Patents by Inventor Vasileios Kanellopoulos
Vasileios Kanellopoulos has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10702842Abstract: The present invention deals with a process of polymerising at least one olefin in a fluidised bed in a fluidised bed polymerisation reactor comprising a top zone, a middle zone in direct contact and below, a bottom zone in direct contact with and below the middle zone and wherein the reactor does not comprise a fluidisation grid. The process comprises passing a stream comprising the fluidisation gas and polymer particles into a separation step and withdrawing a stream comprising the polymer particles from the separation step and returning it to the polymerisation reactor. The process comprises adding a support gas stream to the stream comprising the polymer particles downstream of the separation step.Type: GrantFiled: December 21, 2016Date of Patent: July 7, 2020Assignee: BOREALIS AGInventors: Vasileios Kanellopoulos, Klaus Nyfors, Gunter Weickert, Eric-Jan Prinsen
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Patent number: 10676544Abstract: A process for polymerising alpha-olefin monomers in a loop reactor comprising the steps of introducing a main feed stream (2) comprising at least one alpha-olefin monomer into the loop reactor (1); introducing a polymerisation catalyst into the loop reactor (1); polymerising the at least one alpha-olefin monomer in the presence of the polymerisation catalyst in the loop reactor (1) to produce a slurry comprising polyolefin particles; withdrawing an outlet stream (4) comprising at least a portion of the slurry from the loop reactor (1); adding a first feed stream (9) comprising the at least one alpha-olefin monomer and/or hydrogen to the outlet stream (4) to form a concentrator inlet stream (8); introducing the concentrator inlet stream (8) into a concentrator (5); withdrawing from the concentrator (5) an overflow stream (6) comprising the polyolefin particles, wherein the concentration of the polyolefin particles in the overflow stream (6) is smaller than in the concentrator inlet stream (8); withdrawing fromType: GrantFiled: November 22, 2016Date of Patent: June 9, 2020Assignee: BOREALIS AGInventors: Kauno Alastalo, Mohammad Al-Haj Ali, Vasileios Kanellopoulos, Apostolos Krallis
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Publication number: 20200123279Abstract: A method and arrangement of producing polymer comprising polymerizing in reactor having a top zone having a generally conical shape, a middle zone in direct contact with and below said top zone having a generally cylindrical shape, a bottom zone having a generally conical shape thereby polymerizing at least one olefin, in the presence of a polymerization catalyst and fluidization gas to obtain (i) a first stream comprising fluidization gas and particles of olefin polymer, (ii) a second stream comprising fluidization gas and agglomerates of olefin polymer, (iii) a third olefin polymer product stream—directing the first stream comprising fluidization gas and olefin polymer particles to a series of at least three cyclones connected to the fluidized bed reactor—separating agglomerates of olefin polymer from the second stream, withdrawing from the fluidized bed polymerization reactor the third olefin polymer product stream.Type: ApplicationFiled: June 15, 2018Publication date: April 23, 2020Inventors: Vasileios Kanellopoulos, Apostolos Krallis, Klaus Nyfors, Erno Elovainio
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Patent number: 10597472Abstract: An in-line blending process for polymers comprising: (a) providing two or more reactor-low pressure separator units (1,7) in parallel configuration, each reactor-low pressure separator unit comprising one reactor (2,8) fluidly connected to one low pressure separator (3,9) downstream and further a recycling line (5,11) connecting the low pressure separator (3,9) back to the corresponding reactor (2,8); (b) polymerizing olefin monomers having two or more carbon atoms in each of the reactors (2,8) in solution polymerisation; (c) forming an unreduced reactor effluents stream including a homogenous fluid phase polymer-monomer-solvent mixture in each of the reactors (2,8), (d) passing the unreduced reactor effluents streams from each of the reactors (2,8) through the corresponding low pressure separators (3,9), whereby the temperature and pressure of the low pressure separators (3,9) is adjusted such that a liquid phase and a vapour phase are obtained, whereby yielding a polymer-enriched liquid phase and a polymer-Type: GrantFiled: December 21, 2016Date of Patent: March 24, 2020Assignee: BOREALIS AGInventors: Henry Sleijster, Mohammad Al-Haj Ali, Jukka Rasanen, Samuli Zitting, Michiel Bergstra, Erik Eriksson, Christof Wurnitsch, Guhan Mathivanan, Sameer Vijay, Vasileios Kanellopoulos, Jani Aho, Jouni Takakarhu
