Patent number: 5002752
Abstract: A mixed-solid solution tri-metallic oxide/sulfide catalyst having the formula:M.sub.I O.sub.a S.sub.b .multidot.M.sub.II O.sub.c M.sub.III O.sub.dwherein M.sub.I is vanadium, neodymium, tantalum, chromium, molybdenum, tungsten, and mixtures thereof; O is oxygen; S is sulfur; a is selected from zero and a number up to a positive real number representing the stoichiometric requirement, and b is selected from zero and a number up to a positive real number representing the stoichiometric requirement, provided one of a and b is a positive real number; M.sub.II is titanium, zirconium, hafnium, and mixtures thereof; c is a positive real number up to the stoichiometric requirement; M.sub.III is lithium, sodium, potassium, rubidium, cesium, francium, beryllium, magnesium, calcium, strontium, barium, radium, zinc, cadmium, mercury, scandium, yttrium, lanthanum, actinium, and mixtures thereof; and d is a positive real number up to the stoichiometric requirement; and wherein M.sub.I O.sub.a S.sub.
Type:
Grant
Filed:
February 20, 1990
Date of Patent:
March 26, 1991
Assignee:
Gas Research Institute
Inventors:
Anthony L. Lee, Howard S. Meyer, Vern L. Hill
Patent number: 4929585
Abstract: A mixed-solid solution tri-metallic oxide/sulfide catalyst having the formula:M.sub.I O.sub.a S.sub.b.M.sub.II O.sub.c M.sub.III O.sub.dwherein M.sub.I is vanadium, neodymium, tantalum, chromium, molybdenum, tungsten, and mixtures thereof; O is oxygen; S is sulfur; a is selected from zero and a number up to a positive real number representing the stoichiometric requirement, and b is selected from zero and a number up to a positive real number representing the stoichiometric requirement, provided one of a and b is a positive real number; M.sub.II is titanium, zirconium, hafnium, and mixtures thereof; c is a positive real number up to the stoichiometric requirement; M.sub.III is lithium, sodium, potassium, rubidium, cesium, francium, beryllium, magnesium, calcium, strontium, barium, radium, zinc, cadmium, mercury, scandium, yttrium, lanthanum, actinium, and mixtures thereof; and d is a positive real number up to the stoichiometric requirement; and wherein M.sub.I O.sub.a S.sub.
Type:
Grant
Filed:
June 9, 1989
Date of Patent:
May 29, 1990
Assignee:
Gas Research Institute
Inventors:
Anthony L. Lee, Howard S. Meyer, Vern L. Hill