Patents by Inventor Vasily Topolkaraev

Vasily Topolkaraev has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20120141569
    Abstract: A wipe that contains a fibrous web on which is coated an antimicrobial composition is provided. The composition includes a botanical oil derived from a plant (e.g., thymol, carvacrol, etc.). Because the botanical oil is volatile and tends to evaporate and lose efficacy during storage and prior to use, a protein is also employed in the composition to enhance long term stability of the oil and, in turn, its antimicrobial efficacy. The protein is “film-forming” in the sense that it tends to form a substantially continuous film when coated onto a surface of the fibrous web. Because such proteins are typically stiff and brittle in nature, a continuous film would restrict the ability of the fibers to move and bend, thereby reducing web flexibility and drape. Thus, it is typically desired that the antimicrobial composition form a discontinuous coating on the fibrous web.
    Type: Application
    Filed: December 7, 2010
    Publication date: June 7, 2012
    Applicant: KIMBERLY-CLARK WORLDWIDE, INC.
    Inventors: JaeHong Lee, Vasily A. Topolkaraev, Neil T. Scholl, YoungSook Kim, David W. Koenig, James H. Wang
  • Publication number: 20120040185
    Abstract: Polylactic acid fibers formed from a thermoplastic composition that contains polylactic acid and a polymeric toughening additive are provided. The present inventors have discovered that the specific nature of the components and process by which they are blended may be carefully controlled to achieve a composition having desirable morphological features. More particularly, the toughening additive can be dispersed as discrete physical domains within a continuous phase of the polylactic acid. These domains have a particular size, shape, and distribution such that upon fiber drawing, they absorb energy and become elongated. This allows the resulting composition to exhibit a more pliable and softer behavior than the otherwise rigid polylactic acid. Through selective control over the components and method employed, the present inventors have discovered that the resulting fibers may thus exhibit good mechanical properties, both during and after melt spinning.
    Type: Application
    Filed: August 13, 2010
    Publication date: February 16, 2012
    Applicant: KIMBERLY-CLARK WORLDWIDE, INC.
    Inventors: Vasily A. Topolkaraev, Peiguang Zhou, Gregory J. Wideman, Tom Eby, Ryan J. McEneany
  • Publication number: 20120040582
    Abstract: A method for forming biodegradable fibers is provided. The method includes blending polylactic acid with a polyepoxide modifier to form a thermoplastic composition, extruding the thermoplastic composition through a die, and thereafter passing the extruded composition through a die to form a fiber. Without intending to be limited by theory, it is believed that the polyepoxide modifier reacts with the polylactic acid and results in branching of its polymer backbone, thereby improving its melt strength and stability during fiber spinning without significantly reducing glass transition temperature. The reaction-induced branching can also increase molecular weight, which may lead to improved fiber ductility and the ability to better dissipate energy when subjected to an elongation force. To minimize premature reaction, the polylactic acid and polyepoxide modifier are first blended together at a relatively low temperature(s).
    Type: Application
    Filed: August 13, 2010
    Publication date: February 16, 2012
    Applicant: KIMBERLY-CLARK WORLDWIDE, INC.
    Inventors: Vasily A. Topolkaraev, Ryan J. McEneany, Tom Eby, Tyler J. Lark
  • Patent number: 7994078
    Abstract: The present invention provides a nonwoven web prepared from an aliphatic polyester polymer which has sufficient tear strength and is biodegradable. Biodegradable nonwoven webs of the present are prepared from a polymer blend having from about 65% by weight to about 99% by weight of a biodegradable aliphatic polyester polymer and from about 1% by weight to about 35% by weight of a second polymer selected from the group consisting of a polymer having a lower melting point than the biodegradable aliphatic polyester polymer, a polymer having a lower molecular weight than the biodegradable aliphatic polyester polymer and mixtures thereof. Surprisingly, the nonwoven webs of the present invention have a tear strength greater than the tear strength of a nonwoven web prepared from the biodegradable aliphatic polyester polymer alone.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: August 9, 2011
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Mark G. Reichmann, Maya Aroch, Joy Francine Jordan, Peter Michailovich Kobylivker, Rowland Jaynes McClellan, Jr., Ann Louise McCormack, Palani Raj Ramaswami Wallajapet, Vasily A. Topolkaraev, Dennis Y. Lee, Steven R. Stopper
  • Patent number: 7989062
    Abstract: A biodegradable nonwoven web comprising substantially continuous multicomponent filaments is provided. The filaments comprise a first component and a second component. The first component contains at least one high-melting point aliphatic polyester having a melting point of from about 160° C. to about 250° C. and the second component contains at least one low-melting point aliphatic polyester. The melting point of the low-melting point aliphatic polyester is at least about 30° C. less than the melting point of the high-melting point aliphatic polyester. The low-melting point aliphatic polyester has a number average molecular weight of from about 30,000 to about 120,000 Daltons, a glass transition temperature of less than about 25° C., and an apparent viscosity of from about 50 to about 215 Pascal-seconds, as determined at a temperature of 160° C. and a shear rate of 1000 sec?1.
