and a second substrate having on its surface a second electrode layer. The first and second substrates are arranged so that the first electrode layer overlaid with the semiconductor film and the second electrode layer are opposite each other with an electrolyte disposed therebetween. Spacer particles are interposed between the semiconductor film and the second electrode layer, and at least one of the electrode-layer-having substrates is transparent. A coating liquid for forming the semiconductor film includes both a component for forming the semiconductor film as well as the spacer particles, dispersed in a dispersion medium.
    Type: Grant
    Filed: April 24, 2003
    Date of Patent: February 1, 2005
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Tsuguo Koyanagi, Michio Komatsu
  • Publication number: 20040265587
    Abstract: The process for preparing tubular titanium oxide particles comprises subjecting a water dispersion sol, which is obtained by dispersing (i) titanium oxide particles and/or (ii) titanium oxide type composite oxide particles comprising titanium oxide and an oxide other than titanium oxide in water, said particles having an average particle diameter of 2 to 100 nm, to hydrothermal treatment in the presence of an alkali metal hydroxide. After the hydrothermal treatment, reduction treatment (including nitriding treatment) may be carried out. The tubular titanium oxide particles obtained in this process are useful as catalysts, catalyst carriers, adsorbents, photocatalysts, decorative materials, optical materials and photoelectric conversion materials. Especially when the particles are used for semiconductor films for photovoltaic cells or photocatalysts, prominently excellent effects are exhibited.
    Type: Application
    Filed: April 29, 2004
    Publication date: December 30, 2004
    Inventors: Tsuguo Koyanagi, Katsuhiro Shirono, Atsushi Tanaka, Michio Komatsu
  • Publication number: 20030201010
    Abstract: A photovoltaic cell includes a first substrate having on its surface a first electrode layer having on its surface a semiconductor film on which a photosensitizer is adsorbed, and a second substrate having on its surface a second electrode layer. The first and second substrates are arranged so that the first electrode layer overlaid with the semiconductor film and the second electrode layer are opposite each other with an electrolyte disposed therebetween. Spacer particles are interposed between the semiconductor film and the second electrode layer, and at least one of the electrode-layer-having substrates is transparent. A coating liquid for forming the semiconductor film includes both a component for forming the semiconductor film as well as the spacer particles, dispersed in a dispersion medium.
    Type: Application
    Filed: April 24, 2003
    Publication date: October 30, 2003
    Applicant: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Tsuguo Koyanagi, Michio Komatsu
  • Publication number: 20030196692
    Abstract: Disclosed is a photovoltaic cell comprising a substrate having an electrode layer (1) on the surface and having a porous metal oxide semiconductor film (2) which is formed on the electrode layer (1) and on which a photosensitizer is adsorbed, a substrate having an electrode layer (3) on the surface, both of said substrates being arranged in such a manner that the electrode layer (1) and the electrode layer (3) face each other, and an electrolyte layer provided between the semiconductor film (2) and the electrode layer (3), wherein the semiconductor film (2) contains an inhibitor of back current, and at least one pair of substrate and electrode layer thereon have transparency. The photovoltaic cell is capable of inhibiting back current and decomposition of a spectrosensitizing dye caused by the ultraviolet rays, has high photoelectric conversion efficiency and is capable of generating high electromotive force.
    Type: Application
    Filed: April 17, 2003
    Publication date: October 23, 2003
    Applicant: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD.
    Inventors: Tsuguo Koyanagi, Michael Graetzel
  • Publication number: 20030193037
    Abstract: The inorganic compound sol of the present invention comprises a dispersion medium and, dispersed therein, inorganic compound particulates whose surface has been modified by an organic compound exhibiting a molecular polarizability of from 2×10−40 to 850×10−40 C2m2J−1. This inorganic compound sol modified by an organic compound has desirable affinity with dispersion media, so that its dispersion stability in solvents is excellent without aggregation of particulates.
    Type: Application
    Filed: March 11, 1998
    Publication date: October 16, 2003
    Inventors: TSUGUO KOYANAGI, HIROYASU NISHIDA
  • Publication number: 20030157272
    Abstract: There is provided a process for producing an integrated circuit, wherein not only can conductive fine particles be deposited efficiently and densely in minute wiring channels and connecting holes but also a circuit of low wiring resistance and high density can be formed and wherein a high-degree integration can be achieved to thereby bring about an economic advantage. In particular, there is provided a process for producing an integrated circuit, comprising coating a substrate provided with wiring channels with a coating liquid for integrated circuit formation containing conductive fine particles to thereby form an integrated circuit on the substrate, wherein the coating liquid for integrated circuit formation while being exposed to ultrasonic waves is applied to the wiring channels.
