Abstract: A protective device for a container containing toxic or hazardous materia includes a shell, a mechanism positioned in the shell for sealing a puncture in the container so as to prevent release of the toxic materials from the container and a mechanism for attaching the shell to the container.

Abstract: The present invention relates to acoustic and vibration attenuation compoe material, particularly to damping tiles of the Type VI class 1, suitable for use in aircraft, ship and submarine applications, that is inexpensive, does not result in an unacceptable weight penalty, and is conformable-in-place to complex curvatures. The present acoustic and vibration attenuation composite comprises a constraining layer of at least one ply of graphite fabric together with curable phenolic resin bonded to a viscoelastic layer.

Abstract: Improved acoustic damping materials comprise interpenetrating polymer netks having a soft polymer component and a hard polymer component. The soft polymer component, constituting from 50 to 90 percent by weight of the material, is a polyurethane made by polymerization of a diisocyanate with a polyether glycol, and the hard polymer component is made by polymerization of bisphenol A diglycidyl ether, with boron trichloride amine complex as a curing agent.

Abstract: Improved acoustic damping materials comprise interpenetrating polymer netks having a soft polymer component and a hard polymer component. The soft polymer component, constituting from 50 to 90 percent by weight of the material, is made by polymerizing an aromatic diisocyanate with a polyalkylene ether glycol, and the hard polymer component is an acrylic polymer made by polymerization of the alkyl esters and alkylene diesters of acrylic and/or methacrylic acid, e.g. n-butyl methacrylate and tetramethylene glycol dimethacrylate. The curing of the mixture is carried out at room temperature.

Abstract: A fire protective coating and method for applying same to a composite strure are provided. The coating is a composition of matter comprising a phenolic resin and strength reinforcing fibers embedded within the phenolic resin. The method of coating the structure with the composition of matter uses a phenolic resin in the liquid state. In this way, a mixture of the phenolic resin and strength reinforcing fibers can be applied to the structure's surface by conventional spraying techniques. As the mixture on the surface cures, a fire protective coating is formed on the structure's surface.

Abstract: A process is described for forming a duplex coating as a fire barrier on a omposite structure comprising organic matrices so that the structure shows reduced flammability, less smoke, higher ignition resistance, and more residual flexural strength after exposure to fire. A thin layer of a metal such as zinc is arc wire sprayed onto a surface of the structure to form a bonding and heat-diffusing coating, and a stabilized zirconia coating is then plasma sprayed onto the metal coating to form a thermal barrier coating.

Abstract: A fireproof barrier system for a composite structure is provided. A sheet ablative material is bonded onto the composite structure to be fireproofed. A protective phenolic resin skin is deposited on the sheet to protect the ablative material from handling and water damage while further improving the fire performance of the system. The protective skin may have between about 50 to 80 parts per hundred of aluminum trihydrate mixed therein. The protective phenolic resin skin may further be glass-reinforced.

Abstract: Improved acoustic damping materials comprise interpenetrating polymer netks having a soft polymer component and a hard polymer component. The soft polymer component, constituting from 75 to 95, preferably 90, percent by weight of the material, is made by polymerizing an aromatic diisocyanate with a polyalkylene ether glycol, and the hard polymer component is a vinyl ester polymer made by polymerization of the acrylate or methacrylate ester of the diglycidyl ether of a polyphenol. The curing of the mixture is carried out at room temperature in presence of a peroxide and an aromatic amine. The mixture of ingredients, while liquid, may be injected into mechanical devices, such as shafts of rotating equipment whose noise is to be dampened, and allowed to cure therein.

Abstract: Improved acoustic damping materials comprise interpenetrating polymer netks having a soft polymer component and a hard polymer component. The soft polymer component, constituting from 50 to 90, preferably 70, percent by weight of the material, is made by polymerizing an aromatic diisocyanate with a polyalkylene ether glycol, and the hard polymer component is a vinyl ester polymer made by polymerization of a vinyl ester resin such as the acrylate or methacrylate ester of the diglycidyl ether of a polyphenol. Optionally, the vinyl ester resin may be brominated, whereby increased fire retardance is conferred upon the interpenetrating polymer network. The mixture is cured at room temperature.

Abstract: A method of protecting acoustic and damping tiles from fire damage by placing a fire barrier silicone foam sheet on the inner surface of a mold, mounting the mold at a selected distance from the surface of a hull of a vessel with the fiberglass cloth side of the silicone foam sheet facing the hull and spaced therefrom, injecting a polyurethane foam into the space between the hull surface and the silicone foam sheet, curing the polyurethane foam, and removing the mold. The porosity of the polyurethane foam is imparted by incorporation of 5-50% by volume of Saran.RTM. microspheres.