    Type: Grant
    Filed: April 7, 2006
    Date of Patent: August 2, 2011
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Jayant Chakravarty, Vasily Topolkaraev, John Herbert Conrad, Stephen Avedis Baratian, Jared L. Martin
  • Patent number: 7972692
    Abstract: A multicomponent fiber that contains a high-melting aliphatic polyester and a low-melting aliphatic polyester is provided. The multicomponent fibers are substantially biodegradable, yet readily processed into nonwoven structures that exhibit effective fibrous mechanical properties.
    Type: Grant
    Filed: December 15, 2005
    Date of Patent: July 5, 2011
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Jayant Chakravarty, Vasily Topolkaraev, Gregory J. Wideman
  • Publication number: 20110065573
    Abstract: A biodegradable fiber that is formed from a thermoplastic composition that contains polylactic acid, a plasticizer, and a compatibilizer is provided. The compatibilizer includes a polymer that is modified with a polar compound that is compatible with the plasticizer and a non-polar component provided by the polymer backbone that is compatible with polylactic acid. Such functionalized polymers may thus stabilize each of the polymer phases and reduce plasticizer migration. By reducing the plasticizer migration, the composition may remain ductile and soft. Further, addition of the functionalized polymer may also promote improved bonding and initiate crystallization faster than conventional polylactic acid fibers. The polar compound includes an organic acid, an anhydride of an organic acid, an amide of an organic acid, or a combination thereof. Such compounds are believed to be more compatible with the generally acidic nature of the polylactic acid fibers.
    Type: Application
    Filed: May 30, 2008
    Publication date: March 17, 2011
    Inventors: Ryan J. McEneany, Vasily A. Topolkaraev, Aimin He
  • Publication number: 20110059669
    Abstract: A biodegradable, substantially continuous filament is provided. The filament contains a first component formed from at least one high melting polyester and a second component formed from at least one low melting polyester. The low melting point polyester is an aliphatic-aromatic copolyester formed by melt blending a polymer and an alcohol to initiate an alcoholysis reaction that results in a copolyester having one or more hydroxyalkyl or alkyl terminal groups. By selectively controlling the alcoholysis conditions (e.g., alcohol and copolymer concentrations, catalysts, temperature, etc.), a modified aliphatic-aromatic copolyester may be achieved that has a molecular weight lower than the starting aliphatic-aromatic polymer. Such lower molecular weight polymers also have the combination of a higher melt flow index and lower apparent viscosity, which is useful in the formation of substantially continuous filaments.
    Type: Application
    Filed: August 22, 2007
    Publication date: March 10, 2011
    Inventors: Aimin He, James H. Wang, Vasily A. Topolkaraev, Gregory J. Wideman, Doris Palfery
  • Publication number: 20100323575
    Abstract: A biodegradable fiber for use in forming a nonwoven web is provided. The fiber is formed from a thermoplastic composition comprising at least one polylactic acid in an amount from about 75 wt. % to about 99 wt. % and at least one polyether copolymer in an amount from about 1 wt. % to about 25 wt. %, wherein the polyether copolymer contains from about 40 mol. % to about 95 mol. % of a repeating unit (A) having the following formula. wherein, x is an integer from 1 to 250, the polyether copolymer further containing from about 5 mol. % to about 60 mol. % of a repeating unit (B) having the following formula. wherein, n is an integer from 3 to 20; and y is an integer from 1 to 150. Such polyether copolymers have been found to improve a variety of characteristics of the resulting thermoplastic composition, including its ability to be melt processed into fibers and webs, as well as its sensitivity to moisture.
    Type: Application
    Filed: December 13, 2007
    Publication date: December 23, 2010
    Inventors: Aimin He, Vasily A. Topolkaraev
  • Publication number: 20100318050
    Abstract: The present invention can provide a distinctive article which includes a plurality of fibers (62), wherein the fibers include a selected polymer, fiber material. In a particular aspect, the fiber material can exhibit a “low” crystallization rate. In other aspects, the fiber material has been subjected to a low fiber-draw percentage, and the polymer in the fibers can have a high crystalline content of at least 30%. In still other aspects, the fibers can be configured to provide a fibrous web (60), and the fibrous web (60) can have a distinctive tensile strength quotient, with respect to tensile strengths along its machine-direction (22) and cross-direction (24).