    Type: Application
    Filed: November 1, 2002
    Publication date: August 21, 2003
    Inventors: Atsushi Tonai, Toshiharu Hirai, Tsuguo Koyanagi, Masayuki Matsuda, Michio Komatsu
  • Publication number: 20030150485
    Abstract: The first photoelectric cell of the present invention comprises: an insulating base having on its surface an electrode layer (1), the electrode layer (1) having on its surface a metal oxide semiconductor film (2) on which a photosensitizer is adsorbed; an insulating base having on its surface an electrode layer (3), the electrode layer (1) and the electrode layer (3) arranged opposite to each other; and an electrolyte sealed between the metal oxide semiconductor film (2) and the electrode layer (3), wherein at least one of the electrode-having insulating bases is transparent; and the metal oxide semiconductor film (2) comprises anatase titanium oxide particles. This first photoelectric cell includes a semiconductor film comprising anatase titanium oxide particles, having a high proportion of photosensitizer adsorbed, so that the electron mobility in the semiconductor film is high to thereby realize excellent photoelectric transfer efficiency.
    Type: Application
    Filed: February 6, 2003
    Publication date: August 14, 2003
    Applicant: Catalysts & Chemicals Industries Co., LTD.
    Inventors: Tsuguo Koyanagi, Michio Komatsu, Hirokazu Tanaka, Katsuhiro Shirono
  • Patent number: 6586104
    Abstract: A coating liquid for forming a transparent coating comprising fine particles of an inorganic compound and a hydrolyzate of an organosilicon compound represented by the general formula (I): RnSi(OR′)4−n  (I) wherein R and R′ represent organic groups which may be identical to each other or different from each other, and n is an integer of 1 to 3. This coating liquid ensures excellent substrate wettability and compatibility with various organic solvents so that the printability and applicability thereof are desirable, with the result that a transparent coating film of high uniformity, for example, a flattening coating film, can be formed. The present invention comprises a substrate having a transparent coating film formed on the substrate surface from the above coating liquid.
    Type: Grant
    Filed: February 23, 1998
    Date of Patent: July 1, 2003
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Masayuki Matsuda, Nobuaki Yoshida, Tsuguo Koyanagi, Michio Komatsu
  • Patent number: 6580026
    Abstract: A photovoltaic cell including a first substrate having on its surface a first electrode layer having on its surface a semiconductor film on which a photosensitizer is adsorbed, and a second substrate having on its surface a second electrode layer. The first and second substrates are arranged so that the first electrode layer overlaid with the semiconductor film and the second layer are opposite each other with an electrolyte layer disposed therebetween. The electrolyte layer includes an electrolyte and a liquid crystal and at least one of the electrode-layer-having substrates is transparent.
    Type: Grant
    Filed: February 28, 2001
    Date of Patent: June 17, 2003
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Tsuguo Koyanagi, Michio Komatsu
  • Patent number: 6538194
    Abstract: A photoelectric cell that includes a first insulating base, having on its surface a first electrode layer, which has on its surface a metal oxide semiconductor film, which includes anatase titanium oxide particles, on which a photosensitizer is adsorbed and a second insulating base having on its surface a second electrode layer and an electrolyte sealed between the metal oxide semiconductor film and the second electrode layer. The first electrode layer and the second electrode layer are arranged opposite from each other. At least one of the first and second insulating bases with an electrode layer is transparent.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: March 25, 2003
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Tsuguo Koyanagi, Michio Komatsu, Hirokazu Tanaka, Katsuhiro Shirono
  • Patent number: 6359667
    Abstract: An organopolysiloxane fine particle comprising as a principal component a polysiloxane having a hydrocarbon group (a) directly bonded to a silicon atom and having an OH group (b) directly bonded to a silicon atom, wherein: (i) carbons contained in the hydrocarbon group (a) constitute 5 to 35% of the weight of the organopolysiloxane fine particles, and (ii) the OH group (b) is in an amount of 1 to 8 meq per g of the organopolysiloxane fine particles, the organopolysiloxane fine particles having: (iii) a 10% compressive modulus of elasticity of 150 to 900 Kg/mm2, (iv) an average compressive deformation (Cr)m of 20 to 60%, (v) an average elastic recovery (Rr)m of 60 to 90%, and (vi) an average particle diameter of 0.5 to 50 &mgr;m.
