Abstract: The present invention can provide a method for producing an aromatic nitrile in which a fixed-bed reactor including a plurality of reaction tubes is used to subject a gaseous mixture comprising an aromatic hydrocarbon, ammonia, and oxygen by contact catalytic reaction on a catalyst to thereby produce the corresponding aromatic nitrile, wherein the catalyst is composed of an oxide containing vanadium, chromium, and boron and one or more supports selected from among alumina, silica-alumina, zirconia, and titania. One of the reaction tubes is filled with the catalyst of one kind and examined as to where a hot spot lies therein. An inert substance is filled into that portion of each of the plurality of reaction tubes which corresponds at least to the hot spot, and the catalyst is filled into the remaining portions.

Abstract: The present invention can provide a method for producing an aromatic nitrile in which a fixed-bed reactor including a plurality of reaction tubes is used to subject a gaseous mixture comprising an aromatic hydrocarbon, ammonia, and oxygen by contact catalytic reaction on a catalyst to thereby produce the corresponding aromatic nitrile, wherein the catalyst is composed of an oxide containing vanadium, chromium, and boron and one or more supports selected from among alumina, silica-alumina, zirconia, and titania. One of the reaction tubes is filled with the catalyst of one kind and examined as to where a hot spot lies therein. An inert substance is filled into that portion of each of the plurality of reaction tubes which corresponds at least to the hot spot, and the catalyst is filled into the remaining portions.

Abstract: To provide a steel wire rod having a lubricating coating, which can achieve both corrosion resistance such as long-term rust prevention property, and excellent appearance after heading. The steel wire rod of the present disclosure includes a lubricating coating on a surface thereof, wherein the lubricating coating includes silicon (A), tungsten (B) and an alkali metal salt of fatty acid (C), a dry mass ratio of (B)/(A) is in a range of 1.3 to 18 and a dry mass ratio of (C)/{(A)+(B)} is in a range of 0.14 to 2.0, and the lubricating coating contains no phosphorus.

Abstract: The present invention provides a steel wire rod having a lubricating coating film, which can achieve both workabilities such as wire drawability, spike property and ball ironing property, and corrosion resistance such as long-term rust prevention property; and a method for producing the same. Disclosed are a steel wire rod having a coating film containing no phosphorus, wherein the coating film includes a lower layer coating film composed of oxide and/or hydroxide of zirconium and having a film thickness of 1.0 to 200 nm, and an upper layer coating film containing silicon and tungsten, in order from a steel wire rod side, a mass ratio of tungsten/silicon being in a range of 1.3 to 18; and a method for producing the above steel wire rod, which includes bringing an aqueous chemical conversion treatment solution, which has a pH in a range of 2.5 to 5.0 and contains a water-soluble zirconium compound dissolved therein, into contact with a surface of a steel wire rod to form a lower layer coating film.

Abstract: The present invention provides a steel wire rod including a lubricating coating film, which can reconcile workabilities such as wire drawability, spike property, ball ironing property and film removability, and corrosion resistance such as long-term rust prevention property. The steel wire rod includes a lubricating coating film on a surface, wherein the lubricating coating film contains a water-soluble silicate and a water-soluble tungstate, a mass ratio of water-soluble tungstate/water-soluble silicate being in a range of 0.

Abstract: A water-based lubricating coating agent includes a water-soluble silicate (A) and at least one water-soluble inorganic salt (B) selected from a tungstate, a phosphate and a borate, wherein the water-soluble silicate (A) and the at least one water-soluble inorganic salt (B) are blended such that a solid content mass ratio (B)/(A) falls within a range of 0.7 to 25.

Abstract: In the production of an alkylbenzaldehyde by a method comprising a step of preparing a solution of complex of a starting alkylbenzene and a hydrogen fluoride-boron trifluoride catalyst and a step of formylation by bringing the solution of complex into contact with carbon monoxide, an alkylbenzene having at least one primary alkyl group having two or more carbon atoms on its benzene ring is used as the starting alkylbenzene. The preparation of the solution of complex is carried out in the presence of an aliphatic or alicyclic saturated hydrocarbon having 6 to 10 carbon atoms which contains at least one tertiary carbon atom but contains no quaternary carbon atom. By the combined use of the specific alkylbenzene and the aliphatic or alicyclic saturated hydrocarbon, the disproportionation of the alkylbenzene is prevented and the alkylbenzaldehyde is produced at high yields.

Abstract: In the production of an alkylbenzaldehyde by a method comprising a step of preparing a solution of complex of a starting alkylbenzene and a hydrogen fluoride-boron trifluoride catalyst and a step of formylation by bringing the solution of complex into contact with carbon monoxide, an alkylbenzene having at least one primary alkyl group having two or more carbon atoms on its benzene ring is used as the starting alkylbenzene. The preparation of the solution of complex is carried out in the presence of an aliphatic or alicyclic saturated hydrocarbon having 6 to 10 carbon atoms which contains at least one tertiary carbon atom but contains no quaternary carbon atom. By the combined use of the specific alkylbenzene and the aliphatic or alicyclic saturated hydrocarbon, the disproportionation of the alkylbenzene is prevented and the alkylbenzaldehyde is produced at high yields.

Abstract: In the process of the present invention, a polyalkyl-substituted aromatic aldehyde is produced by the formylation of a corresponding polyalkyl-substituted aromatic compound with carbon monoxide in the presence of hydrogen fluoride/boron trifluoride catalyst. By limiting the amount of hydrogen fluoride to a specific range, the formylation rapidly proceeds under mild conditions without causing the precipitation of solid matters even when the starting polyalkyl-substituted aromatic compound has alkyl groups on both the carbon atoms adjacent to the site to be formylated.

Abstract: In the process of the present invention, a polyalkyl-substituted aromatic aldehyde is produced by the formylation of a corresponding polyalkyl-substituted aromatic compound with carbon monoxide in the presence of hydrogen fluoride/boron trifluoride catalyst. By limiting the amount of hydrogen fluoride to a specific range, the formylation rapidly proceeds under mild conditions without causing the precipitation of solid matters even when the starting polyalkyl-substituted aromatic compound has alkyl groups on both the carbon atoms adjacent to the site to be formylated.