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Patent number: 10450391Abstract: The present invention deals with an olefin polymerisation process. At least one olefin is polymerised in gas phase in a fluidised bed in the presence of an olefin polymerisation catalyst in a polymerisation reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone. Fluidisation gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor, and withdrawn from the top zone of the reactor. The gas is then compressed, cooled and returned into the bottom zone of the reactor. A fluidised bed is thus formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream wherein the superficial velocity of the fluidisation gas is less than the transport velocity of the particles. There is no fluidisation grid in the reactor.Type: GrantFiled: June 10, 2016Date of Patent: October 22, 2019Assignee: Borealis AGInventors: Vasileios Kanellopoulos, Klaus Nyfors, Pablo Ivan Aguayo Arellano, Gunter Weickert, Eric-Jan Prinsen
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Publication number: 20190270830Abstract: The present invention is directed to a process for separating an olefm copolymer from volatile gases using a flash separator. The flash separator can be used with a solution or high pressure process. The mass transport of volatile gases from the viscous polymer melt is increased.Type: ApplicationFiled: September 18, 2017Publication date: September 5, 2019Inventors: Vasileios Kanellopoulos, Mohammad Al-Haj Ali, Apostolos Krallis
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Patent number: 10358507Abstract: The present invention is directed to a process for separating hydrocarbons from a solution comprising a polymer. The process comprises the steps of: (A) withdrawing a solution stream comprising the polymer from a first vessel; (B) passing the solution stream into a flash vessel; (C) spraying the solution stream into droplets in the first flash vessel thereby establishing a stream of droplets within the flash vessel. The solution forms a downwards falling film within the flash vessel.Type: GrantFiled: March 24, 2016Date of Patent: July 23, 2019Assignee: BOREALIS AGInventors: Mohammad Al-Haj Ali, Vasileios Kanellopoulos, Apostolos Krallis, Henry Sleijster, Samuli Zitting
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Publication number: 20180369775Abstract: The present invention deals with a process of polymerising at least one olefin in a fluidised bed in a fluidised bed polymerisation reactor comprising a top zone, a middle zone in direct contact and below, a bottom zone in direct contact with and below the middle zone and wherein the reactor does not comprise a fluidisation grid. The process comprises passing a stream comprising the fluidisation gas and polymer particles into a separation step and withdrawing a stream comprising the polymer particles from the separation step and returning it to the polymerisation reactor. The process comprises adding a support gas stream to the stream comprising the polymer particles downstream of the separation step.Type: ApplicationFiled: December 21, 2016Publication date: December 27, 2018Inventors: Vasileios Kanellopoulos, Klaus Nyfors, Gunter Weickert, Eric-Jan Prinsen
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Publication number: 20180371201Abstract: The present invention deals with a process for polymerising olefins in a solution and withdrawing a stream of the solution from the polymerisation reactor and passing it to a sequence of heating steps. The heated solution is passed to a separation step, which is conducted at a pressure of no more than 15 bar and in which separation step a liquid phase comprising the polymer and a vapour phase coexist. A vapour stream and a concentrated solution stream comprising the polymer are withdrawn from the separation step. At least a part of the vapour stream is passed to the first polymerisation reactor, to the second polymerisation reactor or to both.Type: ApplicationFiled: December 21, 2016Publication date: December 27, 2018Inventors: Mohammad AL-HAJ ALI, Michiel BERGSTRA, Erik ERIKSSON, Guhan MATHIVANAN, Jukka RÄSÄNEN, Henry SLEIJSTER, Sameer VIJAY, Christof WURNITSCH, Samuli ZITTING, Vasileios KANELLOPOULOS, Jani AHO