    Type: Grant
    Filed: August 8, 2000
    Date of Patent: March 19, 2002
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Tsuguo Koyanagi, Michio Komatsu, Kazuhiro Nakayama
  • Publication number: 20020011182
    Abstract: A coating liquid for forming a transparent coating, comprising fine particles of an inorganic compound, and a hydrolyzate of an organosilicon compound represented by the general formula (I):
    Type: Application
    Filed: February 23, 1998
    Publication date: January 31, 2002
    Inventors: MASAYUKI MATSUDA, NOBUAKI YOSHIDA, TSUGUO KOYANAGI, MICHIO KOMATSU
  • Patent number: 6294230
    Abstract: The present invention relates to spherical laminated particles each comprising a core particle and a laminate part disposed on a surface of the core particle, wherein the laminate part has a compressive modulus which is smaller than that of the core particle. These spherical laminated particles have a large compressive strength and is excellent in the recovery from a deformation by an arbitrary load, when the load is removed afterwward, as compared with conventional elastic particles composed of a single substance. Therefore, the use of these spherical laminated particles as spacers minimizes the difference in extent of displacement of spacer particles attributed to the difference in load on individual spacer particles caused by, for example, the waviness of a substrate for liquid crystal display cell during the manufacturing of the liquid crystal display cell, so that the cell gap uniformity can be ensured.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: September 25, 2001
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Tsuguo Koyanagi, Kazuhiro Nakayama, Yutaka Mitsuo, Mitsuru Nakai, Michio Komatsu
  • Patent number: 5204177
    Abstract: Transparent conductive coatings excellent in transparency are provided on substrates such as glass, plastics, etc. by the use of conductive coating materials obtained by maintaining aqueous solutions of hydrolyzable tin containing or indium containing compounds at pH of 8-12, and gradually hydrolyzing said compounds in the solutions to form sols containing colloidal particles, followed by drying and calcining.
    Type: Grant
    Filed: August 27, 1991
    Date of Patent: April 20, 1993
    Assignee: Catalysts & Chemicals Industries, Co., Ltd.
    Inventors: Goro Sato, Michio Komatsu, Tsuguo Koyanagi, Masayuki Matsuda, Hiroo Yoshidome, Akira Nakashima, Kazuaki Inoue
  • Patent number: 4987012
    Abstract: In a process for preparing spherical particles of hydroxide having a particle diameter of from 0.1 to 10 .mu.m by adding a corresponding metal alkoxide to a dispersion of water-alcohol system having dispersed therein a metal oxide or hydroxide as a seed, under alkaline conditions and allowing a decomposition product from said metal alkoxide to attach onto said seed to effect particle growth of the seed, the improvement which comprises maintaining said dispersion at a substantially constant pH within the range between 10 and 13 during the addition of the metal alkoxide to said dispersion and the subsequent particle growth of the seed, thereby to prepare mono-dispersed particles substantially free from particle aggregation having a sharp particle size distribution of a standard deviation of not greater than 0.5. The white particles so prepared may be, after separation, heat treated to provide black particles. The white or black particles may be coated with a synthetic resin in the surface.
    Type: Grant
    Filed: April 18, 1990
    Date of Patent: January 22, 1991
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Goro Sato, Michio Komatsu, Hiroyasu Nishida, Yoshichika Tanaka, Tsuguo Koyanagi, Kei-ichi Mihara
  • Patent number: 4937148
    Abstract: Transparent conductive coatings excellent in transparency are provided on substrates such as glass, plastics, etc. by the use of conductive coating materials obtained by maintaining aqueous solutions of hydrolyzable tin containing or indium containing compounds at pH of 8-12, and gradually hydrolyzing said compounds in the solutions to form sols containing colloidal particles, followed by drying and calcining.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: June 26, 1990
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Goro Sato, Michio Komatsu, Tsuguo Koyanagi, Masayuki Matsuda, Hiroo Yoshidome, Akira Nakashima, Kazuaki Inoue
  • Patent number: 4925704
    Abstract: In a process for preparing spherical particles of a metal oxide or hydroxide having a particle size of from 0.1 to 10 .mu.m by adding a corresponding metal alkoxide to a dispersion of water-alcohol system having dispersed therein a metal oxide or hydroxide as a seed, under alkaline conditions and allowing a decomposition product from said metal alkoxide to attach onto said seed to effect particle growth of the seed, the improvement which comprises maintaining said dispersion at a substantially constant pH within the range between 10 and 13 during the addition of the metal alkoxide to said dispersion and the subsequent particle growth of the seed, thereby to prepare mono-dispersed particles substantially free from particle aggregation having a sharp particle size distribution of a standard deviation of not greater than 0.5. The white particles so prepared may be, after separation, heat treated to provide black particles. The white or black particles may be coated with a synthetic resin in the surface.
    Type: Grant
    Filed: June 13, 1988
    Date of Patent: May 15, 1990
    Assignee: Catalsts & Chemicals Industries Co., Ltd.
    Inventors: Goro Sato, Michio Komatsu, Hiroyasu Nishida, Yoshichika Tanaka, Tsuguo Koyanagi, Kei Mihara
  • Patent number: 4568609
    Abstract: The material obtained by coating a small plate substrate with a metal oxide doped with different metals is light permeable as well as conductive, wherein said plate substrate is selected from mica, illite, bravaisite, kaolinite, bentonite, montmorillonite, smectites, calcium phosphate and glass particle and its ratio of major axis to minor axis is 1-30 and its ratio of minor axis to thickness is 5 or more. This material is useful as the additive for providing a transparent film with conductivity.
    Type: Grant
    Filed: August 28, 1984
    Date of Patent: February 4, 1986
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Goro Sato, Michio Komatsu, Tsuguo Koyanagi, Hirokazu Tanaka