Patents by Inventor Vasilis Papavassiliou

Vasilis Papavassiliou has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11807597
    Abstract: Methods and systems for producing acetic acid, including glacial acetic acid. A first stream of a reactor fluid that includes methyl acetate, water, and a first amount of carbon monoxide may be forwarded from a reactor to a reactor cooler to form a cooled reactor fluid. The cooled reactor fluid may have a concentration of methyl acetate that is lower than the concentration of methyl acetate in the reactor fluid.
    Type: Grant
    Filed: March 31, 2022
    Date of Patent: November 7, 2023
    Assignee: LyondellBasell Acetyls, LLC
    Inventors: Vasilis Papavassiliou, Noel C. Hallinan, David L. Ramage, Gary A. Sawyer, Rene Zamarripa, Michael E. Fitzpatrick, Brian A. Salisbury
  • Publication number: 20220315516
    Abstract: Methods and systems for producing acetic acid, including glacial acetic acid. A first stream of a reactor fluid that includes methyl acetate, water, and a first amount of carbon monoxide may be forwarded from a reactor to a reactor cooler to form a cooled reactor fluid. The cooled reactor fluid may have a concentration of methyl acetate that is lower than the concentration of methyl acetate in the reactor fluid.
    Type: Application
    Filed: March 31, 2022
    Publication date: October 6, 2022
    Applicant: LyondellBasell Acetyls, LLC
    Inventors: Vasilis Papavassiliou, Noel C. Hallinan, David L. Ramage, Gary A. Sawyer, Rene Zamarripa
  • Publication number: 20210269379
    Abstract: Organic sulfur compounds contained in refinery off gas streams having either high or low concentrations of olefins are converted to hydrogen sulfides which can be then be removed using conventional amine treating systems. The process uses a catalytic reactor with or without a hydrotreater depending on the olefin concentration of the off gas stream. The catalytic reactor operates in a hydrogenation mode or an oxidation mode to convert a majority of organic sulfur compounds into hydrogen sulfides.
    Type: Application
    Filed: May 14, 2021
    Publication date: September 2, 2021
    Inventors: Minish Mahendra Shah, Raymond Francis Drnevich, Vasilis Papavassiliou
  • Patent number: 11034630
    Abstract: Organic sulfur compounds contained in refinery off gas streams having either high ort low concentrations of olefins are converted to hydrogen sulfides which can be then be removed using conventional amine treating systems. The process uses a catalytic reactor with or without a hydrotreater depending on the olefin concentration of the off gas stream. The catalytic reactor operates in a hydrogenation mode or an oxidation mode to convert a majority of organic sulfur compounds into hydrogen sulfides.
    Type: Grant
    Filed: July 13, 2018
    Date of Patent: June 15, 2021
    Assignee: PRAXAIR TECHNOLOGY, INC.
    Inventors: Minish Mahendra Shah, Raymond Francis Drnevich, Vasilis Papavassiliou
  • Patent number: 10508245
    Abstract: The present invention relates to decreasing the amount of diluent needed to convert a heavy oil to a bitumen product that can be transported by pipeline. More specifically, the invention relates to a method and apparatus for partially upgrading heavy oil into a lower viscosity bitumen product.
    Type: Grant
    Filed: October 3, 2018
    Date of Patent: December 17, 2019
    Assignee: PRAXAIR TECHNOLOGY, INC.
    Inventors: Vasilis Papavassiliou, Gregory J Panuccio
  • Publication number: 20190031963
    Abstract: The present invention relates to decreasing the amount of diluent needed to convert a heavy oil to a bitumen product that can be transported by pipeline. More specifically, the invention relates to a method and apparatus for partially upgrading heavy oil into a lower viscosity bitumen product.
    Type: Application
    Filed: October 3, 2018
    Publication date: January 31, 2019
    Inventors: Vasilis Papavassiliou, Gregory J. Panuccio
  • Patent number: 10125324
    Abstract: The present invention relates to decreasing the amount of diluent needed to convert a heavy oil to a bitumen product that can be transported by pipeline. More specifically, the invention relates to a method and apparatus for partially upgrading heavy oil into a lower viscosity bitumen product.
    Type: Grant
    Filed: December 18, 2015
    Date of Patent: November 13, 2018
    Assignee: PRAXAIR TECHNOLOGY, INC.