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Publication number: 20180346612Abstract: The present invention is directed to a process for separating hydrocarbons from a solution comprising a polymer. The process comprises the steps of: (A) withdrawing a solution stream comprising the polymer from a first vessel; (B) passing the solution stream into a flash vessel; (C) spraying the solution stream into droplets in the first flash vessel thereby establishing a stream of droplets within the flash vessel. The solution forms a downwards falling film within the flash vessel.Type: ApplicationFiled: March 24, 2016Publication date: December 6, 2018Inventors: Mohammad AL-HAJ ALI, Vasileios KANELLOPOULOS, Apostolos KRALLIS, Henry SLEIJSTER, Samuli ZITTING
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Publication number: 20180327529Abstract: An in-line blending process for polymers comprising: (a) providing two or more reactor-low pressure separator units (1,7) in parallel configuration, each reactor-low pressure separator unit comprising one reactor (2,8) fluidly connected to one low pressure separator (3,9) downstream and further a recycling line (5,11) connecting the low pressure separator (3,9) back to the corresponding reactor (2,8); (b) polymerizing olefm monomers having two or more carbon atoms in each of the reactors (2,8) in soltion polymerisation; (c) forming an unreduced reactor effluents stream including a homogenous fluid phase polymer-monomer-solvent mixture in each of the reactors (2,8), (d) passing the unreduced reactor effluents streams from each of the reactors (2,8) through the corresponding low pressure separators (3,9), whereby the temperature and pressure of the low pressure separators (3,9) is adjusted such that a liquid phase and a vapour phase are obtained, whereby yielding a polymer-enriched liquid phase and a polymer-leType: ApplicationFiled: December 21, 2016Publication date: November 15, 2018Inventors: Henry Sleijster, Mohammad Al-Haj Ali, Jukka Rasanen, Samuli Zitting, Michiel Bergstra, Erik Eriksson, Christof Wurnitsch, Guhan Mathivanan, Sameer Vijay, Vasileios Kanellopoulos, Jani Aho, Jouni Takakarhu
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Publication number: 20180327518Abstract: A process for polymerising alpha-olefin monomers in a loop reactor comprising the steps of introducing a main feed stream (2) comprising at least one alpha-olefin monomer into the loop reactor (1); introducing a polymerisation catalyst into the loop reactor (1); polymerising the at least one alpha-olefin monomer in the presence of the polymerisation catalyst in the loop reactor (1) to produce a slurry comprising polyolefin particles; withdrawing an outlet stream (4) comprising at least a portion of the slurry from the loop reactor (1); adding a first feed stream (9) comprising the at least one alpha-olefin monomer and/or hydrogen to the outlet stream (4) to form a concentrator inlet stream (8); introducing the concentrator inlet stream (8) into a concentrator (5); withdrawing from the concentrator (5) an overflow stream (6) comprising the polyolefin particles, wherein the concentration of the polyolefin particles in the overflow stream (6) is smaller than in the concentrator inlet stream (8); withdrawing fromType: ApplicationFiled: November 22, 2016Publication date: November 15, 2018Inventors: Kauno Alastalo, Mohammad Al-Haj Ali, Vasileios Kanellopoulos, Apostolos Krallis
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Publication number: 20180155465Abstract: The present invention deals with an olefin polymerisation process. At least one olefin is polymerised in gas phase in a fluidised bed in the presence of an olefin polymerisation catalyst in a polymerisation reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone. Fluidisation gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor, and withdrawn from the top zone of the reactor. The gas is then compressed, cooled and returned into the bottom zone of the reactor. A fluidised bed is thus formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream wherein the superficial velocity of the fluidisation gas is less than the transport velocity of the particles. There is no fluidisation grid in the reactor.Type: ApplicationFiled: June 10, 2016Publication date: June 7, 2018Inventors: Vasileios KANELLOPOULOS, Klaus NYFORS, Pablo Ivan AGUAYO ARELLANO, Gunter WEICKERT, Eric-Jan PRINSEN
