Abstract: A polymer foam composition includes: from about 5 wt. % to about 84 wt. % of a polymer base resin; from about 15 wt. % to about 70 wt. % of a thermally conductive filler having an aspect ratio greater than 1:1; from about 0.01 to about 5 wt. % of a nanostructured fluoropolymer; and from about 0.01 wt. % to about 2 wt. % of a foaming agent. The polymer foam composition is formed from a core-back process and exhibits a thermal conductivity of at least 1.5 W/mK when tested in accordance with ISO 22007-2. Articles including the polymer foam composition are further described; in one aspect the article is a heat exchanger. Methods of forming the polymer foam composition are also described.

Abstract: Provided are extrusion dies having entrance, orientation, merging (205), and exit (211) sections, which dies may be used to produce fibers having, e.g., oriented reinforcement materials (e.g., PTFE) dispersed within. The dies provide fibers having enhanced mechanical and processing properties. The orientation section comprises orientation channels (203) wherein a ratio of a cross-sectional area having of the channel inlet to a cross-sectional area of the channel outlet is between 2 and 45.

Abstract: A foamed polymer composition includes a matrix polymer component, and from 0.01 wt % to 2 wt %, based on the weight of the polymer composition, of a nanostructured fluoropolymer, a nanostructured fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. The matrix polymer component includes polybutylene terephthalate (PBT), polyetherimide (PEI), polyethylene terephthalate (PET), polycarbonate (PC), poly(p-phenylene oxide) (PPO), polystyrene (PS), polyphenylene sulfide (PPS), polypropylene (PP), polyamide (PA), polytrimethylene terephthalate (PTT), polyethylene naphthalate (PEN), polybutylene naphthalate (PBN), copolymers thereof, or a combination thereof. Methods for forming foamed polymer compositions, including core-back molding methods and extrusion foaming methods, are also described.

Abstract: A method for forming foamed beads includes: saturating pellets with a blowing agent to form saturated pellets; and depressurizing the saturated pellets in a pressure vessel to form the foamed beads. The pellets include: a matrix polymer component, and from 0.01 wt% to 2 wt%, based on the weight of the pellets, of a nanostructured fluoropolymer, a nanostructured fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof.

Abstract: The disclosure is directed to polymer compositions comprising a matrix polymer component comprising a crystalline or semi-crystalline polymer; and a fibrillated fluoropolymer, a fibrillated fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. Methods of preparing and using these polymer compositions, as well as articles comprising the polymer compositions, as also described.

Abstract: A copolycarbonate optical article comprises a polycarbonate composition including: a copolycarbonate having: 2 to 60 mol % of phthalimidine carbonate units, 2 to 90 mol % of high heat carbonate units, and optionally 2 to 60 mol % of bisphenol A carbonate units. The copolycarbonate has less than 100 ppm of each of phthalimidine, high heat bisphenol, and bisphenol A monomers, and less than 5 ppm of various ions, and is prepared from monomers each having a purity of at least 99.6%. The polycarbonate composition has a glass transition temperature of 200° C. to and a yellowness index of less than 30.

Abstract: In an embodiment, a composition comprises a poly(ester-carbonate-siloxane) copolymer; a nanosilica; a plurality of polysiloxane particles; and a fluoropolymer. The nanosilica can be present in an amount of 1 to 5 wt % based on a total weight of the composition. The nanosilica can have a D50 particle size by volume of 5 to 50 nanometers. The nanosilica can have a hydrophobic coating. The plurality of polysiloxane particles can be present in an amount of 1 to 10 wt % based on a total weight of the composition. The plurality of polysiloxane particles can have a D50 particle size by volume of 0.1 to 10 micrometers. The fluoropolymer can be present in an amount of 0.005 to 5 wt % based on a total weight of the composition.

Abstract: Provided are particulate compositions that include a matrix polymer and fibrillated reinforcement materials (e.g., PTFE or ultra-high molecular weight polyethylene fibrils) dispersed therein. The compositions are suitable for use in additive manufacturing processes.

Abstract: In an embodiment, a composition comprises a poly(ester-carbonate-siloxane) copolymer; a nanosilica; a plurality of polysiloxane particles; and a fluoropolymer. The nanosilica can be present in an amount of 1 to 5 wt % based on a total weight of the composition. The nanosilica can have a D50 particle size by volume of 5 to 50 nanometers. The nanosilica can have a hydrophobic coating. The plurality of polysiloxane particles can be present in an amount of 1 to 10 wt % based on a total weight of the composition. The plurality of polysiloxane particles can have a D50 particle size by volume of 0.1 to 10 micrometers. The fluoropolymer can be present in an amount of 0.005 to 5 wt % based on a total weight of the composition.