    Type: Application
    Filed: July 14, 2010
    Publication date: December 16, 2010
    Inventors: Vasily A. Topolkaraev, Jayant Chakravarty, Kevin Christopher Possell, Hristo Angelov Hristov
  • Patent number: 7790640
    Abstract: The present disclosure generally relates to absorbent articles. More specifically, the present disclosure relates to an absorbent article comprising a surge management layer comprising a nonwoven web. The nonwoven web includes a filler fiber and a binder fiber. A portion of the cross-sectional area of the filler fiber is hollow, and the binder fiber includes a sheath component and a core component.
    Type: Grant
    Filed: March 23, 2006
    Date of Patent: September 7, 2010
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Jayant Chakravarty, Vasily A. Topolkaraev, Cliff J. Ellis
  • Patent number: 7780903
    Abstract: The present invention can provide a distinctive method and process for making polymer fibers (62) and nonwoven fabric webs (60). The method can include providing a fiber material that exhibits a low crystallization rate. In a particular aspect, the fiber material can be subjected to an anneal-quench at an anneal-quench temperature that approximates a prime-temperature at which the polymer material most rapidly crystallizes. In another aspect, the fiber material can be subjected to a fiber-draw at a selected fiber-draw temperature, and in a further aspect, the fiber-draw temperature can be configured to approximate the prime-temperature of the polymer material. In still other aspects, the fiber material can be subjected to a relatively small amount of fiber-draw, and the fiber-draw can be provided at a relatively low fiber-draw speed.
    Type: Grant
    Filed: June 1, 2005
    Date of Patent: August 24, 2010
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Vasily A. Topolkaraev, Jayant Chakravarty, Kevin Christopher Possell, Hristo Angelov Hristov
  • Publication number: 20100159203
    Abstract: A biodegradable and renewable film that may be employed in a wide variety of applications is provided. The film is formed from a thermoplastic composition that contains at least one starch and at least one plant protein. Even at a high renewable material content, the present inventors have discovered that films may be readily formed from plant proteins and starches by selectively controlling the individual amount of the starch and plant proteins, the nature of the starch and plant proteins, and other components used in the film. Balancing the amount of starches and plant proteins within a certain range, for instance, can reduce the likelihood of plant protein aggregation and enhance the ability of the composition to be melt processed. The composition also contains at least one plasticizer that improves the thermoplastic nature of the protein and starch components. The selection of the plasticizer may also help reduce the tendency of the plant protein to aggregate during melt processing.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 24, 2010
    Applicant: Klmberly-Clark Worldwide, Inc.
    Inventors: Bo Shi, Sarah A. Funk, James H. Wang, Gregory J. Wideman, Ross T. Kaufman, Vasily A. Topolkaraev
  • Publication number: 20100048082
    Abstract: A method for forming a biodegradable polylactic acid suitable for use in fibers is provided. Specifically, a polylactic acid is melt processed at a controlled water content to initiate a hydrolysis reaction. Without intending to be limited by theory, it is believed that the hydroxyl groups present in water are capable of attacking the ester linkage of polylactic acids, thereby leading to chain scission or “depolymerization” of the polylactic acid molecule into one or more shorter ester chains. The shorter chains may include polylactic acids, as well as minor portions of lactic acid monomers or oligomers, and combinations of any of the foregoing. By selectively controlling the hydrolysis conditions (e.g., moisture and polymer concentrations, temperature, shear rate, etc.), a hydrolytically degraded polylactic acid may be achieved that has a molecular weight lower than the starting polymer.
    Type: Application
    Filed: December 15, 2006
    Publication date: February 25, 2010
    Inventors: Vasily A. Topolkaraev, Gregory J. Wideman, Ross T. Kaufman, Alan E. Wright, Jeffrey J. Krueger, Jayant Chakravarty
  • Publication number: 20100048081
    Abstract: A method for forming a biodegradable polyester suitable for use in fibers is provided. Specifically, a biodegradable polyester is melt processed at a controlled water content to initiate a hydrolysis reaction. Without intending to be limited by theory, it is believed that the hydroxyl groups present in water are capable of attacking the ester linkage of the polyester, thereby leading to chain scission or “depolymerization” of the polyester molecule into one or more shorter ester chains. By selectively controlling the reaction conditions (e.g., water content, temperature, shear rate, etc.), a hydrolytically degraded polyester may be achieved that has a molecular weight lower than the starting polymer. Such lower molecular weight polymers have a higher melt flow rate and lower apparent viscosity, which are useful in a wide variety of fiber forming applications, such as in the meltblowing of nonwoven webs.