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Patent number: 9790290Abstract: An olefin polymerization process comprising polymerizing olefins in gas phase in a fluidized bed in the presence of an olefin polymerization catalyst in a polymerization reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone having a height to diameter ratio L/D of at least 4, above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone wherein (i) fluidization gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor; (ii) the fluidization gas is withdrawn from the top zone of the reactor, filtered, compressed, cooled and returned into the bottom zone of the reactor; (iii) a fluidized bed is formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream; and (iv) there is no fluidization grid in the reactor; characterized in that the gas velocity is maintained in the reactor such that NBrType: GrantFiled: February 27, 2015Date of Patent: October 17, 2017Assignee: Borealis AGInventors: Vasileios Kanellopoulos, Apostolos Krallis, Mohammad Al-Haj Ali, Ravindra Tupe
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Patent number: 9539556Abstract: The present invention is directed to a process for polymerizing olefins in gas phase in a fluidized bed reactor having a vertical body, a generally conical downwards tapering bottom zone, a generally cylindrical middle zone above the bottom zone, and a generally conical upwards tapering top zone above the middle zone. The fluidization gas is withdrawn from the top zone of the reactor, compressed and cooled so that a part of the fluidization gas condenses and then introduced to the bottom zone of the reactor. The bed is thus cooled upon evaporation of the liquid. There is no fluidization grid in the reactor.Type: GrantFiled: February 27, 2015Date of Patent: January 10, 2017Assignee: BOREALIS AGInventors: Mohammad Al-Haj Ali, Apostolos Krallis, Vasileios Kanellopoulos
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Publication number: 20160354747Abstract: The present invention is directed to a process for polymerizing olefins in gas phase in a fluidized bed reactor having a vertical body, a generally conical downwards tapering bottom zone, a generally cylindrical middle zone above the bottom zone, and a generally conical upwards tapering top zone above the middle zone. The fluidization gas is withdrawn from the top zone of the reactor, compressed and cooled so that a part of the fluidization gas condenses and then introduced to the bottom zone of the reactor. The bed is thus cooled upon evaporation of the liquid. There is no fluidization grid in the reactor.Type: ApplicationFiled: February 27, 2015Publication date: December 8, 2016Inventors: Mohammad Al-Haj Ali, Apostolos Krallis, Vasileios Kanellopoulos
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Publication number: 20160355613Abstract: An olefin polymerization process comprising polymerizing olefins in gas phase in a fluidized bed in the presence of an olefin polymerization catalyst in a polymerization reactor having a vertical body; a generally conical downwards tapering bottom zone; a generally cylindrical middle zone having a height to diameter ratio L/D of at least 4, above and connected to said bottom zone; and a generally conical upwards tapering top zone above and connected to said middle zone wherein (i) fluidization gas is introduced to the bottom zone of the reactor from where it passes upwards through the reactor; (ii) the fluidization gas is withdrawn from the top zone of the reactor, filtered, compressed, cooled and returned into the bottom zone of the reactor; (iii) a fluidized bed is formed within the reactor where the growing polymer particles are suspended in the upwards rising gas stream; and (iv) there is no fluidization grid in the reactor; characterized in that the gas velocity is maintained in the reactor such that NBrType: ApplicationFiled: February 27, 2015Publication date: December 8, 2016Inventors: Vasileios Kanellopoulos, Apostolos Krallis, Mohammad Al-Haj Ali, Ravindra Tupe
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Patent number: 9382359Abstract: Reactor assembly for the production of polymers including a fluidized bed reactor and method for operating the reactor assembly.Type: GrantFiled: August 26, 2013Date of Patent: July 5, 2016Assignee: BOREALIS AGInventors: Vasileios Kanellopoulos, Mohammad Al-Haj Ali
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Publication number: 20150218295Abstract: Reactor assembly for the production of polymers including a fluidized bed reactor and method for operating the reactor assembly.Type: ApplicationFiled: August 26, 2013Publication date: August 6, 2015Applicant: BOREALIS AGInventors: Vasileios Kanellopoulos, Mohammad Al-Haj Ali