Abstract: Provided are extrusion dies having entrance, orientation, merging (205), and exit (211) sections, which dies may be used to produce fibers having, e.g., oriented reinforcement materials (e.g., PTFE) dispersed within. The dies provide fibers having enhanced mechanical and processing properties. The orientation section comprises orientation channels (203) wherein a ratio of a cross-sectional area having of the channel inlet to a cross-sectional area of the channel outlet is between 2 and 45.

Abstract: In an embodiment, a composition comprises a polycarbonate; 1 to 5 wt % based on a total weight of the composition of a nanosilica having a D50 particle size by volume of 5 to 50 nanometers; wherein the nanosilica has a hydrophobic coating; and a siloxane domain having repeat units of the formula 10; wherein each R is independently a C1-13 monovalent organic group and the value of E is 2 to 1,000; wherein the composition comprises at least one of a polycarbonate-polysiloxane copolymer, 0.1 to 5 wt % of a polysiloxane homopolymer based on the total weight of the composition, or a plurality of polysiloxane particles having a D50 particle size by volume of 0.1 to 10 micrometers.

Abstract: A copolycarbonate optical article comprises a polycarbonate composition including: a copolycarbonate having: 2 to 60 mol % of phthalimidine carbonate units, 2 to 90 mol % of high heat carbonate units, and optionally 2 to 60 mol % of bisphenol A carbonate units. The copolycarbonate has less than 100 ppm of each of phthalimidine, high heat bisphenol, and bisphenol A monomers, and less than 5 ppm of various ions, and is prepared from monomers each having a purity of at least 99.6%. The polycarbonate composition has a glass transition temperature of 200° C. to and a yellowness index of less than 30.

Abstract: A branched polycarbonate comprising: high heat aromatic carbonate units derived from a high heat aromatic dihydroxy monomer units; optionally, low heat carbonate units derived from low heat monomer units; and 0.05-1.5 mole percent, preferably 0.05-1.0 mole percent, of a branching agent based on the total number of moles in the branched polycarbonate; wherein the branched polycarbonate has a tensile stress at break of 10-70 megaPascals measured according to ISO 527, and a glass transition temperature of 170-260° C. measured by differential scanning calorimetry according to ASTM D3418 with a 20° C./min heating rate.

Abstract: The invention relates to a heterophasic propylene copolymer comprising a matrix phase comprising a propylene polymer and a dispersed phase comprising an ethylene-?-olefin elastomer comprising ethylene and at least one C3 to C10 olefin, wherein the propylene polymer has a melt flow index of at least 200 dg/min or at least 150 dg/min as determined by IS01 133:2005 at 230° C. and 2.16 kg, wherein the propylene polymer has an intrinsic viscosity IVPP and the ethylene-?-olefin elastomer has an intrinsic viscosity IVEPR where the ratio of IVEPR/IVPP is 3-7, wherein the copolymer comprises 8-20 wt % or 20-30 wt % of the ethylene-a-olefin elastomer, wherein the ethylene-a-olefin elastomer of the dispersed phase comprises 10-55 wt % of ethylene.

Abstract: Provided are fibers that comprise a matrix thermoplastic polymer and fibrillated reinforcement materials (e.g., PTFE fibrils) dispersed therein. The disclosed fibers exhibit improved processability and other improved handling characteristics as compared to fibril-free fibers.

Abstract: The disclosure is directed to polymer compositions comprising a matrix polymer component comprising a crystalline or semi-crystalline polymer; and a fibrillated fluoropolymer, a fibrillated fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. Methods of preparing and using these polymer compositions, as well as articles comprising the polymer compositions, as also described.

Abstract: The disclosure is directed to polymer compositions comprising a matrix polymer component comprising a crystalline or semi-crystalline polymer; and a fibrillated fluoropolymer, a fibrillated fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. Methods of preparing and using these polymer compositions, as well as articles comprising the polymer compositions, as also described.

Abstract: Polycarbonate blend compositions are disclosed. The compositions include at least one polycarbonate and one photochromic dye. The compositions can include at least one poly(aliphatic ester)-polycarbonate. The compositions can be used to prepare articles of manufacture.

Abstract: Described herein are polymer compositions comprising a matrix polymer component comprising a dynamic cross-linked polymer composition; and a fibrillated fluoropolymer, a fibrillated fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. Methods of making and using these polymer compositions are also described.

Abstract: Described herein are polymer compositions comprising a matrix polymer component comprising a dynamic cross-linked polymer composition; and a fibrillated fluoropolymer, a fibrillated fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. Methods of making and using these polymer compositions are also described.