    Type: Application
    Filed: December 15, 2006
    Publication date: February 25, 2010
    Inventors: Vasily A. Topolkaraev, Gregory J. Wideman, Ross T. Kaufman, Alan E. Wright, Jeffrey J. Krueger, Jayant Chakravarty
  • Publication number: 20090305594
    Abstract: A method for forming a fiber is provided. The method comprises supplying at least one aromatic polyester to a melt processing device and modifying the aromatic polyester with at least one polyether copolymer within the device to form a thermoplastic composition having a melt flow rate that is greater than the melt flow rate of the aromatic polyester. The polyether copolymer contains a repeating unit (A) having the following formula: ?C2H4O?x ??(A) wherein, x is an integer from 1 to 250, the polyether copolymer further containing a repeating unit (B) having the following formula: ?CnH2nO?y ??(B) wherein, n is an integer from 3 to 20; and y is an integer from 1 to 150.
    Type: Application
    Filed: June 10, 2008
    Publication date: December 10, 2009
    Applicant: Kimberly-Clark Worldwide, Inc.
    Inventors: Aimin He, Vasily A. Topolkaraev, Alan E. Wright, Gregory J. Wideman
  • Patent number: 7619132
    Abstract: A multilayer film includes a plastic layer and an elastomeric layer. The plastic layer can contain a co-polyester of terepthalic acid, adipic acid and butanediol, and the elastomeric layer can contain a polyurethane elastomer. The plastic layer and/or the elastomeric layer can contain filler particles, and may be present as a bilayer laminate. The plastic layer and a filled elastomeric layer can also be combined with an unfilled elastomeric layer to form a tri-layer laminate. The multilayer films can provide breathable films with improved degradability, stretchability and recoverability, and tactile feel.
    Type: Grant
    Filed: December 30, 2004
    Date of Patent: November 17, 2009
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Vasily A. Topolkaraev, Patrick Martin Downey
  • Publication number: 20090171307
    Abstract: Methods for forming a translucent window on the inner surface of a liquid impermeable breathable film outer cover of an absorbent product, such as a diaper, for viewing a water dispersible ink to indicate when an insult has occurred are disclosed. Additionally, absorbent products having a translucent window and a water dispersible ink are disclosed.
    Type: Application
    Filed: December 28, 2007
    Publication date: July 2, 2009
    Applicant: Kimberly-Clark Worldwide, Inc.
    Inventors: Sharon S. Chang, Darold D. Tippey, Shirlee Ann Weber, Jessica Sara Van Handel, Vasily A. Topolkaraev, Debra Ann Miller
  • Publication number: 20080287026
    Abstract: A biodegradable nonwoven laminate is provided. The laminate comprises a spunbond layer formed from substantially continuous filaments that contain a first aliphatic polyester having a melting point of from about 50° C. to about 160° C. The meltblown layer is formed from microfibers that contain a second aliphatic polyester having a melting point of from about 50° C. to about 160° C. The first aliphatic polyester, the second aliphatic polyester, or both have an apparent viscosity of from about 20 to about 215 Pascal-seconds, as determined at a temperature of 160° C. and a shear rate of 1000 sec-1. The first aliphatic polyester may be the same or different than the second aliphatic polyester.
    Type: Application
    Filed: April 7, 2006
    Publication date: November 20, 2008
    Inventors: Jayant Chakravarty, Vasily Topolkaraev, Ross T. Kaufman, Stephen Avedis Baratian, Jared L. Martin
  • Publication number: 20080287024
    Abstract: A biodegradable nonwoven web comprising substantially continuous multicomponent filaments is provided. The filaments comprise a first component and a second component. The first component contains at least one high-melting point aliphatic polyester having a melting point of from about 160° C. to about 250° C. and the second component contains at least one low-melting point aliphatic polyester. The melting point of the low-melting point aliphatic polyester is at least about 30° C. less than the melting point of the high-melting point aliphatic polyester. The low-melting point aliphatic polyester has a number average molecular weight of from about 30,000 to about 120,000 Daltons, a glass transition temperature of less than about 25° C., and an apparent viscosity of from about 50 to about 215 Pascal-seconds, as determined at a temperature of 160° C. and a shear rate of 1000 sec?1.
    Type: Application
    Filed: April 7, 2006
    Publication date: November 20, 2008
    Inventors: Jayant Chakravarty, Vasily Topolkaraev, John Herbert Conrad, Stephen Avedis Baratian, Jared L. Martin