    Inventors: Vasilis Papavassiliou, Gregory J. Panuccio
  • Publication number: 20180319723
    Abstract: Organic sulfur compounds contained in refinery off gas streams having either high ort low concentrations of olefins are converted to hydrogen sulfides which can be then be removed using conventional amine treating systems. The process uses a catalytic reactor with or without a hydrotreater depending on the olefin concentration of the off gas stream. The catalytic reactor operates in a hydrogenation mode or an oxidation mode to convert a majority of organic sulfur compounds into hydrogen sulfides.
    Type: Application
    Filed: July 13, 2018
    Publication date: November 8, 2018
    Inventors: Minish Mahendra Shah, Raymond Francis Drnevich, Vasilis Papavassiliou
  • Publication number: 20180282641
    Abstract: The present invention relates to decreasing the amount of diluent needed to convert a heavy oil to a bitumen product that can be transported by pipeline. More specifically, the invention relates to a method and apparatus for partially upgrading heavy oil into a lower viscosity bitumen product.
    Type: Application
    Filed: June 6, 2018
    Publication date: October 4, 2018
    Inventors: Vasilis Papavassiliou, Gregory J. Panuccio
  • Patent number: 10011784
    Abstract: The present invention relates to decreasing the amount of diluent needed to convert a heavy oil to a bitumen product that can be transported by pipeline. More specifically, the invention relates to a method and apparatus for partially upgrading heavy oil into a lower viscosity bitumen product.
    Type: Grant
    Filed: December 18, 2015
    Date of Patent: July 3, 2018
    Assignee: PRAXAIR TECHNOLOGY, INC.
    Inventors: Vasilis Papavassiliou, Gregory J. Panuccio
  • Publication number: 20170175013
    Abstract: The present invention relates to decreasing the amount of diluent needed to convert a heavy oil to a bitumen product that can be transported by pipeline. More specifically, the invention relates to a method and apparatus for partially upgrading heavy oil into a lower viscosity bitumen product.
    Type: Application
    Filed: December 18, 2015
    Publication date: June 22, 2017
    Inventors: Vasilis Papavassiliou, Gregory J. Panuccio
  • Publication number: 20170175004
    Abstract: The present invention relates to decreasing the amount of diluent needed to convert a heavy oil to a bitumen product that can be transported by pipeline. More specifically, the invention relates to a method and apparatus for partially upgrading heavy oil into a lower viscosity bitumen product.
    Type: Application
    Filed: December 18, 2015
    Publication date: June 22, 2017
    Inventors: Vasilis Papavassiliou, Gregory J. Panuccio
  • Patent number: 9540293
    Abstract: Organic sulfur compounds contained in refinery off gas streams having either high ort low concentrations of olefins are converted to hydrogen sulfides which can be then be removed using conventional amine treating systems. The process uses a catalytic reactor with or without a hydrotreater depending on the olefin concentration of the off gas stream. The catalytic reactor operates in a hydrogenation mode or an oxidation mode to convert a majority of organic sulfur compounds into hydrogen sulfides.
    Type: Grant
    Filed: April 24, 2014
    Date of Patent: January 10, 2017
    Assignee: Praxair Technology, Inc.
    Inventors: Minish Mahendra Shah, Raymond Francis Drnevich, Vasilis Papavassiliou
  • Publication number: 20160361687
    Abstract: Organic sulfur compounds contained in refinery off gas streams having either high ort low concentrations of olefins are converted to hydrogen sulfides which can be then be removed using conventional amine treating systems. The process uses a catalytic reactor with or without a hydrotreater depending on the olefin concentration of the off gas stream. The catalytic reactor operates in a hydrogenation mode or an oxidation mode to convert a majority of organic sulfur compounds into hydrogen sulfides.
    Type: Application
    Filed: August 29, 2016
    Publication date: December 15, 2016
    Inventors: Minish Mahendra Shah, Raymond Francis Drnevich, Vasilis Papavassiliou
  • Publication number: 20140235915
    Abstract: Organic sulfur compounds contained in refinery off gas streams having either high ort low concentrations of olefins are converted to hydrogen sulfides which can be then be removed using conventional amine treating systems. The process uses a catalytic reactor with or without a hydrotreater depending on the olefin concentration of the off gas stream. The catalytic reactor operates in a hydrogenation mode or an oxidation mode to convert a majority of organic sulfur compounds into hydrogen sulfides.
    Type: Application
    Filed: April 24, 2014
    Publication date: August 21, 2014
    Inventors: Minish Mahendra Shah, Raymond Francis Drnevich, Vasilis Papavassiliou
  • Patent number: 8808654
    Abstract: Organic sulfur compounds contained in refinery off gas streams having either high ort low concentrations of olefins are converted to hydrogen sulfides which can be then be removed using conventional amine treating systems. The process uses a catalytic reactor with or without a hydrotreater depending on the olefin concentration of the off gas stream. The catalytic reactor operates in a hydrogenation mode or an oxidation mode to convert a majority of organic sulfur compounds into hydrogen sulfides.
    Type: Grant
    Filed: August 16, 2010
    Date of Patent: August 19, 2014
    Assignee: Praxair Technology, Inc.
    Inventors: Minish Mahendra Shah, Raymond Francis Drnevich, Vasilis Papavassiliou
  • Patent number: 8409427
    Abstract: The present invention provides a method and apparatus for producing a treated hydrocarbon containing stream for use as a feed to a steam methane reformer of a hydrogen plant. In accordance with such method, amounts of olefins and organic sulfur species within an untreated feed are decreased in a reactor that is operated in either a hydrogenation mode to hydrogenate the olefins into saturated hydrocarbons or a pre-reforming mode in which hydrocarbon containing two or more carbon atoms including the olefins are reacted with oxygen and steam to form saturated hydrocarbons, methane, additional hydrogen and carbon monoxide. The reactor is configured and operates at a sufficiently high space velocity that olefin and organic species slip occurs that is further treated in a hydrotreater. The reactor contains a catalyst capable of promoting both hydrogenation and oxidation reactions and the hydrotreater contains a catalyst that is capable of only promoting hydrogenation reactions.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: April 2, 2013
    Assignee: Praxair Technology, Inc.
    Inventors: Troy M. Raybold, Raymond Francis Drnevich, Vasilis Papavassiliou
  • Patent number: 8323365
    Abstract: The present invention relates to systems and processes for producing syngas in steam methane reformer (SMR)-based plants, particularly to the use of a high space velocity, dual mode catalytic reactor to pre-reform plant feedstock. The dual mode reactor has the capability to operate in two modes: either without oxygen addition in a reforming mode or with oxygen addition in a partial oxidation-reforming mode. The dual mode reactor allows the syngas production rate of the plant to be manipulated without the added capital expense of a reheat coil and with reduced impact on export steam production.
    Type: Grant
    Filed: May 22, 2008
    Date of Patent: December 4, 2012
    Assignee: Praxair Technology, Inc.
    Inventors: Raymond Francis Drnevich, Vasilis Papavassiliou, Troy Michael Raybold, Ramchandra Mukund Watwe
  • Patent number: 8318004
    Abstract: A method and apparatus for producing a treated hydrocarbon containing stream for use as a feed to a hydrogen plant having a steam methane reformer in which an untreated hydrocarbon containing stream is introduced into two reaction stages connected in series to hydrogenate olefins and to convert organic sulfur species to hydrogen sulfide. The second of the two stages can also be operated in a pre-reforming mode to generate additional hydrogen through introduction of the oxygen and steam into such stage. A sulfur tolerant catalyst is used in both stages to promote hydrogenation and oxidation reactions. Sulfur is removed between stages by adsorption of the hydrogen sulfide to prevent deactivation of the catalyst in the second of the stages that would otherwise occur during operation of the second reaction stage in a pre-reforming mode of operation.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: November 27, 2012
    Assignee: Praxair Technology, Inc.
    Inventors: Raymond Francis Drnevich, Vasilis Papavassiliou, Troy M. Raybold, Perry Raymond Pacouloute
  • Publication number: 20120041242
    Abstract: A method and apparatus for producing a substitute natural gas stream to be added to a natural gas stream in which at least part of a refinery gas stream is reacted in a catalytic reactor to hydrogenate olefins into saturated hydrocarbons. The extent to which hydrogen and olefins are reacted in the catalytic reactor is controlled to reduce the concentration of olefins in the resulting substitute natural gas stream and to increase the interchangeability of the substitute natural gas stream with the natural gas. This control can be effectuated by by-passing part of the refinery off gas to an intermediate product stream produced by the catalytic reactor and thereby forming the substitute natural gas stream from the by-passed refinery gas stream and the intermediate product stream.
    Type: Application
    Filed: August 12, 2010
    Publication date: February 16, 2012
    Inventors: Gregory Joseph Panuccio, Vasilis Papavassiliou, Raymond Francis Drnevich